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Metauroxite

A valid IMA mineral species
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About MetauroxiteHide

Formula:
(UO2)2(C2O4)(OH)2(H2O)2
Colour:
Light yellow
Lustre:
Vitreous
Hardness:
2
Specific Gravity:
4.403 (Calculated)
Crystal System:
Triclinic
Name:
Named for being lower hydrate counterpart of uroxite.
The lower hydrate counterpart of uroxite. Second natural uranium (uranyl) oxalate. Known synthetic analogue. Structure determined.


Unique IdentifiersHide

Mindat ID:
53690
Long-form identifier:
mindat:1:1:53690:9

IMA Classification of MetauroxiteHide

Classification of MetauroxiteHide

10.AB.52

10 : ORGANIC COMPOUNDS
A : Salts of organic acids
B : Oxalates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MurxIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MetauroxiteHide

Vitreous
Colour:
Light yellow
Streak:
Very pale yellow
Hardness:
Tenacity:
Brittle
Cleavage:
Distinct/Good
Two good cleavages probably on {101} and {010} based on the structure.
Fracture:
Irregular/Uneven
Density:
4.403 g/cm3 (Calculated)

Chemistry of MetauroxiteHide

Mindat Formula:
(UO2)2(C2O4)(OH)2(H2O)2
Element Weights:
Element% weight
U68.191 %
O27.501 %
C3.441 %
H0.866 %

Calculated from ideal end-member formula.

Crystallography of MetauroxiteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 5.5635(3) Å, b = 6.1152(4) Å, c = 7.8283(4) Å
α = 85.572(5)°, β = 89.340(4)°, γ = 82.468(5)°
Ratio:
a:b:c = 0.91 : 1 : 1.28
Unit Cell V:
263.25 ų
Z:
1
Morphology:
Crude blades and lozenge-shaped tablets; commonly in irregular and bowtie-like intergrowths. Tablets are apparently flattened on {011}.
Twinning:
Twinning is ubiquitous, by 180° rotation around the perpendicular to {011}. Polysynthetic.

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
53 : Other minerals with taphonomic origins<0.4
Stage 10b: Anthropogenic minerals<10 Ka
55 : Anthropogenic mine minerals

Type Occurrence of MetauroxiteHide

General Appearance of Type Material:
Light yellow crude blades and tablets
Place of Conservation of Type Material:
Mineralogical collections of the Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA, catalogue numbers 67289 and 67290 (cotypes).
Geological Setting of Type Material:
Post-mining secondary phases found in efflorescent crusts on mine walls.
Associated Minerals at Type Locality:

Synonyms of MetauroxiteHide

Other Language Names for MetauroxiteHide

Common AssociatesHide

Associations Based on Photo Data:
2 photos of Metauroxite associated with GypsumCaSO4 · 2H2O
1 photo of Metauroxite associated with Uranopilite(UO2)6(SO4)O2(OH)6 · 14H2O
1 photo of Metauroxite associated with JarositeKFe3+3(SO4)2(OH)6

Related Minerals - Strunz-mindat GroupingHide

10.AB.Deveroite-(Ce)Ce2(C2O4)3 · 10H2OMon. 2/m : P21/b
10.AB.EdwindavisiteCu(C2O4)(NH3)Orth. mmm(2/m2/m2/m) : Pbca
10.AB.XFalottaiteMnC2O4 · 3H2OOrth. mmm(2/m2/m2/m)
10.AB.Uroxite [(UO2)2(C2O4)(OH)2(H2O)2] · H2OMon. 2/m : P21/b
10.AB.05KatsarositeZn(C2O4) · 2H2OMon. 2/m : B2/b
10.AB.05AndreybulakhiteNi(C2O4) · 2H2OMon. 2/m : B2/b
10.AB.05HumboldtineFe2+(C2O4) · 2H2OMon. 2/m
10.AB.05LindbergiteMn2+(C2O4) · 2H2OMon. 2/m
10.AB.10GlushinskiteMg(C2O4) · 2H2OMon. 2/m : B2/b
10.AB.15MoolooiteCu(C2O4) · nH2OOrth.
10.AB.20StepanoviteNaMgFe3+(C2O4)3 · 8-9H2OTrig. 3m : P3c1
10.AB.25MinguzziteK3Fe3+(C2O4)3 · 3H2OMon. 2/m : P21/b
10.AB.30WheatleyiteNa2Cu(C2O4)2 · 2H2OTric. 1 : P1
10.AB.35ZhemchuzhnikoviteNaMgAl(C2O4)3 · 8H2OTrig. 3m : P3c1
10.AB.40WeddelliteCa(C2O4) · (2.5-x)H2OTet. 4/m : I4/m
10.AB.45WhewelliteCa(C2O4) · H2OMon. 2/m : P21/b
10.AB.47FiemmeiteCu2(C2O4)(OH)2 · 2H2OMon. 2/m : P21/b
10.AB.50CaoxiteCa(C2O4) · 3H2OTric. 1 : P1
10.AB.50MiddlebackiteCu2C2O4(OH)2Mon. 2/m : P21/b
10.AB.55Oxammite(NH4)2(C2O4) · H2OOrth. 222 : P21212
10.AB.60NatroxalateNa2(C2O4)Mon. 2/m : P21/b
10.AB.60Phoxite(NH4)2Mg2(C2O4)(PO3OH)2(H2O)4Mon. 2/m : P21/b
10.AB.60Carboferriphoxite[(NH4)K(H2CO3)][Fe3+(HPO4)(H2PO4)(C2O4)]Tric. 1 : P1
10.AB.60Ferriphoxite[(NH4)2K(H2O)][Fe3+(HPO4)2(C2O4)]Mon. 2/m : P21/b
10.AB.65Coskrenite-(Ce)Ce2(SO4)2(C2O4) · 8H2OTric.
10.AB.70Levinsonite-(Y)(Y,Nd,La)Al(C2O4)(SO4)2 · 12H2OMon. 2/m
10.AB.75Zugshunstite-(Ce)(Ce,Nd,La)Al(C2O4)(SO4)2 · 12H2OMon. 2/m : B2/b
10.AB.80NovgorodovaiteCa2(C2O4)Cl2 · 2H2OMon. 2/m

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 68.1914% 17,047,850 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 0.0000% 0 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Fluorescence of MetauroxiteHide

Weak green-gray fluorescence under 405 nm laser illumination

Other InformationHide

Notes:
Insoluble in H2O and slowly soluble in dilute HCl
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MetauroxiteHide

References for MetauroxiteHide

Localities for MetauroxiteHide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
USA (TL)
 
  • Colorado
    • San Miguel County
Kampf et al. (2020)
  • Utah
    • San Juan County
      • La Sal Creek Mining District
Personal communication with Dr. Travis ...
 
and/or  
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