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Orientite

A valid IMA mineral species - grandfathered
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About OrientiteHide

07077970017271925728635.jpg
Seal of Oriente Province, Cuba
Formula:
Ca8Mn3+10(SiO4)3(Si3O10)3(OH)10 · 4H2O
Colour:
Light reddish brown, chocolate-brown
Lustre:
Resinous, Sub-Metallic, Dull
Hardness:
4 - 5
Specific Gravity:
3.05 - 3.33
Crystal System:
Orthorhombic
Name:
Named in 1921 by Donnel Foster Hewett and Earl Vincent Shannon for the type locality, the Oriente Province in Cuba. In 1976, Oriente Province was split up into 6 provinces. The type locality is now located in Santiago de Cuba Province.
This page provides mineralogical data about Orientite.


Unique IdentifiersHide

Mindat ID:
3017
Long-form identifier:
mindat:1:1:3017:1

Similar NamesHide

IMA Classification of OrientiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca8Mn3+10(SiO4)3(Si3O10)3(OH)10(H2O)4
First published:
1921

Classification of OrientiteHide

9.BJ.05

9 : SILICATES (Germanates)
B : Sorosilicates
J : Sorosilicates with Si3O10, Si4O11, etc. anions; cations in octahedral [6] and greater coordination
58.3.1.2

58 : SOROSILICATES Insular, Mixed, Single, and Larger Tetrahedral Groups
3 : Insular, Mixed, Single, and Larger Tetrahedral Groups with insular single and triple groups (n=1, 3)
14.18.22

14 : Silicates not Containing Aluminum
18 : Silicates of Mn and Na, K, Mg, Ca or Fe

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
OrnIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of OrientiteHide

Resinous, Sub-Metallic, Dull
Transparency:
Transparent, Translucent
Colour:
Light reddish brown, chocolate-brown
Streak:
Brown
Hardness:
4 - 5 on Mohs scale
Tenacity:
Brittle
Cleavage:
Imperfect/Fair
Perfect to imperfect on {001}
may be parting
Density:
3.05 - 3.33 g/cm3 (Measured)    3.48 g/cm3 (Calculated)

Optical Data of OrientiteHide

Type:
Biaxial (+)
RI values:
nα = 1.756 - 1.765 nβ = 1.777 - 1.79 nγ = 1.794 - 1.81
2V:
Measured: 67° to 83°, Calculated: 90°
Max. Birefringence:
δ = 0.038 - 0.045
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
relatively strong
Pleochroism:
Visible
Comments:
X = red-brown to brownish yellow; Y = yellow to reddish brown; Z = brownish yellow to deep brownish red

Chemistry of OrientiteHide

Mindat Formula:
Ca8Mn3+10(SiO4)3(Si3O10)3(OH)10 · 4H2O
Element Weights:
Element% weight
O42.240 %
Mn25.900 %
Si15.889 %
Ca15.116 %
H0.855 %

Calculated from ideal end-member formula.
O
Mn
Si
Ca
H
Common Impurities:
Al,Fe,V,Cu,Mg,K,H2O,S

Crystallography of OrientiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Cell Parameters:
a = 9.074(4) Å, b = 6.121(2) Å, c = 19.130(7) Å
Ratio:
a:b:c = 1.482 : 1 : 3.125
Unit Cell V:
1,062.52 ų (Calculated from Unit Cell)
Z:
4
Comment:
Space group: Ccmm.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000965OrientiteMoore P B, Shen J, Araki T (1985) Crystal chemistry of the (M2)3+ phi2 sheet: Structural principles and crystal structures of ruizite, macfallite and orientite American Mineralogist 70 171-1811985Lake Manganese, Copper Harbor, Keweenaw County, Michigan, USA0293
0001007OrientiteMellini M, Merlino S, Pasero M (1986) X-ray and HRTEM structure analysis of orientite American Mineralogist 71 176-18719860293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.448 Å(100)
4.740 Å(100)
3.026 Å(45)
4.070 Å(35)
3.270 Å(30)
4.509 Å(25)
4.388 Å(15)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
22 : Hydration and low-? subsurface aqueous alteration (see also #23)
High-? alteration and/or metamorphism
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits

Type Occurrence of OrientiteHide

Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 93819.
The Natural History Museum, London, England, 1923,1029.

Other Language Names for OrientiteHide

Dutch:Orientiet
German:Orientit
Simplified Chinese:锰柱石
Spanish:Orientita

Common AssociatesHide

Associations Based on Photo Data:
19 photos of Orientite associated with MacfalliteCa2Mn3+3(SiO4)(Si2O7)(OH)3
10 photos of Orientite associated with CalciteCaCO3
4 photos of Orientite associated with QuartzSiO2
3 photos of Orientite associated with BrauniteMn2+Mn3+6(SiO4)O8
3 photos of Orientite associated with Hydroxyapophyllite-(K)KCa4(Si8O20)(OH,F) · 8H2O
3 photos of Orientite associated with Cerchiaraite-(Mn)Ba4Mn3+4(Si4O12)O2(OH)4Cl2[Si2O3(OH)4]
3 photos of Orientite associated with NamansiliteNaMn3+Si2O6
3 photos of Orientite associated with NeltneriteCaMn3+6(SiO4)O8
2 photos of Orientite associated with Fluorapophyllite-(K)KCa4(Si8O20)(F,OH) · 8H2O
1 photo of Orientite associated with PectoliteNaCa2Si3O8(OH)

Related Minerals - Strunz-mindat GroupingHide

9.BJ.ArsenmedaiteMn2+6 As5+Si5O18(OH)Mon. 2/m
9.BJ.10RosenhahniteHCa3[Si3O9(OH)]Tric. 1 : P1
9.BJ.15TrabzoniteCa4(Si3O9)(OH)2Orth. mm2 : Ama2
9.BJ.20Thalénite-(Y)Y3Si3O10FMon. 2/m : P21/b
9.BJ.25TiragalloiteMn2+4As5+Si3O12(OH)Mon. 2/m
9.BJ.30MedaiteMn2+6V5+Si5O18(OH)Mon. 2/m
9.BJ.35StrontioruiziteSr2Mn3+2Si4O11(OH)4 · 2H2OMon. 2 : B2
9.BJ.35RuiziteCa2Mn3+2[Si4O11(OH)2](OH)2 · 2H2OMon. 2
9.BJ.35Taniajacoite SrCaMn3+2Si4O11(OH)4 · 2H2OTric. 1
9.BJ.40Ardennite-(As)Mn2+4Al4(AlMg)(AsO4)(SiO4)2(Si3O10)(OH)6Orth. mmm(2/m2/m2/m)
9.BJ.40KannaniteCa4Al4(AlMg)(VO4)(SiO4)2(Si3O10)(OH)6Orth. mmm(2/m2/m2/m) : Pmmn
9.BJ.40AlpeiteCa4Mn3+2Al2(Mn3+Mg)(SiO4)2(Si3O10)(V5+O4)(OH)6Orth. mmm(2/m2/m2/m) : Pmmn
9.BJ.40Ardennite-(V)Mn2+4Al4(AlMg)(VO4)(SiO4)2(Si3O10)(OH)6Orth. mmm(2/m2/m2/m) : Pmmn
9.BJ.45KilchoaniteCa6(SiO4)(Si3O10)Orth. mmm(2/m2/m2/m)
9.BJ.50Prismatine(◻,Fe,Mg)(Mg,Al,Fe)5Al4Si2(Si,Al)2(B,Si,Al)(O,OH,F)22Orth. mmm(2/m2/m2/m) : Cmcm
9.BJ.50KornerupineMg3Al6(Si,Al,B)5O21(OH)Orth. mmm(2/m2/m2/m) : Cmcm
9.BJ.55ZunyiteAl13Si5O20(OH,F)18ClIso. 43m : F43m
9.BJ.60HubeiteCa2Mn2+Fe3+Si4O12(OH) · 2H2OTric. 1 : P1
9.BJ.65Cassagnaite(Ca,Mn2+)4(Fe3+,Mn3+,Al)4(V3+,Mg,Al)2(Si3O10)(SiO4)2(OH,O)8Orth. mmm(2/m2/m2/m) : Cmcm
9.BJ.70PavlovskyiteCa8(SiO4)2(Si3O10)Orth. mmm(2/m2/m2/m) : Pbcn

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for OrientiteHide

References for OrientiteHide

Localities for OrientiteHide

Showing 12 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
China
 
  • Fujian
    • Longyan
      • Liancheng Co.
        • Liancheng Mn deposit
Nanlai Zheng et al. (1986)
Cuba (TL)
 
  • Santiago de Cuba Province
AM 70 (1985) +1 other reference
      • Bueycito
King (n.d.)
Iran
 
  • Kurdistan Province
    • Divandarreh County
Moinevaziri (2019)
Italy
 
  • Liguria
    • La Spezia Province
      • Borghetto di Vara
Palenzona (1990) +1 other reference
Japan
 
  • Hokkaidō Prefecture
    • Okhotsk Subprefecture
      • Kitami City
Miyajima et al. (1994)
Mexico
 
  • Chihuahua
    • Saucillo Municipality
      • Naica
Gazquez et al. (1)
Serbia
 
  • Central Serbia
    • Bor District
      • Bor
Pačevski et al. (2016) +1 other reference
South Africa
 
  • Northern Cape
    • John Taolo Gaetsewe District Municipality
      • Joe Morolong Local Municipality
Cairncross et al. (1995)
USA
 
  • Michigan
    • Keweenaw County
      • Grant Township
        • Copper Harbor
Morris (1983)
  • New York
    • Lewis County
      • Diana Township
Michael Hawkins
 
and/or  
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