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Desautelsite

A valid IMA mineral species
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About DesautelsiteHide

09752980017271922536620.jpg
Paul E. Desautels
Formula:
Mg6Mn3+2(OH)16[CO3] · 4H2O
Colour:
Bright orange
Hardness:
2
Specific Gravity:
2.13
Crystal System:
Trigonal
Name:
Named by P. J. Dunn, D. R. Peacor, and T. D. Palmer in 1979 in honor of Paul Ernest Desautels (24 September 1920, Philadelphia, Pennsylvania, USA – 25 July 1991), chemist and Curator of Mineralogy, National Museum of Natural History (Smithsonian Institution), Washington, D.C., USA.
Hydrotalcite Group.
Mn3+-analogue of pyroaurite.


Unique IdentifiersHide

Mindat ID:
1266
Long-form identifier:
mindat:1:1:1266:5

IMA Classification of DesautelsiteHide

Approved
IMA Formula:
Mg6Mn3+2(OH)16(CO3)·4H2O
Approval year:
1978
First published:
1979

Classification of DesautelsiteHide

5.DA.50

5 : CARBONATES (NITRATES)
D : Carbonates with additional anions, with H2O
A : With medium-sized cations
16b.6.2.4

16b : HYDRATED CARBONATES CONTAINING HYDROXYL OR HALOGEN
6 : AmBn(XO3)pZqxH2O & with (m+n):p = 8:1
11.12.3

11 : Carbonates
12 : Carbonates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
DesIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
DesWarr (2020)Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of DesautelsiteHide

Transparency:
Translucent
Colour:
Bright orange
Streak:
Pale orange
Hardness:
Cleavage:
Perfect
Perfect on {0001}
Density:
2.13(2) g/cm3 (Measured)    2.10 g/cm3 (Calculated)

Optical Data of DesautelsiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.569 nε = 1.547
Max. Birefringence:
δ = 0.022
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Low (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Pleochroism:
Strong
Comments:
O = deep orange; E = pale orange.

Chemistry of DesautelsiteHide

Mindat Formula:
Mg6Mn3+2(OH)16[CO3] · 4H2O
Element Weights:
Element% weight
O55.765 %
Mg22.099 %
Mn16.651 %
H3.666 %
C1.820 %

Calculated from ideal end-member formula.
O
Mg
Mn
H
C

Crystallography of DesautelsiteHide

Crystal System:
Trigonal
Class (H-M):
3m(32/m) - Hexagonal Scalenohedral
Cell Parameters:
a = 3.114(1) Å, c = 23.39(2) Å
Ratio:
a:c = 1 : 7.511
Unit Cell V:
196.43 ų (Calculated from Unit Cell)
Morphology:
As hexagonal scales and plates, flattened on {0001}, with {0001} and {1010}.
Twinning:
By rotation about [0001], common.
Comment:
SG R-3m or R3m; Z = 3/8

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.76 Å(100)
3.88 Å(60)
2.622 Å(50)
2.332 Å(60)
1.981 Å(60)
1.768 Å(20)
1.527 Å(30)
Comments:
Powder pattern indistinguishable from that of pyroaurite (Fe2+-analogue).

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
7 : Ultramafic igneous rocks
Stage 3b: Earth’s earliest hydrosphere>4.45
13 : Hadean serpentinization

Type Occurrence of DesautelsiteHide

Synonyms of DesautelsiteHide

Other Language Names for DesautelsiteHide

Relationship of Desautelsite to other SpeciesHide

Other Members of Hydrotalcite Group:
DroninoiteNi6Fe3+2(OH)16Cl2 · 4H2OTrig. 3m(32/m) : R3m
HydrotalciteMg6Al2(CO3)(OH)16 · 4H2OTrig. 3m(32/m) : R3m
IowaiteMg6Fe3+2(OH)16Cl2 · 4H2OTrig. 3m(32/m) : R3m
KaznakhtiteNi6Co3+2(CO3)(OH)16 · 4H2OTrig. 3 : R3
MeixneriteMg6Al2(OH)16(OH)2 · 4H2OTrig. 3m(32/m) : R3m
PyroauriteMg6Fe3+2(OH)16[CO3] · 4H2OTrig. 3m(32/m) : R3m
ReevesiteNi6Fe3+2(OH)16(CO3) · 4H2OTrig. 3m(32/m) : R3m
StichtiteMg6Cr3+2(OH)16[CO3] · 4H2OTrig. 3m(32/m) : R3m
TakoviteNi6Al2(OH)16[CO3] · 4H2OTrig. 3m(32/m) : R3m
'UM2002-02-COH:FeNi'(Fe2+,Ni)6Fe3+2(CO3)(OH)16 · 4H2O
WoodalliteMg6Cr2(OH)16Cl2 · 4H2OTrig. 3m(32/m) : R3m

Common AssociatesHide

Associations Based on Photo Data:
45 photos of Desautelsite associated with ArtiniteMg2(CO3)(OH)2 · 3H2O
4 photos of Desautelsite associated with 'Serpentinite'
4 photos of Desautelsite associated with AntigoriteMg3(Si2O5)(OH)4
3 photos of Desautelsite associated with HydromagnesiteMg5(CO3)4(OH)2 · 4H2O
3 photos of Desautelsite associated with PyroauriteMg6Fe3+2(OH)16[CO3] · 4H2O
2 photos of Desautelsite associated with Serpentine SubgroupD3[Si2O5](OH)4
2 photos of Desautelsite associated with 'Pyroaurite-2H'Mg6Fe3+2(OH)16(CO3) · 4H2O
2 photos of Desautelsite associated with AragoniteCaCO3
1 photo of Desautelsite associated with BruciteMg(OH)2

Related Minerals - Strunz-mindat GroupingHide

5.DA.AlexkhomyakoviteK6(Ca2Na)(CO3)5Cl · 6H2OHex. 6/mmm(6/m2/m2/m) : P63/mcm
5.DA.AmoraiteCa12Al6(OH)36(CO3)2(SO3) · 15H2O Tric. 1 : P1
5.DA.05DypingiteMg5(CO3)4(OH)2 · 5H2OMon. 2 : P21
5.DA.05'UM1986-10-CO:ClHMgMnZn (also called Mineral F, Dunn, 1995)'Mg5(Zn,Mn)3(CO3)2(OH,Cl)12 · H2O
5.DA.05'UM1987-01-CO:HMgS'Mg4(CO3)2(OH)4 · 6H2O ?Mon.
5.DA.05GiorgiositeMg5(CO3)4(OH)2 · 5-6H2O
5.DA.05HydromagnesiteMg5(CO3)4(OH)2 · 4H2OMon. 2/m : P21/b
5.DA.05WidgiemoolthaliteNi5(CO3)4(OH)2 · 5H2OMon. 2/m : P21/b
5.DA.10ArtiniteMg2(CO3)(OH)2 · 3H2OMon. 2/m : B2/m
5.DA.10ChlorartiniteMg2(CO3)(OH)Cl · 2H2OTrig. 3m : R3c
5.DA.10IndigiriteMg2Al2(CO3)4(OH)2 · 15H2O
5.DA.15ZaratiteNi3(CO3)(OH)4 · 4H2O ?Iso.
5.DA.15OtwayiteNi2(CO3)(OH)2 · H2OOrth.
5.DA.20KambaldaiteNaNi4(CO3)3(OH)3 · 3H2OHex. 6 : P63
5.DA.25CallaghaniteCu2Mg2(CO3)(OH)6 · 2H2OMon. 2/m : B2/b
5.DA.30Claraite(Cu,Zn)15(CO3)4(AsO4)2(SO4)(OH)14 · 7H2OTric. 1 : P1
5.DA.35HydroscarbroiteAl14(CO3)3(OH)36 · nH2OTric.
5.DA.35ScarbroiteAl5(CO3)(OH)13 · 5H2OTric.
5.DA.40KarchevskyiteMg18Al9(OH)54Sr2(CO3)9(H2O)6(H3O)5Trig.
5.DA.40'UM1987-05-OH:AlCMg'Mg4Al2(OH)12(CO3,SO4) · 3H2O
5.DA.40QuintiniteMg4Al2(OH)12(CO3) · 3H2OHex. 622 : P6322
5.DA.40CharmariteMn2+4Al2(OH)12[CO3] · 3H2OHex.
5.DA.40CaresiteFe2+4Al2(OH)12[CO3] · 3H2OTrig. 32 : P3112
5.DA.45'Hydrotalcite-2H'Mg6Al2(CO3)(OH)16 · 4H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
5.DA.45'Stichtite-2H'Mg6(Cr,Al)2(CO3)(OH)16 · 4H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
5.DA.45BrugnatelliteMg6Fe3+(CO3)(OH)13 · 4H2OHex.
5.DA.45ZaccagnaiteZn4Al2(OH)12[CO3] · 3H2OHex.
5.DA.45'Pyroaurite-2H'Mg6Fe3+2(OH)16(CO3) · 4H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
5.DA.45LiudongshengiteZn4Cr2(OH)12(CO3) · 3H2OTrig. 3m(32/m) : R3m
5.DA.45ChlormagaluminiteMg4Al2(OH)12Cl2 · 3H2OHex. 6/mmm(6/m2/m2/m) : P63/mcm
5.DA.50PyroauriteMg6Fe3+2(OH)16[CO3] · 4H2OTrig. 3m(32/m) : R3m
5.DA.50TakoviteNi6Al2(OH)16[CO3] · 4H2OTrig. 3m(32/m) : R3m
5.DA.50ReevesiteNi6Fe3+2(OH)16(CO3) · 4H2OTrig. 3m(32/m) : R3m
5.DA.50KaznakhtiteNi6Co3+2(CO3)(OH)16 · 4H2OTrig. 3 : R3
5.DA.50ComblainiteNi4Co2(OH)12[CO3] · 3H2OTrig.
5.DA.50Marioantofilliite[Cu4Al2(OH)12](CO3) · 3H2OMon. 2/m : B2/m
5.DA.50HydrotalciteMg6Al2(CO3)(OH)16 · 4H2OTrig. 3m(32/m) : R3m
5.DA.50StichtiteMg6Cr3+2(OH)16[CO3] · 4H2OTrig. 3m(32/m) : R3m
5.DA.55CoalingiteMg10Fe3+2(OH)24[CO3] · 2H2OTrig. 3m(32/m) : R3m
5.DA.55Akopovaite Al4Li2(OH)12(CO3)(H2O)3Mon. 2/m : B2/m
5.DA.60ŠlikiteZn2Mg(CO3)2(OH)2 · 4H2OTric. 1 : P1
5.DA.65MarkliteCu5(CO3)2(OH)6 · 6H2OMon. 2/m : P21/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for DesautelsiteHide

References for DesautelsiteHide

Localities for DesautelsiteHide

Showing 10 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
China
 
  • Inner Mongolia
    • Baotou City
      • Bayan Obo mining district
        • Bayan Obo deposit
Xue et al. (2026)
Japan
 
  • Aichi Prefecture
    • Shinshiro city
Ohe Rikosya specimens.
  • Kochi Prefecture
    • Kochi City
Matsubara (1984)
  • Mie Prefecture
    • Toba City
Yamada (2004)
USA
 
  • California
    • Fresno County
      • Coalinga
Dunn et al. (1979) +2 other references
Dunn et al. (1979)
    • San Benito County
      • Picacho Peak
www.benitoitemine.com
Pemberton (1983) +1 other reference
  • Maryland
    • Montgomery County
      • Rockville
Parker (2005)
  • Pennsylvania
    • Lancaster County
      • Fulton Township
Dunn et al. (1979)
 
and/or  
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