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Arhbarite

A valid IMA mineral species
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About ArhbariteHide

Formula:
Cu2Mg(AsO4)(OH)3
Colour:
Dark blue to medium blue
Lustre:
Sub-Vitreous, Waxy
Specific Gravity:
3.71
Crystal System:
Triclinic
Name:
Named by K. Schmetzer, Gerd Tremmel, and Olaf Medenbach in 1982 after the type locality, the Arhbar mine, Bou Azzer, Morocco.
This page provides mineralogical data about Arhbarite.


Unique IdentifiersHide

Mindat ID:
333
Long-form identifier:
mindat:1:1:333:1

IMA Classification of ArhbariteHide

Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
Cu2+2MgAs5+O4(OH)3
First published:
19982
Approval history:
Redefined IMA 2002-B (as triclinic): Krause et al (2003); Grice et al. (2003).

Classification of ArhbariteHide

8.BE.25

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
E : With only medium-sized cations, (OH, etc.):RO4 > 2:1
42.6.5.2

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
6 : A2(XO4)Zq·xH2O
20.1.10

20 : Arsenates (also arsenates with phosphate, but without other anions)
1 : Arsenates of Cu

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
ArhIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ArhbariteHide

Sub-Vitreous, Waxy
Transparency:
Translucent
Colour:
Dark blue to medium blue
Streak:
Light blue, sky-blue
Tenacity:
Brittle
Cleavage:
None Observed
Density:
3.71 g/cm3 (Measured)    3.99(4) g/cm3 (Calculated)
Comment:
Dcalc 3.96, Moroccan sample, and 4.03, Chilean sample.

Optical Data of ArhbariteHide

Type:
Biaxial
RI values:
nα = 1.720 nγ = 1.740
2V:
Measured: 90°
Birefringence:
0.020
Max. Birefringence:
δ = 0.020
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
relatively strong
Optical Extinction:
45° to fiber axis.
Pleochroism:
Visible
Comments:
X' = turquoise-blue; Z' = dark turquoise-blue.

Chemistry of ArhbariteHide

Mindat Formula:
Cu2Mg(AsO4)(OH)3
Element Weights:
Element% weight
Cu37.234 %
O32.811 %
As21.949 %
Mg7.121 %
H0.886 %

Calculated from ideal end-member formula.
Cu
O
As
Mg
H

Crystallography of ArhbariteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pedial
Space Group:
P1
Setting:
P1
Cell Parameters:
a = 5.315 Å, b = 5.978 Å, c = 5.03 Å
α = 113.58°, β = 97.14°, γ = 89.31°
Ratio:
a:b:c = 0.889 : 1 : 0.841
Unit Cell V:
145.21 ų (Calculated from Unit Cell)
Morphology:
Found in botryoidal clusters of tightly radially grown crystals.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.57 Å(100)
4.51 Å(90)
3.72 Å(60)
3.25 Å(40)
2.63 Å(40)
2.60 Å(50)
2.47 Å(50)
Comments:
ICDD 35-562.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])
Geological Setting:
Oxidized zone of a hydrothermal polymetallic ore deposit.

Type Occurrence of ArhbariteHide

General Appearance of Type Material:
Blue, spherulitic aggregates on massive dolomite.
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 160383.
Geological Setting of Type Material:
Oxidized zone of a hydrothermal polymetallic ore deposit.
Associated Minerals at Type Locality:

Other Language Names for ArhbariteHide

Dutch:Arhbariet
French:Arhbarite
German:Arhbarit
Norwegian:Arhbaritt
Spanish:Arhbarita

Common AssociatesHide

Associations Based on Photo Data:
38 photos of Arhbarite associated with ConichalciteCaCu(AsO4)(OH)
17 photos of Arhbarite associated with GuanacoiteMgCu2Mg2(AsO4)2(OH)4(H2O)4
14 photos of Arhbarite associated with GilmariteCu3(AsO4)(OH)3
7 photos of Arhbarite associated with EnargiteCu3AsS4
3 photos of Arhbarite associated with MalachiteCu2(CO3)(OH)2
1 photo of Arhbarite associated with DolomiteCaMg(CO3)2
1 photo of Arhbarite associated with CalciteCaCO3
1 photo of Arhbarite associated with QuartzSiO2

Related Minerals - Strunz-mindat GroupingHide

8.BE.05AugeliteAl2(PO4)(OH)3Mon. 2/m : B2/m
8.BE.10GrattarolaiteFe3+3(PO4)O3Trig. 3m : R3m
8.BE.15CornetiteCu3(PO4)(OH)3Orth. mmm(2/m2/m2/m) : Pbca
8.BE.20ClinoclaseCu3(AsO4)(OH)3Mon. 2/m : P21/b
8.BE.25GilmariteCu3(AsO4)(OH)3Tric. 1 : P1
8.BE.30FlinkiteMn2+2Mn3+(AsO4)(OH)4Orth. mmm(2/m2/m2/m) : Pnma
8.BE.30ArganditeMn7(VO4)2(OH)8Mon. 2/m : P21/m
8.BE.30RaadeiteMg7(PO4)2(OH)8Mon. 2/m
8.BE.30AllactiteMn2+7(AsO4)2(OH)8Mon. 2/m : P21/b
8.BE.35'Mineral E (of Dunn, et. al., 1982)'Orth. mmm(2/m2/m2/m)
8.BE.35Chlorophoenicite(Mn,Mg)3Zn2(AsO4)(OH,O)6Mon. 2/m : B2/m
8.BE.35Magnesiochlorophoenicite(Mg,Mn)3Zn2(AsO4)(OH,O)6Mon. 2/m : B2/m
8.BE.40Gerdtremmelite(Zn,Fe)(Al,Fe)2(AsO4)(OH)5Tric.
8.BE.45DixeniteCuMn2+14Fe2+(SiO4)2(As5+O4)(As3+O3)5(OH)6Trig. 3 : R3
8.BE.45McgoverniteMn19Zn3(AsO4)3(AsO3)(SiO4)3(OH)21Trig. 3m : R3c
8.BE.45Hematolite(Mn,Mg,Al,Fe3+)15(As5+O4)2(As3+O3)(OH)23Trig. 3 : R3
8.BE.45Turtmannite(Mn,Mg)22.5Mg3-3x((V5+,As5+)O4)3(As3+O3)x(SiO4)3O5-5x(OH)20+xTrig.
8.BE.45CarlfrancisiteMn2+3(Mn2+,Mg,Fe3+,Al)42[As3+O3]2(As5+O4)4[(Si,As5+)O4]6[(As5+,Si)O4]2(OH)42Trig. 3m : R3c
8.BE.45Arakiite(Zn,Mn2+)(Mn2+,Mg)12(Fe3+,Al)2(As5+O4)2(As3+O3)(OH)23Mon. m : Bb
8.BE.45KraissliteZn3(Mn,Mg)25(Fe3+,Al)(As3+O3)2[(Si,As5+)O4]10(OH)16Orth. 222 : C2221
8.BE.50SynadelphiteMn2+9(As5+O4)2(As3+O3)(OH)9 · 2H2OOrth. mmm(2/m2/m2/m) : Pnma
8.BE.55Holdenite(Mn2+,Mg)6Zn3(AsO4)2(SiO4)(OH)8Orth. mmm(2/m2/m2/m) : Ccca
8.BE.60KoliciteMn2+7Zn4(AsO4)2(SiO4)2(OH)8Orth. mmm(2/m2/m2/m) : Cmca
8.BE.65Sabelliite(Cu,Zn)2Zn(AsO4,SbO4)(OH)3Trig. 3 : P3
8.BE.70JarosewichiteMn2+3Mn3+(AsO4)(OH)6Orth. 222
8.BE.75TheisiteCu5Zn5(AsO4,SbO4)2(OH)14Orth.
8.BE.80CoparsiteCu4(AsO4,VO4)O2ClOrth. mmm(2/m2/m2/m) : Pbcm
8.BE.85WaterhouseiteMn2+7(PO4)2(OH)8Mon. 2/m : P21/b
8.BE.90VasilseverginiteCu9O4(AsO4)2(SO4)2Mon. 2/m

Fluorescence of ArhbariteHide

Not fluorescent.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ArhbariteHide

References for ArhbariteHide

Localities for ArhbariteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Chile
 
  • Antofagasta
    • Antofagasta Province
      • Taltal
Färber et al. (1998) +1 other reference
Morocco (TL)
 
  • Drâa-Tafilalet Region
    • Zagora Province
      • Agdz Cercle
        • Tansifte Caïdat
          • Aghbar
Schmetzer et al. (1982) +1 other reference
 
and/or  
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