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Marklite

A valid IMA mineral species
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08746570017272472577565.jpg
Marklite

Friedrich-Christian Mine, Wildschapbach valley, Bad Rippoldsau-Schapbach, Freudenstadt, Karlsruhe Region, Baden-Württemberg, Germany
08746570017272472577565.jpg
Marklite

Friedrich-Christian Mine, Wildschapbach valley, Bad Rippoldsau-Schapbach, Freudenstadt, Karlsruhe Region, Baden-Württemberg, Germany
08746570017272472577565.jpg
Marklite

Friedrich-Christian Mine, Wildschapbach valley, Bad Rippoldsau-Schapbach, Freudenstadt, Karlsruhe Region, Baden-Württemberg, Germany
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About MarkliteHide

06844600017272472588904.jpg
Gregor Markl in the field
Formula:
Cu5(CO3)2(OH)6 · 6H2O
Crystal System:
Monoclinic
Name:
Named after Prof. Dr. Gregor Markl,born February 22nd, 1971 in Frankfurt a.M., Germany,mineralogist at the University of Tübingen, Germany, who found the type specimen of marklite, for his numerous studies and books on crustal petrology, geochemistry and specifically on the hydrothermal ore deposits of the Black Forest area (genesis, oxidative alteration, mineralogy and geochemistry).
New structure type.

Visually similar to devilline and serpierite.

Chemically similar to georgeite; also to claraite (Zn-bearing) and 'cuproartinite' (Mg-bearing); and to azurite and malachite (basic but without water molecules).


Unique IdentifiersHide

Mindat ID:
46877
Long-form identifier:
mindat:1:1:46877:8

Similar NamesHide

MarliteA synonym of 'Marlstone'

IMA Classification of MarkliteHide

IMA status:
Approved
IMA Formula:
Cu2+5(CO3)2(OH)6·6H2O
Approval year:
2016

Classification of MarkliteHide

Strunz-mindat (2026):
5.DA.65

5 : CARBONATES (NITRATES)
D : Carbonates with additional anions, with H2O
A : With medium-sized cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MklIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Chemistry of MarkliteHide

Mindat Formula:
Cu5(CO3)2(OH)6 · 6H2O
Element Weights:
Element% weight
Cu49.041 %
O44.451 %
C3.708 %
H2.800 %

Calculated from ideal end-member formula.
Cu
O
C
H
Elements listed:
C, Cu, H, O - search for minerals with similar chemistry

Crystallography of MarkliteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 12.137(2) Å, b = 6.3832(6) Å, c = 10.579(1) Å
β = 112.4(1)°
Ratio:
a:b:c = 1.901 : 1 : 1.657
Unit Cell V:
757.74 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
11.23 Å(100)
5.61 Å(41)
5.31 Å(32)
3.743 Å(16)
3.054 Å(17)
2.675 Å(30)
2.241 Å(27)
1.539 Å(21)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47c : [Carbonates, phosphates, borates, nitrates]
Stage 10b: Anthropogenic minerals<10 Ka
55 : Anthropogenic mine minerals

Type Occurrence of MarkliteHide

Type Locality:
ⓘ Friedrich-Christian Mine, Wildschapbach valley, Bad Rippoldsau-Schapbach, Freudenstadt, Karlsruhe Region, Baden-Württemberg, Germany
Place of Conservation of Type Material:
Mineralogical collections of (1) the Eberhard Karls Universität, Tübingen, Germany (catalogue number 3586 T), and (2) the Natural History Museum of Los Angeles County, Los Angeles, USA (catalogue number 65630)

Synonyms of MarkliteHide

Other Language Names for MarkliteHide

Dutch:Markliet
German:Marklit

Related Minerals - Strunz-mindat GroupingHide

5.DA.AlexkhomyakoviteK6(Ca2Na)(CO3)5Cl · 6H2OHex. 6/mmm(6/m2/m2/m) : P63/mcm
5.DA.AmoraiteCa12Al6(OH)36(CO3)2(SO3) · 15H2O Tric. 1 : P1
5.DA.05DypingiteMg5(CO3)4(OH)2 · 5H2OMon. 2 : P21
5.DA.05'UM1986-10-CO:ClHMgMnZn (also called Mineral F, Dunn, 1995)'Mg5(Zn,Mn)3(CO3)2(OH,Cl)12 · H2O
5.DA.05'UM1987-01-CO:HMgS'Mg4(CO3)2(OH)4 · 6H2O ?Mon.
5.DA.05GiorgiositeMg5(CO3)4(OH)2 · 5-6H2O
5.DA.05HydromagnesiteMg5(CO3)4(OH)2 · 4H2OMon. 2/m : P21/b
5.DA.05WidgiemoolthaliteNi5(CO3)4(OH)2 · 5H2OMon. 2/m : P21/b
5.DA.10ArtiniteMg2(CO3)(OH)2 · 3H2OMon. 2/m : B2/m
5.DA.10ChlorartiniteMg2(CO3)(OH)Cl · 2H2OTrig. 3m : R3c
5.DA.10IndigiriteMg2Al2(CO3)4(OH)2 · 15H2O
5.DA.15ZaratiteNi3(CO3)(OH)4 · 4H2O ?Iso.
5.DA.15OtwayiteNi2(CO3)(OH)2 · H2OOrth.
5.DA.20KambaldaiteNaNi4(CO3)3(OH)3 · 3H2OHex. 6 : P63
5.DA.25CallaghaniteCu2Mg2(CO3)(OH)6 · 2H2OMon. 2/m : B2/b
5.DA.30Claraite(Cu,Zn)15(CO3)4(AsO4)2(SO4)(OH)14 · 7H2OTric. 1 : P1
5.DA.35HydroscarbroiteAl14(CO3)3(OH)36 · nH2OTric.
5.DA.35ScarbroiteAl5(CO3)(OH)13 · 5H2OTric.
5.DA.40KarchevskyiteMg18Al9(OH)54Sr2(CO3)9(H2O)6(H3O)5Trig.
5.DA.40'UM1987-05-OH:AlCMg'Mg4Al2(OH)12(CO3,SO4) · 3H2O
5.DA.40QuintiniteMg4Al2(OH)12(CO3) · 3H2OHex. 622 : P6322
5.DA.40CharmariteMn2+4Al2(OH)12[CO3] · 3H2OHex.
5.DA.40CaresiteFe2+4Al2(OH)12[CO3] · 3H2OTrig. 32 : P3112
5.DA.45'Hydrotalcite-2H'Mg6Al2(CO3)(OH)16 · 4H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
5.DA.45'Stichtite-2H'Mg6(Cr,Al)2(CO3)(OH)16 · 4H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
5.DA.45BrugnatelliteMg6Fe3+(CO3)(OH)13 · 4H2OHex.
5.DA.45ZaccagnaiteZn4Al2(OH)12[CO3] · 3H2OHex.
5.DA.45'Pyroaurite-2H'Mg6Fe3+2(OH)16(CO3) · 4H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
5.DA.45LiudongshengiteZn4Cr2(OH)12(CO3) · 3H2OTrig. 3m(32/m) : R3m
5.DA.45ChlormagaluminiteMg4Al2(OH)12Cl2 · 3H2OHex. 6/mmm(6/m2/m2/m) : P63/mcm
5.DA.50PyroauriteMg6Fe3+2(OH)16[CO3] · 4H2OTrig. 3m(32/m) : R3m
5.DA.50TakoviteNi6Al2(OH)16[CO3] · 4H2OTrig. 3m(32/m) : R3m
5.DA.50ReevesiteNi6Fe3+2(OH)16(CO3) · 4H2OTrig. 3m(32/m) : R3m
5.DA.50KaznakhtiteNi6Co3+2(CO3)(OH)16 · 4H2OTrig. 3 : R3
5.DA.50ComblainiteNi4Co2(OH)12[CO3] · 3H2OTrig.
5.DA.50Marioantofilliite[Cu4Al2(OH)12](CO3) · 3H2OMon. 2/m : B2/m
5.DA.50HydrotalciteMg6Al2(CO3)(OH)16 · 4H2OTrig. 3m(32/m) : R3m
5.DA.50StichtiteMg6Cr3+2(OH)16[CO3] · 4H2OTrig. 3m(32/m) : R3m
5.DA.50DesautelsiteMg6Mn3+2(OH)16[CO3] · 4H2OTrig. 3m(32/m)
5.DA.55CoalingiteMg10Fe3+2(OH)24[CO3] · 2H2OTrig. 3m(32/m) : R3m
5.DA.55Akopovaite Al4Li2(OH)12(CO3)(H2O)3Mon. 2/m : B2/m
5.DA.60ŠlikiteZn2Mg(CO3)2(OH)2 · 4H2OTric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MarkliteHide

References for MarkliteHide

Localities for MarkliteHide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Germany (TL)
 
  • Baden-Württemberg
    • Karlsruhe Region
      • Freudenstadt
        • Bad Rippoldsau-Schapbach
          • Wildschapbach valley
Anonymous (2016)
Italy
 
  • Veneto
    • Vicenza Province
      • Torrebelvicino
        • Mercanti Valley
          • Monte Trisa Mines
Rocchetti et al. (2018)
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