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Simonkolleite

A valid IMA mineral species

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Photos of Simonkolleite (17)Discuss Simonkolleite

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Edit Simonkolleite Add Synonym Edit CIF structures Clear Cache

Simonkolleite

Genna zinc smelter slag locality, Helmke quarry nature reserve, Letmathe, Iserlohn, Märkischer Kreis, Arnsberg, North Rhine-Westphalia, Germany

Simonkolleite

Slag dumps, Richelsdorf Smelter, Süß, Nentershausen, Hersfeld-Rotenburg, Kassel Region, Hesse, Germany

Simonkolleite

Richelsdorf Smelter, Süß, Nentershausen, Hersfeld-Rotenburg, Kassel Region, Hesse, Germany

Simonkolleite

Genna zinc smelter slag locality, Helmke quarry nature reserve, Letmathe, Iserlohn, Märkischer Kreis, Arnsberg, North Rhine-Westphalia, Germany

Simonkolleite

Slag dumps, Richelsdorf Smelter, Süß, Nentershausen, Hersfeld-Rotenburg, Kassel Region, Hesse, Germany

Simonkolleite

Richelsdorf Smelter, Süß, Nentershausen, Hersfeld-Rotenburg, Kassel Region, Hesse, Germany

Simonkolleite

Genna zinc smelter slag locality, Helmke quarry nature reserve, Letmathe, Iserlohn, Märkischer Kreis, Arnsberg, North Rhine-Westphalia, Germany

Simonkolleite

Slag dumps, Richelsdorf Smelter, Süß, Nentershausen, Hersfeld-Rotenburg, Kassel Region, Hesse, Germany

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About SimonkolleiteHide

Werner Simon

Formula:

Zn₅Cl₂(OH)₈ · H₂O

Colour:

Colourless

Lustre:

Vitreous, Sub-Vitreous

Hardness:

1½

Specific Gravity:

3.20

Crystal System:

Trigonal

Name:

Named in 1985 by Karl Schmetzer, Günther Schnorrer-Köhler, and Olaf Medenbach in honor of Werner Simon [b. December 18, 1939 Rockensuess, Germany], a professional printer and business owner and Kurt Kolle [b. 1949, Germany], both mineral collectors of Cornberg, near Michelsdorf, who submitted the samples for investigation.

Type Locality:

ⓘ Slag dumps, Richelsdorf Smelter, Süß, Nentershausen, Hersfeld-Rotenburg, Kassel Region, Hesse, Germany

In synthetic form, used as a zinc nutritional supplement for animals.

Unique IdentifiersHide

Mindat ID:

3668

Long-form identifier:

mindat:1:1:3668:5

IMA Classification of SimonkolleiteHide

IMA status:

Approved

IMA Formula:

Zn²⁺₅(OH)₈Cl₂·H₂O

Approval year:

1983

Classification of SimonkolleiteHide

Strunz-mindat (2026):

3.DA.20

3 : HALIDES
D : Oxyhalides, hydroxyhalides and related double halides
A : With Cu, etc., without Pb

Dana 8th ed.:

10.5.8.1

10 : OXYHALIDES AND HYDROXYHALIDES
5 : A_m(O,OH)_pX_q

Hey's CIM Ref.:

8.5.1

8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
5 : Halides of Zn and Hg

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference for Standard
Skl	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of SimonkolleiteHide

Lustre:

Vitreous, Sub-Vitreous

Transparency:

Transparent, Translucent

Colour:

Colourless

Streak:

White

Hardness:

1½ on Mohs scale

Tenacity:

Brittle

Cleavage:

Perfect
{0001}

Density:

3.20 g/cm³ (Measured) 3.35 g/cm³ (Calculated)

Optical Data of SimonkolleiteHide

Type:

Uniaxial (+)

RI values:

n_ω = 1.657 n_ε = 1.700

Birefringence:

0.043

Max. Birefringence:

δ = 0.043
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.

Thickness: 30 µm

Rotation:

Surface Relief:

Moderate

Pleochroism:

Non-pleochroic

Chemistry of SimonkolleiteHide

Mindat Formula:

Zn₅Cl₂(OH)₈ · H₂O

Element Weights:

Element	% weight
Zn	59.234 %
O	26.092 %
Cl	12.848 %
H	1.826 %

Calculated from ideal end-member formula.

Elements listed:

Cl, H, O, Zn - search for minerals with similar chemistry

Crystallography of SimonkolleiteHide

Crystal System:

Trigonal

Class (H-M):

3m(32/m) - Hexagonal Scalenohedral

Space Group:

P3m1

Cell Parameters:

a = 6.34 Å, c = 23.66 Å

Ratio:

a:c = 1 : 3.732

Unit Cell V:

823.61 Å³ (Calculated from Unit Cell)

Crystal StructureHide

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CIF File Best | x | y | z | a | b | c

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0005776	Simonkolleite	Hawthorne F C, Sokolova E V (2002) Simonkolleite, Zn5(OH)8Cl2(H2O), a decorated interrupted-sheet structure of the form [M_2]4 The Canadian Mineralogist 40 939-946		2002		0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Simonkolleite'
loop_
_publ_author_name
'Hawthorne F C'
'Sokolova E V'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 40 
_journal_year 2002
_journal_page_first 939
_journal_page_last 946
_publ_section_title
;
 Simonkolleite, Zn5(OH)8Cl2(H2O), a decorated interrupted-sheet structure
 of the form [M_2]4
;
_database_code_amcsd 0005776
_chemical_formula_sum 'Zn5 Cl2 O9 H10'
_cell_length_a 6.3412
_cell_length_b 6.3412
_cell_length_c 23.646
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 823.438
_exptl_crystal_density_diffrn      3.339
_symmetry_space_group_name_H-M 'R -3 m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '2/3+x,1/3+y,1/3+z'
  '1/3+x,2/3+y,2/3+z'
  'x,x-y,z'
  '2/3+x,1/3+x-y,1/3+z'
  '1/3+x,2/3+x-y,2/3+z'
  'y,x,-z'
  '2/3+y,1/3+x,1/3-z'
  '1/3+y,2/3+x,2/3-z'
  '-x+y,y,z'
  '2/3-x+y,1/3+y,1/3+z'
  '1/3-x+y,2/3+y,2/3+z'
  '-x,-x+y,-z'
  '2/3-x,1/3-x+y,1/3-z'
  '1/3-x,2/3-x+y,2/3-z'
  '-y,-x,z'
  '2/3-y,1/3-x,1/3+z'
  '1/3-y,2/3-x,2/3+z'
  'x-y,-y,-z'
  '2/3+x-y,1/3-y,1/3-z'
  '1/3+x-y,2/3-y,2/3-z'
  'y,-x+y,-z'
  '2/3+y,1/3-x+y,1/3-z'
  '1/3+y,2/3-x+y,2/3-z'
  '-x+y,-x,z'
  '2/3-x+y,1/3-x,1/3+z'
  '1/3-x+y,2/3-x,2/3+z'
  '-x,-y,-z'
  '2/3-x,1/3-y,1/3-z'
  '1/3-x,2/3-y,2/3-z'
  '-y,x-y,z'
  '2/3-y,1/3+x-y,1/3+z'
  '1/3-y,2/3+x-y,2/3+z'
  'x-y,x,-z'
  '2/3+x-y,1/3+x,1/3-z'
  '1/3+x-y,2/3+x,2/3-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Zn(1)   0.50000   0.00000   0.00000   1.00000   0.01220
Zn(2)   0.00000   0.00000   0.07172   1.00000   0.01240
Cl   0.00000   0.00000   0.16948   1.00000   0.02530
O-h(1)   0.82880   0.17120   0.04988   1.00000   0.01250
O-h(2)   0.00000   0.00000   0.37410   1.00000   0.01170
Wat(3)   0.96900   0.03100   0.50200   0.16667   0.03690
H(1)   0.78600   0.21400   0.08600   1.00000   0.05000
H(2)   0.00000   0.00000   0.41550   1.00000   0.05000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Zn(1) 0.00990 0.00850 0.01770 0.00420 0.00020 0.00040
Zn(2) 0.01140 0.01140 0.01450 0.00570 0.00000 0.00000
Cl 0.03110 0.03110 0.01370 0.01560 0.00000 0.00000
O-h(1) 0.01280 0.01280 0.01330 0.00730 -0.00030 0.00030
O-h(2) 0.01170 0.01170 0.01150 0.00590 0.00000 0.00000

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
7.87 Å	(100)
3.58 Å	(30)
3.17 Å	(40)
2.94 Å	(30)
2.73 Å	(60)
2.67 Å	(70)
2.37 Å	(40)
1.59 Å	(40)

Comments:

IcDD 7-155

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 7: Great Oxidation Event	<2.4
47a : [Near-surface hydration of prior minerals]
47g : [Halogen-bearing surface weathering minerals]
Stage 10b: Anthropogenic minerals	<10 Ka
56 : Slag and smelter minerals (see also #51 and #55)

Type Occurrence of SimonkolleiteHide

Type Locality:

ⓘ Slag dumps, Richelsdorf Smelter, Süß, Nentershausen, Hersfeld-Rotenburg, Kassel Region, Hesse, Germany

General Appearance of Type Material:

Tabular hexagonal crystals to 1 mm

Geological Setting of Type Material:

Originally found as a weathering product of zn-bearing slags at the Richelsdorf Smelting Refinery.

Synonyms of SimonkolleiteHide

IMA1983-019

Other Language Names for SimonkolleiteHide

Dutch:Simonkolleiet

German:Simonkolleit

Russian:Симонколлеит

Spanish:Simonkolleita

Common AssociatesHide

Associations Based on Photo Data:

1 photo of Simonkolleite associated with Brianyoungite	Zn₃(CO₃,SO₄)(OH)₄
1 photo of Simonkolleite associated with 'Slag'
1 photo of Simonkolleite associated with Namuwite	Zn₄(SO₄)(OH)₆ · 4H₂O

Related Minerals - Strunz-mindat Grouping Hide

3.DA.	Parahibbingite	Fe₂(OH)₃Cl	Trig. 3m(32/m) : R3m
3.DA.	Centennialite	CaCu₃Cl₂(OH)₆ · nH₂O (n ~ 0.7)	Trig. 3m(32/m) : P3m1
3.DA.	Bounahasite	Cu⁺Cu²⁺₂(OH)₃Cl₂	Mon. 2/m
3.DA.	Muonionalustaite	Ni₃(OH)₄Cl₂ · 4H₂O	Mon. 2/m : B2/m
3.DA.05	Melanothallite	Cu₂Cl₂O	Orth. mmm(2/m2/m2/m) : Fddd
3.DA.10c	Haydeeite	Cu₃Mg(OH)₆Cl₂	Trig. 3m(32/m) : P3m1
3.DA.10b	Clinoatacamite	Cu₂(OH)₃Cl	Mon. 2/m
3.DA.10c	Paratacamite	Cu₃(Cu,Zn)(OH)₆Cl₂	Trig. 3 : R3
3.DA.10c	Kapellasite	Cu₃Zn(OH)₆Cl₂	Trig. 3m(32/m) : P3m1
3.DA.10c	Leverettite	Cu₃Co(OH)₆Cl₂	Trig. 3 : R3
3.DA.10a	Hibbingite	Fe²⁺₂(OH)₃Cl	Orth. mmm(2/m2/m2/m) : Pnma
3.DA.10c	Paratacamite-(Ni)	Cu₃(Ni,Cu)(OH)₆Cl₂	Trig. 3 : R3
3.DA.10a	Kempite	Mn²⁺₂(OH)₃Cl	Orth. mmm(2/m2/m2/m) : Pnma
3.DA.10c	Tondiite	Cu₃Mg(OH)₆Cl₂	Trig. 3m(32/m) : R3m
3.DA.10a	Atacamite	Cu₂(OH)₃Cl	Orth. mmm(2/m2/m2/m) : Pnma
3.DA.10b	Belloite	Cu(OH)Cl	Mon. 2/m : P2₁/b
3.DA.10c	Misakiite	Cu₃Mn(OH)₆Cl₂	Trig. 3m(32/m) : P3m1
3.DA.10b	Iyoite	MnCuCl(OH)₃	Mon. 2/m : P2₁/m
3.DA.10c	Kuliginite	Fe₃Mg(OH)₆Cl₂	Trig. 3 : R3
3.DA.10c	Gillardite	Cu₃Ni(OH)₆Cl₂	Trig. 3m(32/m) : R3m
3.DA.10b	'Unnamed (Cu-Zn Chloride Hydroxide)'	CuZnCl(OH)₃	Mon. 2/m : P2₁/m
3.DA.10b	Botallackite	Cu₂(OH)₃Cl	Mon. 2/m : P2₁/m
3.DA.10c	Herbertsmithite	Cu₃Zn(OH)₆Cl₂	Trig. 3m(32/m) : R3m
3.DA.15	Claringbullite	Cu₄ClF(OH)₆	Hex. 6/mmm(6/m2/m2/m) : P6₃/mmc
3.DA.15	Barlowite	Cu₄BrF(OH)₆	Hex. 6/mmm(6/m2/m2/m) : P6₃/mmc
3.DA.25	Buttgenbachite	Cu₁₉(NO₃)₂(OH)₃₂Cl₄ · 2H₂O	Hex. 6/mmm(6/m2/m2/m) : P6₃/mmc
3.DA.25	Connellite	Cu₁₉(SO₄)(OH)₃₂Cl₄ · 3H₂O	Hex. 6m2 : P62c
3.DA.30	Abhurite	Sn₂₁Cl₁₆(OH)₁₄O₆	Trig. 32 : R32
3.DA.35	Ponomarevite	K₄Cu₄Cl₁₀O	Mon. 2/m : B2/b
3.DA.40	Calumetite	CaCu₄(OH)₈Cl₂ · 3.5H₂O	Orth. mmm(2/m2/m2/m) : Cmcm
3.DA.40	Anthonyite	Cu(OH,Cl)₂ · 3H₂O	Mon. 2/m
3.DA.45	Khaidarkanite	Cu₄Al₃(OH)₁₄F₃ · 2H₂O	Mon. 2/m : B2/m
3.DA.50	Bobkingite	Cu₅Cl₂(OH)₈ · 2H₂O	Mon. 2/m : B2/m
3.DA.55	Avdoninite	K₂Cu₅(OH)₄Cl₈ · H₂O	Mon. 2/m : P2₁/b
3.DA.60	Droninoite	Ni₆Fe³⁺₂(OH)₁₆Cl₂ · 4H₂O	Trig. 3m(32/m) : R3m
3.DA.70	Chrysothallite	K₆Cu₆Tl³⁺Cl₁₇(OH)₄ · H₂O	Tet. 4/mmm(4/m2/m2/m) : I4/mmm
3.DA.70	Dioskouriite	CaCu₄Cl₆(OH)₄ · 4H₂O	Mon. 2/m : P2₁/b
3.DA.75	Feodosiyite	Cu₁₁Mg₂Cl₁₈(OH)₈ · 16H₂O	Mon. 2/m : P2₁/b
3.DA.80	Romanorlovite	K₈Cu₆Cl₁₇(OH)₃	Tet. 4/mmm(4/m2/m2/m) : I4/mmm

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for SimonkolleiteHide

mindat.org URL:

https://www.mindat.org/min-3668.html
Please feel free to link to this page.

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External Links:

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

Mineral Dealers:

Buy from D. Joyce minerals

References for SimonkolleiteHide

Reference List:

Allmann, Rudolf (1968) Verfeinerung der Struktur des Zinkhydroxidchlorids II, Zn₅(OH)₈Cl₂· 1H₂O. Zeitschrift für Kristallographie, 126 (5-6). 417-426 doi:10.1524/zkri.1968.126.5-6.417

Schmetzer, K., Schnorrer-Köhler, G., Medenbach, O. (1985) Wülfingite, ε-Zn(OH)₂, and simonkolleite, Zn(OH)₈Cl₂•H₂O, two new minerals from Richelsdorf, Hesse, R. F. G. Neues Jahrbuch für Mineralogie - Monatshefte, 1985. 145-154

American Mineralogist (1988): 73: 194-195.

Hawthorne, F. C.; Sokolova, E. (2002) Simonkolleite, Zn5(OH)8Cl2(H2O), a decorated interrupted-sheet structure of the form [MΦ2]4. The Canadian Mineralogist, 40 (3). 939-946 doi:10.3749/gscanmin.40.3.939

(2007) Simonkolleite. Handbook of Mineralogy. Mineralogical Society of America

en.wikipedia.org (n.d.) https://en.wikipedia.org/wiki/Zinc_chloride_hydroxide_monohydrate

Localities for SimonkolleiteHide

Showing 14 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Belgium
Flanders Limburg Dilsen-Stokkem Rotem ⓘ Rotem slag locality ?
Wallonia Liège Plombières ⓘ Bleyberg zinc and lead smelter slag locality	Blaß et al. (1995)

Germany
Hesse Darmstadt Frankfurt ⓘ Heddernheim slag locality	Blessing et al. (1991)
Kassel Region Hersfeld-Rotenburg Nentershausen Süß Richelsdorf Smelter ⓘ Slag dumps (TL)	Weiß (1990)
Lower Saxony Goslar District Langelsheim Astfeld ⓘ Herzog Julius smelter slag locality	Schnorrer (1995) +1 other reference
North Rhine-Westphalia Arnsberg Hochsauerlandkreis Arnsberg Hüsten ⓘ "An der Seilbahn" slag locality	Weiß (1990)
Märkischer Kreis Iserlohn Letmathe Helmke quarry nature reserve ⓘ Genna zinc smelter slag locality	Bender et al. (1994) +1 other reference
Cologne Aachen Stolberg ⓘ Birkengang zinc smelter slag locality	Blaß et al. (1995)
ⓘ Münsterbusch zinc smelter slag locality	International Association of Collectors of Slag Minerals (3) +1 other reference
Euskirchen Kall ⓘ Copper smelter slag locality	Blaß et al. (1995)

Switzerland
Vaud Aigle Bex ⓘ Salt mine	Stalder et al. (1998)

UK
England Cornwall Crantock ⓘ The Gannel Smelter slag locality	Pirrie et al. (2000)

USA
Arizona Maricopa County Painted Rock Mountains Painted Rock Mining District Theba ⓘ Rowley Mine	RRUFF project
New Jersey Sussex County ⓘ ~~Franklin~~	King (n.d.)

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Simonkolleite

About SimonkolleiteHide

Unique IdentifiersHide

IMA Classification of SimonkolleiteHide

Classification of SimonkolleiteHide

Mineral SymbolsHide

Physical Properties of SimonkolleiteHide

Optical Data of SimonkolleiteHide

Chemistry of SimonkolleiteHide

Crystallography of SimonkolleiteHide

Crystal StructureHide

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Type Occurrence of SimonkolleiteHide

Synonyms of SimonkolleiteHide

Other Language Names for SimonkolleiteHide

Common AssociatesHide

Related Minerals - Strunz-mindat GroupingHide

Other InformationHide

Internet Links for SimonkolleiteHide

References for SimonkolleiteHide

Localities for SimonkolleiteHide

Locality ListHide

Related Minerals - Strunz-mindat Grouping Hide