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Rosenhahnite

A valid IMA mineral species
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About RosenhahniteHide

Formula:
HCa3[Si3O9(OH)]
Colour:
White, beige, colourless, yellow-brown
Lustre:
Vitreous
Hardness:
4½ - 5
Specific Gravity:
2.89
Crystal System:
Triclinic
Name:
Named by Adolf Pabst, E.B. Gross, and J.T Alfors in 1967 in honor of Leo Rosenhahn (1903/4 - 1991), amateur mineralogist from San Anselmo, California, USA.
This page provides mineralogical data about Rosenhahnite.


Unique IdentifiersHide

Mindat ID:
3455
Long-form identifier:
mindat:1:1:3455:1

IMA Classification of RosenhahniteHide

Classification of RosenhahniteHide

9.BJ.10

9 : SILICATES (Germanates)
B : Sorosilicates
J : Sorosilicates with Si3O10, Si4O11, etc. anions; cations in octahedral [6] and greater coordination
57.1.4.1

57 : SOROSILICATES Si3O10 Groups and Larger Noncyclic Groups
1 : Insular Si3O10 and Larger Noncyclic Groups with [Si3O10] groups
14.5.9

14 : Silicates not Containing Aluminum
5 : Silicates of Ca

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
RhhIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of RosenhahniteHide

Vitreous
Transparency:
Transparent, Translucent
Colour:
White, beige, colourless, yellow-brown
Streak:
White
Hardness:
4½ - 5 on Mohs scale
Cleavage:
Perfect
Perfect on {001}, good on {100} and {010}.
Density:
2.89(2) g/cm3 (Measured)    2.905 g/cm3 (Calculated)
Comment:
Berman balance. Calculated value is for the ideal formula.

Optical Data of RosenhahniteHide

Type:
Biaxial (-)
RI values:
nα = 1.624 - 1.625 nβ = 1.640 - 1.641 nγ = 1.646 - 1.647
2V:
Measured: 64° (4), Calculated: 64°
Max. Birefringence:
δ = 0.022
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r < v

Chemistry of RosenhahniteHide

Mindat Formula:
HCa3[Si3O9(OH)]
Element Weights:
Element% weight
O43.655 %
Ca32.806 %
Si22.990 %
H0.550 %

Calculated from ideal end-member formula.
Common Impurities:
B,Al,Fe,Mn,Mg,Sr,Ba,Na,H2O

Crystallography of RosenhahniteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 6.955(2) Å, b = 9.484(2) Å, c = 6.812(2) Å
α = 108.64(2)°, β = 94.84(2)°, γ = 95.89(2)°
Ratio:
a:b:c = 0.733 : 1 : 0.718
Unit Cell V:
420.23 ų (Calculated from Unit Cell)
Z:
2
Morphology:
The type crystals are tabular to lathlike with {010} by far the most prominent form. Other forms observed include {001}, {100}, {140}, {110}, {210}, {110}, {210}, {032}, {021}, {031}, {101}, {122}.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000580RosenhahniteWan C, Ghose S, Gibbs G V (1977) Rosenhahnite, Ca3Si3O8(OH)2: crystal structure and the stereochemical configuration of the hydroxylated trisilicate group, [Si3O8(OH)2] American Mineralogist 62 503-51219770293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.20 Å(100)
2.965 Å(90)
3.043 Å(60)
2.775 Å(40)
3.36 Å(30)
2.659 Å(30)
1.886 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47)

Type Occurrence of RosenhahniteHide

General Appearance of Type Material:
Narrow veinlets less than 3 cm thick with small pockets.
Place of Conservation of Type Material:
California Division of Mines & Geology, San Francisco, California, USA.
National Museum of Natural History (Smithsonian), Washington, D.C., USA 120124, 134562.
The Natural History Museum, London England, 1976,392-393.
Geological Setting of Type Material:
Veins in brecciated, fine-grained diopside-garnet metasedimentary rock.
Associated Minerals at Type Locality:

Synonyms of RosenhahniteHide

Other Language Names for RosenhahniteHide

Related Minerals - Strunz-mindat GroupingHide

9.BJ.ArsenmedaiteMn2+6 As5+Si5O18(OH)Mon. 2/m
9.BJ.05OrientiteCa8Mn3+10(SiO4)3(Si3O10)3(OH)10 · 4H2O Orth. mmm(2/m2/m2/m)
9.BJ.15TrabzoniteCa4(Si3O9)(OH)2Orth. mm2 : Ama2
9.BJ.20Thalénite-(Y)Y3Si3O10FMon. 2/m : P21/b
9.BJ.25TiragalloiteMn2+4As5+Si3O12(OH)Mon. 2/m
9.BJ.30MedaiteMn2+6V5+Si5O18(OH)Mon. 2/m
9.BJ.35StrontioruiziteSr2Mn3+2Si4O11(OH)4 · 2H2OMon. 2 : B2
9.BJ.35RuiziteCa2Mn3+2[Si4O11(OH)2](OH)2 · 2H2OMon. 2
9.BJ.35Taniajacoite SrCaMn3+2Si4O11(OH)4 · 2H2OTric. 1
9.BJ.40Ardennite-(As)Mn2+4Al4(AlMg)(AsO4)(SiO4)2(Si3O10)(OH)6Orth. mmm(2/m2/m2/m)
9.BJ.40KannaniteCa4Al4(AlMg)(VO4)(SiO4)2(Si3O10)(OH)6Orth. mmm(2/m2/m2/m) : Pmmn
9.BJ.40AlpeiteCa4Mn3+2Al2(Mn3+Mg)(SiO4)2(Si3O10)(V5+O4)(OH)6Orth. mmm(2/m2/m2/m) : Pmmn
9.BJ.40Ardennite-(V)Mn2+4Al4(AlMg)(VO4)(SiO4)2(Si3O10)(OH)6Orth. mmm(2/m2/m2/m) : Pmmn
9.BJ.45KilchoaniteCa6(SiO4)(Si3O10)Orth. mmm(2/m2/m2/m)
9.BJ.50Prismatine(◻,Fe,Mg)(Mg,Al,Fe)5Al4Si2(Si,Al)2(B,Si,Al)(O,OH,F)22Orth. mmm(2/m2/m2/m) : Cmcm
9.BJ.50KornerupineMg3Al6(Si,Al,B)5O21(OH)Orth. mmm(2/m2/m2/m) : Cmcm
9.BJ.55ZunyiteAl13Si5O20(OH,F)18ClIso. 43m : F43m
9.BJ.60HubeiteCa2Mn2+Fe3+Si4O12(OH) · 2H2OTric. 1 : P1
9.BJ.65Cassagnaite(Ca,Mn2+)4(Fe3+,Mn3+,Al)4(V3+,Mg,Al)2(Si3O10)(SiO4)2(OH,O)8Orth. mmm(2/m2/m2/m) : Cmcm
9.BJ.70PavlovskyiteCa8(SiO4)2(Si3O10)Orth. mmm(2/m2/m2/m) : Pbcn

Fluorescence of RosenhahniteHide

Fluoresces light orangish pink under LW UV.

Other InformationHide

Notes:
Slightly soluble in concentrated acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for RosenhahniteHide

References for RosenhahniteHide

Localities for RosenhahniteHide

Showing 9 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Tasmania
    • Huon Valley municipality
R Bottrill unpub. Data
Czech Republic
 
  • Vysočina Region
    • Havlíčkův Brod District
      • Krucemburk
Marek V.: Rosenhahnite from Staré Ransko (East Bohemia)
Japan
 
  • Hiroshima Prefecture
    • Shoubara City
Henmi (1982)
  • Kochi Prefecture
    • Kochi City
      • Engyouji (Engyoji)
Anthony et al. (2016)
      • Rendai
Mineralogical Journal Vol. 13 (1986)
New Zealand
 
  • Waikato Region
    • Waitomo District
      • Piopio
Leach et al. (1977) +1 other reference
Russia
 
  • Sverdlovsk Oblast
    • Asbest
Zadov +9 other references
USA (TL)
 
  • California
    • Mendocino County
      • Cloverdale area
        • Russian River
Pabst et al. (1967) +4 other references
  • North Carolina
    • Durham County
      • Durham
Kenny Gay message 15.09.2005 +2 other references
 
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