Rutile Group
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About Rutile Group
Formula:
M4+O2
Crystal System:
Tetragonal
Unique Identifiers
Mindat ID:
29330
Long-form identifier:
mindat:1:1:29330:5
Chemistry of Rutile Group
Mindat Formula:
M4+O2
Age distribution
Recorded ages:
Mesoarchean to Jurassic : 2974 ± 59 Ma to 156 ± 4 Ma - based on 56 recorded ages.
Sample ages:
| Sample ID | Recorded age | Geologic Time | Dating method |
|---|---|---|---|
| 1 | 156 ± 4 Ma | Jurassic | U-Pb |
| 2 | 498.03594 to 494.36406 Ma | Cambrian | U-Pb |
| 3 | 513.1776 to 510.8224 Ma | Cambrian Series 2 | U-Pb |
| 4 | 517.56468 to 513.23532 Ma | Cambrian Series 2 | U-Pb |
| 5 | 548.91696 to 547.28304 Ma | Ediacaran | U-Pb |
| 6 | 2098 ± 7 Ma | Rhyacian | Pb/Pb |
| 7 | 2217.5 Ma | Rhyacian | U-Pb |
| 8 | 2599 Ma | Neoarchean | Pb-Pb |
| 9 | 2630 Ma | Neoarchean | Pb-Pb |
| 10 | 2632 ± 3 Ma | Neoarchean | U-Pb |
| 11 | 2633 Ma | Neoarchean | Pb-Pb |
| 12 | 2635 Ma | Neoarchean | Pb-Pb |
| 13 | 2641 ± 4 Ma | Neoarchean | U-Pb |
| 14 | 2643 Ma | Neoarchean | Pb-Pb |
| 15 | 2652 Ma | Neoarchean | Pb-Pb |
| 16 | 2836 ± 26 Ma | Mesoarchean | |
| 17 | 2839 ± 16 Ma | Mesoarchean | Pb-Pb |
| 18 | 2877 ± 20 Ma | Mesoarchean | |
| 19 | 2886 ± 21 Ma | Mesoarchean | Pb-Pb |
| 20 | 2974 ± 59 Ma | Mesoarchean | Pb-Pb |
Sample references:
Chemical Analysis
Oxide wt%:
| 1 | 2 | 3 | |
|---|---|---|---|
| SnO | 91.67 % | ||
| Nb2O5 | 3.97 % | 21 % | 13 % |
| Ta2O5 | 4.36 % | 22 % | 41 % |
| TiO2 | 43 % | 28 % | |
| Fe2O3 | 13 % | 14 % | |
| SnO2 | 0.8 % | 0.2 % | |
| ZrO2 | 3.6 % | ||
| SrO2 | 0.1 % | ||
| Total: | 100 % | 99.8 % | 99.9 % |
Sample references:
Crystallography of Rutile Group
Crystal System:
Tetragonal
Class (H-M):
4/mmm(4/m2/m2/m) - Ditetragonal Dipyramidal
Morphology:
Crystals in this group are often elongated in [001] and also pyramidal. Striae are nearly always found parallel to [001].
Twinning:
Most members of the group are nearly always twinned on {101} and less often on {301}.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0010475 | Argutite | Rosales I, Juarez-Arellano E A, Magana C R, Bucio L, Orozco E (2007) Incorporation of vanadium(V) into the rutile-type phase of GeO2: the solid solution Ge0.74V0.21[box]0.05O2 Acta Crystallographica E63 i99-i101 | ![]() | 2007 | synthetic | 0 | 293 |
| 0014928 | Tripuhyite | Basso R, Cabella R, Lucchetti G, Marescotti P, Martinelli A (2003) Structural studies on synthetic and natural Fe-Sb-oxides of MO2 type Neues Jahrbuch fur Mineralogie, Monatshefte 2003 407-420 | 2003 | Djebel Nador, Algeria | 0 | 293 | |
| 0014927 | Tripuhyite | Basso R, Cabella R, Lucchetti G, Marescotti P, Martinelli A (2003) Structural studies on synthetic and natural Fe-Sb-oxides of MO2 type Neues Jahrbuch fur Mineralogie, Monatshefte 2003 407-420 | 2003 | Djebel Nador, Algeria | 0 | 293 | |
| 0014926 | Tripuhyite | Basso R, Cabella R, Lucchetti G, Marescotti P, Martinelli A (2003) Structural studies on synthetic and natural Fe-Sb-oxides of MO2 type This is the preferred structural model Neues Jahrbuch fur Mineralogie, Monatshefte 2003 407-420 | 2003 | Djebel Nador, Algeria | 0 | 293 | |
| 0014566 | Tripuhyite | Berlepsch P, Armbruster T, Brugger J, Criddle A J, Graeser S (2003) Tripuhyte, FeSbO4, revisited Mineralogical Magazine 67 31-46 | ![]() | 2003 | Falotta, Grisons, Switzerland | 0 | 293 |
| 0014565 | Tripuhyite | Berlepsch P, Armbruster T, Brugger J, Criddle A J, Graeser S (2003) Tripuhyte, FeSbO4, revisited Mineralogical Magazine 67 31-46 | ![]() | 2003 | Tripuhy, Minas Gerais, Brazil | 0 | 293 |
| 0019244 | Plattnerite | Bolzan A A, Fong C, Kennedy B J, Howard C J (1997) Structural studies of rutile-type metal dioxides Acta Crystallographica B53 373-380 | ![]() | 1997 | synthetic | 0 | 293 |
| 0019242 | Cassiterite | Bolzan A A, Fong C, Kennedy B J, Howard C J (1997) Structural studies of rutile-type metal dioxides Acta Crystallographica B53 373-380 | ![]() | 1997 | synthetic | 0 | 293 |
| 0019240 | Argutite | Bolzan A A, Fong C, Kennedy B J, Howard C J (1997) Structural studies of rutile-type metal dioxides Acta Crystallographica B53 373-380 | ![]() | 1997 | synthetic | 0 | 293 |
| 0019092 | Rutile | Howard C J, Sabine T M, Dickson F (1991) Structural and thermal parameters for rutile and anatase Acta Crystallographica B47 462-468 | ![]() | 1991 | synthetic | 0 | 293 |
| 0009716 | Plattnerite | D'Antonio P, Santoro A (1980) Powder neutron diffraction study of chemically prepared B-lead dioxide Acta Crystallographica B36 2394-2397 | ![]() | 1980 | synthetic | 0 | 293 |
| 0009405 | Argutite | Baur W H, Khan A A (1971) Rutile-type compounds. VI. SiO2, GeO2 and a comparison with other rutile-type structures Acta Crystallographica B27 2133-2139 | ![]() | 1971 | synthetic | 0 | 293 |
| 0020161 | Plattnerite | Grocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-177 | 2014 | Synthetic | 23.5 | 293 | |
| 0020162 | Plattnerite | Grocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-177 | 2014 | Synthetic | 29 | 293 | |
| 0020163 | Plattnerite | Grocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-177 | 2014 | Synthetic | 39 | 293 | |
| 0020164 | Plattnerite | Grocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-177 | 2014 | Synthetic | 62.7 | 293 | |
| 0020165 | Plattnerite | Grocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-177 | 2014 | Synthetic | 75.1 | 293 | |
| 0020166 | Plattnerite | Grocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-177 | 2014 | Synthetic | 93 | 293 | |
| 0020167 | Plattnerite | Grocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-177 | 2014 | Synthetic | 105 | 293 | |
| 0020168 | Plattnerite | Grocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-177 | 2014 | Synthetic | 120 | 293 | |
| 0020169 | Plattnerite | Grocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-177 | 2014 | Synthetic | 140 | 293 | |
| 0008431 | Argutite | Haines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582 | 2000 | 0 | 293 | ||
| 0005167 | Rutile | Meagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO2 polymorphs: Refinement of the crystal structure of rutile and brookite at high temperature Sample at 900 degrees C The Canadian Mineralogist 17 77-85 | ![]() | 1979 | 0 | 293 | |
| 0005166 | Rutile | Meagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO2 polymorphs: Refinement of the crystal structure of rutile and brookite at high temperature Sample at 600 degrees C The Canadian Mineralogist 17 77-85 | ![]() | 1979 | 0 | 293 | |
| 0005165 | Rutile | Meagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO2 polymorphs: Refinement of the crystal structure of rutile and brookite at high temperature Sample at 300 degrees C The Canadian Mineralogist 17 77-85 | ![]() | 1979 | 0 | 293 | |
| 0005164 | Rutile | Meagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO2 polymorphs: Refinement of the crystal structure of rutile and brookite at high temperature Sample at 25 degrees C The Canadian Mineralogist 17 77-85 | ![]() | 1979 | 0 | 293 | |
| 0009404 | Rutile | Baur W H, Khan A A (1971) Rutile-type compounds. VI. SiO2, GeO2 and a comparison with other rutile-type structures Acta Crystallographica B27 2133-2139 | ![]() | 1971 | 0 | 293 | |
| 0009416 | Plattnerite | Baur W H, Khan A A (1971) Rutile-type compounds. VI. SiO2, GeO2 and a comparison with other rutile-type structures Acta Crystallographica B27 2133-2139 | ![]() | 1971 | 0 | 293 | |
| 0009406 | Cassiterite | Baur W H, Khan A A (1971) Rutile-type compounds. VI. SiO2, GeO2 and a comparison with other rutile-type structures Acta Crystallographica B27 2133-2139 | ![]() | 1971 | 0 | 293 | |
| 0011762 | Rutile | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 239-444 | 1963 | 0 | 293 | ||
| 0011760 | Pyrolusite | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 239-444 | 1963 | 0 | 293 | ||
| 0011767 | Paratellurite | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 239-444 | 1963 | 0 | 293 | ||
| 0011761 | Cassiterite | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Rutile structure Crystal Structures 1 239-444 | 1963 | 0 | 293 | ||
| 0011759 | Argutite | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Rutile structure Crystal Structures 1 239-444 | 1963 | 0 | 293 | ||
| 0009161 | Rutile | Baur W H (1956) Uber die verfeinerung der kristallstrukturbestimmung einiger vertreter des rutiltyps: TiO2, SnO2, GeO2 und MgF2 Acta Crystallographica 9 515-520 | ![]() | 1956 | 0 | 293 | |
| 0009162 | Cassiterite | Baur W H (1956) Uber die verfeinerung der kristallstrukturbestimmung einiger vertreter des rutiltyps: TiO2, SnO2, GeO2 und MgF2 Acta Crystallographica 9 515-520 | ![]() | 1956 | 0 | 293 | |
| 0009164 | Argutite | Baur W H (1956) Uber die verfeinerung der kristallstrukturbestimmung einiger vertreter des rutiltyps: TiO2, SnO2, GeO2 und MgF2 Acta Crystallographica 9 515-520 | ![]() | 1956 | 0 | 293 | |
| 0017791 | Pyrolusite | Kondrashev Y D, Zaslavskii A I (1951) The structure of the modifications of manganese oxide Izvestiya Akademii Nauk SSSR 15 179-186 | 1951 | 0 | 293 | ||
| 0001737 | Rutile | Swope R J, Smyth J R, Larson A C (1995) H in rutile-type compounds: I. Single-crystal neutron and X-ray diffraction study of H in rutile American Mineralogist 80 448-453 | ![]() | 1995 | 0 | 300 | |
| 0001736 | Rutile | Swope R J, Smyth J R, Larson A C (1995) H in rutile-type compounds: I. Single-crystal neutron and X-ray diffraction study of H in rutile American Mineralogist 80 448-453 | ![]() | 1995 | 0 | 300 | |
| 0001735 | Rutile | Swope R J, Smyth J R, Larson A C (1995) H in rutile-type compounds: I. Single-crystal neutron and X-ray diffraction study of H in rutile American Mineralogist 80 448-453 | ![]() | 1995 | 0 | 24 | |
| 0008432 | Argutite | Haines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582 | 2000 | 4.2 | 293 | ||
| 0008433 | Argutite | Haines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582 | 2000 | 6.2 | 293 | ||
| 0008434 | Argutite | Haines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582 | 2000 | 8.9 | 293 | ||
| 0008435 | Argutite | Haines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582 | 2000 | 10.4 | 293 | ||
| 0008436 | Argutite | Haines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582 | 2000 | 10.5 | 293 | ||
| 0008437 | Argutite | Haines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582 | 2000 | 16.1 | 293 | ||
| 0008438 | Argutite | Haines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582 | 2000 | 20.3 | 293 | ||
| 0008439 | Argutite | Haines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582 | 2000 | 25 | 293 |
CIF Raw Data - click here to close
Relationship of Rutile Group to other Species
Rutile Group Members:
| Argutite | GeO2 | Tet. 4/mmm(4/m2/m2/m) : P42/mnm |
| Cassiterite | SnO2 | Tet. 4/mmm(4/m2/m2/m) : P42/mnm |
| Paratellurite | TeO2 | Tet. 422 |
| Plattnerite | PbO2 | Tet. 4/mmm(4/m2/m2/m) : P42/mnm |
| Pyrolusite | Mn4+O2 | Tet. 4/mmm(4/m2/m2/m) : P42/mnm |
| Rutile | TiO2 | Tet. 4/mmm(4/m2/m2/m) : P42/mnm |
| Tripuhyite | Fe3+Sb5+O4 | Tet. 4/mmm(4/m2/m2/m) : P42/mnm |
| 'UM2000-35-O:FeNbScTaTi' | (Sc,Fe2+,Fe3+,Mn)(Ti,Sn,Zr)1.5(Nb,Ta,W)1.33O8 |
Click on any node to view relationships. Formula-derived relationship network for the group members above. Use Find related species to add formula-neighbour species outside the current group view. Solid links show inferred chemical differences; dashed violet links show same-formula crystallographic differences. Hydration states are not treated as relationship changes. These relationships do not imply any real-world substitution reactions between these species.
Minerals structurally related to group:
| 'Sellaite' | MgF2 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Rutile Group in petrology
An essential component of rock names highlighted in red, an accessory component in rock names highlighted in green.
Internet Links for Rutile Group
mindat.org URL:
https://www.mindat.org/min-29330.html
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References for Rutile Group
Significant localities for Rutile Group
Showing 51 significant localities out of 19,322 recorded on mindat.org.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Australia | |
| [Cassiterite] Blissett (1959) +1 other reference |
| [Pyrolusite] BHP |
Austria | |
| [Rutile] |
Azerbaijan | |
| [Rutile] Pavel M. Kartashov (n.d.) +1 other reference |
Bolivia | |
| [Cassiterite] Cook (1977) +2 other references |
Brazil | |
| [Tripuhyite] Hussak et al. (1897) +1 other reference |
Canada | |
| [Rutile] Ty Balacko Specimens |
| [Pyrolusite] Sorrell (n.d.) +1 other reference |
Czech Republic | |
| [Cassiterite] Palache et al. (1951) |
France | |
| [Rutile] Le Roc'h P. () |
| [Argutite] Johan et al. (1983) +1 other reference |
Germany | |
| [Pyrolusite] |
Greece | |
| [Plattnerite] Rieck (n.d.) |
Italy | |
| [Plattnerite] |
| [Plattnerite] Maida (2002) |
| [Cassiterite] Alessandro Genazzani collection |
| [Rutile] Baldi M. |
| [Rutile] Biagioni C. (Alpi Apuane, Lucca) | |
| [Rutile] Biagioni C. (Alpi Apuane, Lucca) | |
Mexico | |
| [Paratellurite] Amer.Min. (1960) |
| [Paratellurite] Switzer et al. (1960) |
Peru | |
| [Rutile] Guido del Castillo (2004) |
Portugal | |
| [Cassiterite] 335-354 +8 other references | |
| [Pyrolusite] Nunes (n.d.) |
Russia | |
| [Rutile var: Ilmenorutile] Pekov (1998) |
| [Cassiterite] Evseev (1973) +3 other references |
Spain | |
| [Rutile] Calderón (1910) |
UK | |
| [Cassiterite] Henwood (1843) +4 other references |
| [Cassiterite] Dale Foster Photo & specimen |
| [Cassiterite] Henwood (1843) +2 other references |
| [Cassiterite] Henwood (1843) +2 other references |
| [Cassiterite] Reid et al. (1906) +2 other references |
| [Cassiterite] Rocks and Minerals 16 +1 other reference |
| [Cassiterite var: Wood Tin] Foster (n.d.) | |
| [Cassiterite, Cassiterite var: Wood Tin] Henwood (1843) +3 other references | |
| [Cassiterite] Collins (1871) +2 other references | |
| [Cassiterite] Darnley et al. (1965) |
| [Plattnerite] Haidinger W (1845) |
USA | |
| [Pyrolusite] Schairer (1931) |
| [Cassiterite] Scovil (1992) +1 other reference |
| [Rutile] Palache et al. (1951) |
| [Cassiterite] King et al. (1994) |
| [Rutile] K. Wood collection |
| [Rutile] Second Geological Survey of ... |
| [Rutile] Ref.1 |
| [Rutile] pg. 234 +1 other reference |
| [Rutile] Michael W. Kieron collection |
| [Rutile] Michael W. Kieron collection |
| [Cassiterite] Rocks & Min.:60:168. |
| [Rutile] Eric He's Collection +1 other reference |








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Diamantina, Minas Gerais, Brazil