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Koktaite

A valid IMA mineral species - grandfathered
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About KoktaiteHide

Formula:
(NH4)2Ca(SO4)2 · H2O
Colour:
Colourless, white
Specific Gravity:
2.09
Crystal System:
Monoclinic
Name:
Named in honor of Jaroslav Kokta (29 April 1904, Skorotice, Austria-Hungary - 2 August 1970, Ostrava, Czechoslovakia), chemist at the Masarykov University, Brno, Czechoslovakia who analyzed the artificial compound.
This page provides mineralogical data about Koktaite.


Unique IdentifiersHide

Mindat ID:
2237
Long-form identifier:
mindat:1:1:2237:4

IMA Classification of KoktaiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
(N3-H4)2Ca(S6+O4)2·H2O
First published:
1948

Classification of KoktaiteHide

7.CD.35

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
D : With only large cations
29.3.1.2

29 : HYDRATED ACID AND NORMAL SULFATES
3 : A2B(XO4)2·xH2O
25.4.11

25 : Sulphates
4 : Sulphates of Ca, Sr and Ba

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
KktIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KoktaiteHide

Transparency:
Transparent, Translucent
Colour:
Colourless, white
Streak:
White
Cleavage:
None Observed
Density:
2.09 g/cm3 (Measured)    2.114 g/cm3 (Calculated)

Optical Data of KoktaiteHide

Type:
Biaxial (-)
RI values:
nα = 1.524 nβ = 1.532 nγ = 1.536
2V:
Measured: 72° , Calculated: 70°
Max. Birefringence:
δ = 0.012
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Dispersion:
r > v
Comments:
Y = b; Z' ∧ c (on {110})=2◦

Chemistry of KoktaiteHide

Mindat Formula:
(NH4)2Ca(SO4)2 · H2O
Element Weights:
Element% weight
O50.296 %
S22.400 %
Ca13.999 %
N9.785 %
H3.521 %

Calculated from ideal end-member formula.

Crystallography of KoktaiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/a
Cell Parameters:
a = 10.17 Å, b = 7.15 Å, c = 6.34 Å
β = 102.75°
Ratio:
a:b:c = 1.422 : 1 : 0.887
Unit Cell V:
449.65 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Crystals acicular or fibrous-lamellar.
Forms: {100}, {110}, {001}, {011}, {101}
Twinning:
On {100}, common.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.83 Å(100)
3.30 Å(65)
4.96 Å(40)
5.83 Å(25)
3.00 Å(25)
3.56 Å(20)
2.89 Å(20)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
21 : Chemically precipitated carbonate, phosphate, iron formations
Stage 7: Great Oxidation Event<2.4
45a : [Sulfates, arsenates, selenates, antimonates]
45b : [Other oxidized fumarolic minerals]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
50 : Coal and/or oil shale minerals<0.36
52 : Guano- and urine-derived minerals<0.4
Stage 10b: Anthropogenic minerals<10 Ka
54 : Coal and other mine fire minerals (see also #51 and #56)

Type Occurrence of KoktaiteHide

General Appearance of Type Material:
Pseudomorphs after gypsum.
Place of Conservation of Type Material:
1) Moravian Museum, Brno, Czech Republic, A6109.
2) National School of Mines, Paris, France.
3) National Museum of Natural History, Washington, D.C., USA, 137963.
Geological Setting of Type Material:
Waste piles of a lignite mine.
Associated Minerals at Type Locality:

Synonyms of KoktaiteHide

Other Language Names for KoktaiteHide

Dutch:Koktaiet
German:Koktait
Spanish:Koktaita

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Koktaite associated with Mascagnite(NH4)2SO4
1 photo of Koktaite associated with GypsumCaSO4 · 2H2O
1 photo of Koktaite associated with AnhydriteCaSO4

Related Minerals - Strunz-mindat GroupingHide

7.CD.Argesite(NH4)7Bi3Cl16 Trig. 3m(32/m) : R3c
7.CD.Campostriniite(Bi3+,Na)3(NH4,K)2Na2(SO4)6 · H2OMon. 2/m : B2/b
7.CD.05MatteucciteNaHSO4 · H2OMon. m
7.CD.10MirabiliteNa2SO4 · 10H2OMon. 2/m : P21/b
7.CD.15Lecontite(NH4)Na(SO4) · 2H2OOrth. 222 : P212121
7.CD.20HydroglauberiteNa10Ca3(SO4)8 · 6H2OMon.
7.CD.25EugsteriteNa4Ca(SO4)3 · 2H2OMon.
7.CD.30GörgeyiteK2Ca5(SO4)6 · H2OMon. 2/m : B2/b
7.CD.35SyngeniteK2Ca(SO4)2 · H2OMon. 2/m : P21/m
7.CD.35AntofagastaiteNa2Ca(SO4)2 · 1.5H2OMon. 2/m : P21/m
7.CD.40GypsumCaSO4 · 2H2OMon. 2/m
7.CD.45Chinleite-(Y)NaY(SO4)2 · H2OTrig. 32
7.CD.45BassaniteCa(SO4) · 0.5H2OMon. 2 : B2
7.CD.45Chinleite-(Nd)NaNd(SO4)2 · H2OTrig. 32 : P3221
7.CD.45Chinleite-(Ce)NaCe(SO4)2(H2O)Trig. 32 : P3221
7.CD.50Zircosulfate(Zr,Ti)(SO4)2 · 4H2OOrth. mmm(2/m2/m2/m) : Fddd
7.CD.55SchieffelinitePb10Te6+6O20(OH)14(SO4)(H2O)5Orth. mmm(2/m2/m2/m) : Cmcm
7.CD.60MontaniteBi2(TeO6) · nH2OHex. 6 : P6
7.CD.65OmongwaiteNa2Ca5(SO4)6 · 3H2OMon. 2 : B2

Other InformationHide

Notes:
Soluble in H2O, leaving a residue of gypsum.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KoktaiteHide

References for KoktaiteHide

Localities for KoktaiteHide

Showing 18 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Czech Republic
 
  • Moravian-Silesian Region
    • Ostrava-City District
      • Ostrava
Matýsek et al. (2022)
Matýsek et al. (2022)
  • South Moravian Region
    • Brno-Country District
      • Zastávka
Dr. Jaroslav Hyrsl labels
    • Hodonín District
Sekanina (1948) +1 other reference
Germany
 
  • Thuringia
    • Greiz District
      • Ronneburg
Witzke et al. (1998)
Ghana
 
  • Oti Region
Addae et al. (2026)
Hungary
 
  • Baranya County
    • Pécs District
Szakáll et al. (2008)
  • Borsod-Abaúj-Zemplén County
    • Miskolc District
      • Miskolc
Szakáll et al. (1997)
New Zealand
 
  • Waikato Region
    • Taupo District
Johnstone (1979)
Johnstone (1979)
Poland
 
  • Silesian Voivodeship
    • Rybnik
      • Niedobczyce
Ł. Kruszewski (PXRD data)
    • Wodzisław County
      • Wodzisław Śląski
Kruszewski et al. (2018)
Russia
 
  • Chelyabinsk Oblast
Cesnokov et al. (1998)
USA
 
  • California
    • Imperial County
      • Salton Sea
        • Mullet Island
Adams et al. (2014)
Adams et al. (2014)
    • Santa Barbara County
Kampf et al. (2024)
Venezuela
 
  • Miranda
Urbani
Franco Urbani (2009)
 
and/or  
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