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Argesite

A valid IMA mineral species
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About ArgesiteHide

01755820017271950928787.jpg
Brontes, Arges, and Steropes
Formula:
(NH4)7Bi3Cl16
Colour:
Pale yellow
Lustre:
Vitreous
Specific Gravity:
2.88
Crystal System:
Trigonal
Name:
After Uranus’s son Arges, one of the three Cyclops who were helpers of Hephaistos, the ancient Greek god of fire (Vulcanus for the ancient Romans) whose workshops were alleged to be located at Vulcano island (or Etna).
Unique combination of elements. One of two NH4-Bi minerals, the second being campostriniite.


Unique IdentifiersHide

Mindat ID:
42369
Long-form identifier:
mindat:1:1:42369:6

IMA Classification of ArgesiteHide

Approved
IMA Formula:
(N3-H4)7Bi3+3Cl16
Approval year:
2011

Classification of ArgesiteHide

7.CD.

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
D : With only large cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
AgeIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ArgesiteHide

Vitreous
Colour:
Pale yellow
Streak:
White
Cleavage:
None Observed
Fracture:
Conchoidal
Density:
2.88(1) g/cm3 (Measured)    2.843 g/cm3 (Calculated)

Optical Data of ArgesiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.731(2) nε = 1.725(2)
Max. Birefringence:
δ = 0.006
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.

Surface Relief:
Moderate

Chemistry of ArgesiteHide

Mindat Formula:
(NH4)7Bi3Cl16
Element Weights:
Element% weight
Bi47.479 %
Cl42.958 %
N7.425 %
H2.137 %

Calculated from ideal end-member formula.

Crystallography of ArgesiteHide

Crystal System:
Trigonal
Class (H-M):
3m(32/m) - Hexagonal Scalenohedral
Space Group:
R3c
Setting:
R3c
Cell Parameters:
a = 13.093(1) Å, c = 102.682(9) Å
Ratio:
a:c = 1 : 7.843
Unit Cell V:
15245 ų
Z:
18
Morphology:
Habit is almost tabular [according to the {001} pinacoid] and in most cases is very complex, due to the presence of various rhombohedra and bipyramids.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0019257ArgesiteDemartin F, Campostrini I, Castellano C, Gramaccioli C M (2012) Argesite, (NH4)7Bi3Cl16, a new mineral from La Fossa Crater, Vulcano, Aeolian Islands, Italy: A first example of the [Bi2Cl10]4- anion American Mineralogist 97 1446-14512012La Fossa Crater, Vulcano, Aeolian Islands, Italy0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.46 Å(11)
6.14 Å(16)
5.71 Å(11)
3.808 Å(44)
3.164 Å(100)
2.742 Å(24)
1.906 Å(16)
1.686 Å(13)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
45b : [Other oxidized fumarolic minerals]

Type Occurrence of ArgesiteHide

General Appearance of Type Material:
Pale-yellow crystals up to 0.15 mm in length.
Place of Conservation of Type Material:
Type material is deposited in the Reference Collection of the DCSSI, University of Milan, Milan, Italy, sample number 2011-04.
Geological Setting of Type Material:
In an active medium-temperature (~250 °C) intracrater fumarole on a pyroclastic breccia.
Associated Minerals at Type Locality:

Synonyms of ArgesiteHide

Other Language Names for ArgesiteHide

Dutch:Argesiet
French:Argesite
German:Argesit
Norwegian:Argesitt

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Argesite associated with Adranosite(NH4)4NaAl2(SO4)4Cl(OH)2

Related Minerals - Strunz-mindat GroupingHide

7.CD.Campostriniite(Bi3+,Na)3(NH4,K)2Na2(SO4)6 · H2OMon. 2/m : B2/b
7.CD.05MatteucciteNaHSO4 · H2OMon. m
7.CD.10MirabiliteNa2SO4 · 10H2OMon. 2/m : P21/b
7.CD.15Lecontite(NH4)Na(SO4) · 2H2OOrth. 222 : P212121
7.CD.20HydroglauberiteNa10Ca3(SO4)8 · 6H2OMon.
7.CD.25EugsteriteNa4Ca(SO4)3 · 2H2OMon.
7.CD.30GörgeyiteK2Ca5(SO4)6 · H2OMon. 2/m : B2/b
7.CD.35SyngeniteK2Ca(SO4)2 · H2OMon. 2/m : P21/m
7.CD.35AntofagastaiteNa2Ca(SO4)2 · 1.5H2OMon. 2/m : P21/m
7.CD.35Koktaite(NH4)2Ca(SO4)2 · H2OMon. 2/m : P21/b
7.CD.40GypsumCaSO4 · 2H2OMon. 2/m
7.CD.45Chinleite-(Y)NaY(SO4)2 · H2OTrig. 32
7.CD.45BassaniteCa(SO4) · 0.5H2OMon. 2 : B2
7.CD.45Chinleite-(Nd)NaNd(SO4)2 · H2OTrig. 32 : P3221
7.CD.45Chinleite-(Ce)NaCe(SO4)2(H2O)Trig. 32 : P3221
7.CD.50Zircosulfate(Zr,Ti)(SO4)2 · 4H2OOrth. mmm(2/m2/m2/m) : Fddd
7.CD.55SchieffelinitePb10Te6+6O20(OH)14(SO4)(H2O)5Orth. mmm(2/m2/m2/m) : Cmcm
7.CD.60MontaniteBi2(TeO6) · nH2OHex. 6 : P6
7.CD.65OmongwaiteNa2Ca5(SO4)6 · 3H2OMon. 2 : B2

Fluorescence of ArgesiteHide

Non-fluorescent.

Other InformationHide

Notes:
The mineral is not hygroscopic and is stable in open air.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ArgesiteHide

References for ArgesiteHide

Localities for ArgesiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy (TL)
 
  • Sicily
    • Metropolitan City of Messina
      • Eolie Islands (Aeolian Islands)
        • Lipari
          • Vulcano Island
Williams et al. (2011) +1 other reference
 
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