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Rutile Group

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About Rutile GroupHide

Formula:
M4+O2
Crystal System:
Tetragonal
Tetragonal oxides of general formula M4+O2.

Sellaite is a structurally related magnesium fluoride.


Unique IdentifiersHide

Mindat ID:
29330
Long-form identifier:
mindat:1:1:29330:5

Chemistry of Rutile GroupHide

Age distributionHide

Recorded ages:
Mesoarchean to Jurassic : 2974 ± 59 Ma to 156 ± 4 Ma - based on 56 recorded ages.
Sample ages:
Sample IDRecorded ageGeologic TimeDating method
1156 ± 4 MaJurassicU-Pb
2498.03594 to 494.36406 MaCambrianU-Pb
3513.1776 to 510.8224 MaCambrian Series 2U-Pb
4517.56468 to 513.23532 MaCambrian Series 2U-Pb
5548.91696 to 547.28304 MaEdiacaranU-Pb
62098 ± 7 MaRhyacianPb/Pb
72217.5 MaRhyacianU-Pb
82599 MaNeoarcheanPb-Pb
92630 MaNeoarcheanPb-Pb
102632 ± 3 MaNeoarcheanU-Pb
112633 MaNeoarcheanPb-Pb
122635 MaNeoarcheanPb-Pb
132641 ± 4 MaNeoarcheanU-Pb
142643 MaNeoarcheanPb-Pb
152652 MaNeoarcheanPb-Pb
162836 ± 26 MaMesoarchean
172839 ± 16 MaMesoarcheanPb-Pb
182877 ± 20 MaMesoarchean
192886 ± 21 MaMesoarcheanPb-Pb
202974 ± 59 MaMesoarcheanPb-Pb
Sample references:
IDLocalityReferenceNotes
1Xianghualing Sn-polymetallic ore field, Linwu Co., Chenzhou, Hunan, China
2Musoshi Mine, Musoshi, Kipushi Territory, Haut-Katanga, DR Congo
3  "  "
4  "  "
5  "  "
6Ashanti gold belt, Ghana
7Cobalt-Gowganda region, Timiskaming District, Ontario, Canada
8Hemlo gold deposit, Bomby Township, Thunder Bay District, Ontario, Canada
9  "  "
10  "  "
11  "  "
12  "  "
13  "  "
14  "  "
15  "  "
16Wodgina Tantalite Mine, Wodgina, Abydos Station, Port Hedland Shire, Western Australia, Australia
17Moolyella pegmatite field, Marble Bar, East Pilbara Shire, Western Australia, Australia
18Tabba Tabba pegmatite, East Pilbara Shire, Western Australia, Australia
19  "  "
20  "  "

Chemical AnalysisHide

Crystallography of Rutile GroupHide

Crystal System:
Tetragonal
Class (H-M):
4/mmm(4/m2/m2/m) - Ditetragonal Dipyramidal
Morphology:
Crystals in this group are often elongated in [001] and also pyramidal. Striae are nearly always found parallel to [001].
Twinning:
Most members of the group are nearly always twinned on {101} and less often on {301}.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0010475ArgutiteRosales I, Juarez-Arellano E A, Magana C R, Bucio L, Orozco E (2007) Incorporation of vanadium(V) into the rutile-type phase of GeO2: the solid solution Ge0.74V0.21[box]0.05O2 Acta Crystallographica E63 i99-i1012007synthetic0293
0014928TripuhyiteBasso R, Cabella R, Lucchetti G, Marescotti P, Martinelli A (2003) Structural studies on synthetic and natural Fe-Sb-oxides of MO2 type Neues Jahrbuch fur Mineralogie, Monatshefte 2003 407-4202003Djebel Nador, Algeria0293
0014927TripuhyiteBasso R, Cabella R, Lucchetti G, Marescotti P, Martinelli A (2003) Structural studies on synthetic and natural Fe-Sb-oxides of MO2 type Neues Jahrbuch fur Mineralogie, Monatshefte 2003 407-4202003Djebel Nador, Algeria0293
0014926TripuhyiteBasso R, Cabella R, Lucchetti G, Marescotti P, Martinelli A (2003) Structural studies on synthetic and natural Fe-Sb-oxides of MO2 type This is the preferred structural model Neues Jahrbuch fur Mineralogie, Monatshefte 2003 407-4202003Djebel Nador, Algeria0293
0014566TripuhyiteBerlepsch P, Armbruster T, Brugger J, Criddle A J, Graeser S (2003) Tripuhyte, FeSbO4, revisited Mineralogical Magazine 67 31-462003Falotta, Grisons, Switzerland0293
0014565TripuhyiteBerlepsch P, Armbruster T, Brugger J, Criddle A J, Graeser S (2003) Tripuhyte, FeSbO4, revisited Mineralogical Magazine 67 31-462003Tripuhy, Minas Gerais, Brazil0293
0019244PlattneriteBolzan A A, Fong C, Kennedy B J, Howard C J (1997) Structural studies of rutile-type metal dioxides Acta Crystallographica B53 373-3801997synthetic0293
0019242CassiteriteBolzan A A, Fong C, Kennedy B J, Howard C J (1997) Structural studies of rutile-type metal dioxides Acta Crystallographica B53 373-3801997synthetic0293
0019240ArgutiteBolzan A A, Fong C, Kennedy B J, Howard C J (1997) Structural studies of rutile-type metal dioxides Acta Crystallographica B53 373-3801997synthetic0293
0019092RutileHoward C J, Sabine T M, Dickson F (1991) Structural and thermal parameters for rutile and anatase Acta Crystallographica B47 462-4681991synthetic0293
0009716PlattneriteD'Antonio P, Santoro A (1980) Powder neutron diffraction study of chemically prepared B-lead dioxide Acta Crystallographica B36 2394-23971980synthetic0293
0009405ArgutiteBaur W H, Khan A A (1971) Rutile-type compounds. VI. SiO2, GeO2 and a comparison with other rutile-type structures Acta Crystallographica B27 2133-21391971synthetic0293
0020161PlattneriteGrocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-1772014Synthetic23.5293
0020162PlattneriteGrocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-1772014Synthetic29293
0020163PlattneriteGrocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-1772014Synthetic39293
0020164PlattneriteGrocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-1772014Synthetic62.7293
0020165PlattneriteGrocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-1772014Synthetic75.1293
0020166PlattneriteGrocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-1772014Synthetic93293
0020167PlattneriteGrocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-1772014Synthetic105293
0020168PlattneriteGrocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-1772014Synthetic120293
0020169PlattneriteGrocholski B, Shim S H, Cottrell E, Prakapenka V B (2014) Crystal structure and compressibility of lead dioxide up to 140 GPa American Mineralogist 99 170-1772014Synthetic140293
0008431ArgutiteHaines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-58220000293
0005167RutileMeagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO2 polymorphs: Refinement of the crystal structure of rutile and brookite at high temperature Sample at 900 degrees C The Canadian Mineralogist 17 77-8519790293
0005166RutileMeagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO2 polymorphs: Refinement of the crystal structure of rutile and brookite at high temperature Sample at 600 degrees C The Canadian Mineralogist 17 77-8519790293
0005165RutileMeagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO2 polymorphs: Refinement of the crystal structure of rutile and brookite at high temperature Sample at 300 degrees C The Canadian Mineralogist 17 77-8519790293
0005164RutileMeagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO2 polymorphs: Refinement of the crystal structure of rutile and brookite at high temperature Sample at 25 degrees C The Canadian Mineralogist 17 77-8519790293
0009404RutileBaur W H, Khan A A (1971) Rutile-type compounds. VI. SiO2, GeO2 and a comparison with other rutile-type structures Acta Crystallographica B27 2133-213919710293
0009416PlattneriteBaur W H, Khan A A (1971) Rutile-type compounds. VI. SiO2, GeO2 and a comparison with other rutile-type structures Acta Crystallographica B27 2133-213919710293
0009406CassiteriteBaur W H, Khan A A (1971) Rutile-type compounds. VI. SiO2, GeO2 and a comparison with other rutile-type structures Acta Crystallographica B27 2133-213919710293
0011762RutileWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 239-44419630293
0011760PyrolusiteWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 239-44419630293
0011767ParatelluriteWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 239-44419630293
0011761CassiteriteWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Rutile structure Crystal Structures 1 239-44419630293
0011759ArgutiteWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Rutile structure Crystal Structures 1 239-44419630293
0009161RutileBaur W H (1956) Uber die verfeinerung der kristallstrukturbestimmung einiger vertreter des rutiltyps: TiO2, SnO2, GeO2 und MgF2 Acta Crystallographica 9 515-52019560293
0009162CassiteriteBaur W H (1956) Uber die verfeinerung der kristallstrukturbestimmung einiger vertreter des rutiltyps: TiO2, SnO2, GeO2 und MgF2 Acta Crystallographica 9 515-52019560293
0009164ArgutiteBaur W H (1956) Uber die verfeinerung der kristallstrukturbestimmung einiger vertreter des rutiltyps: TiO2, SnO2, GeO2 und MgF2 Acta Crystallographica 9 515-52019560293
0017791PyrolusiteKondrashev Y D, Zaslavskii A I (1951) The structure of the modifications of manganese oxide Izvestiya Akademii Nauk SSSR 15 179-18619510293
0001737RutileSwope R J, Smyth J R, Larson A C (1995) H in rutile-type compounds: I. Single-crystal neutron and X-ray diffraction study of H in rutile American Mineralogist 80 448-45319950300
0001736RutileSwope R J, Smyth J R, Larson A C (1995) H in rutile-type compounds: I. Single-crystal neutron and X-ray diffraction study of H in rutile American Mineralogist 80 448-45319950300
0001735RutileSwope R J, Smyth J R, Larson A C (1995) H in rutile-type compounds: I. Single-crystal neutron and X-ray diffraction study of H in rutile American Mineralogist 80 448-4531995024
0008432ArgutiteHaines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-58220004.2293
0008433ArgutiteHaines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-58220006.2293
0008434ArgutiteHaines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-58220008.9293
0008435ArgutiteHaines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582200010.4293
0008436ArgutiteHaines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582200010.5293
0008437ArgutiteHaines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582200016.1293
0008438ArgutiteHaines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582200020.3293
0008439ArgutiteHaines J, Leger J M, Chateau C, Pereira A S (2000) Structural evolution of rutile-type and CaCl2-type germanium dioxide at high pressure Physics and Chemistry of Minerals 27 575-582200025293
CIF Raw Data - click here to close

Relationship of Rutile Group to other SpeciesHide

Rutile Group Members:
Argutite GeO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
Cassiterite SnO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
Paratellurite TeO2Tet. 422
Plattnerite PbO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
Pyrolusite Mn4+O2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
Rutile TiO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
Tripuhyite Fe3+Sb5+O4Tet. 4/mmm(4/m2/m2/m) : P42/mnm
'UM2000-35-O:FeNbScTaTi' (Sc,Fe2+,Fe3+,Mn)(Ti,Sn,Zr)1.5(Nb,Ta,W)1.33O8
Click on any node to view relationships. Formula-derived relationship network for the group members above. Use Find related species to add formula-neighbour species outside the current group view. Solid links show inferred chemical differences; dashed violet links show same-formula crystallographic differences. Hydration states are not treated as relationship changes. These relationships do not imply any real-world substitution reactions between these species.
Minerals structurally related to group:

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Rutile Group in petrologyHide

Internet Links for Rutile GroupHide

References for Rutile GroupHide

Significant localities for Rutile GroupHide

Showing 51 significant localities out of 19,322 recorded on mindat.org.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Tasmania
    • Northern Midlands municipality
      • Rossarden mining district
[Cassiterite] Blissett (1959) +1 other reference
  • Western Australia
    • East Pilbara Shire
      • Weeli Wolli Creek Area
        • Mining Area C
[Pyrolusite] BHP
Austria
 
  • Salzburg
    • St. Johann im Pongau District
      • Bad Gastein
[Rutile]
Azerbaijan
 
  • Nakhchivan Autonomous Republic
    • Ordubad District
[Rutile] Pavel M. Kartashov (n.d.) +1 other reference
Bolivia
 
  • La Paz
    • Loayza Province
[Cassiterite] Cook (1977) +2 other references
Brazil
 
  • Minas Gerais
    • Ouro Preto
[Tripuhyite] Hussak et al. (1897) +1 other reference
Canada
 
  • British Columbia
    • New Westminster Mining Division
      • Jones Lake Power Station
[Rutile] Ty Balacko Specimens
  • Nova Scotia
    • Hants Co.
[Pyrolusite] Sorrell (n.d.) +1 other reference
Czech Republic
 
  • Karlovy Vary Region
    • Sokolov District
[Cassiterite] Palache et al. (1951)
France
 
  • Brittany
    • Morbihan
      • Pontivy
        • Plumelin
[Rutile] Le Roc'h P. ()
  • Occitanie
    • Haute-Garonne
      • Saint-Gaudens
        • Argut-Dessous
[Argutite] Johan et al. (1983) +1 other reference
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Schwarzwald-Baar-Kreis
        • Triberg im Schwarzwald
          • Gremmelsbach
[Pyrolusite]
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Agios Konstantinos (Kamariza)
[Plattnerite] Rieck (n.d.)
Italy
 
  • Lombardy
    • Bergamo Province
      • Oltre il Colle
        • Vedra Valley
          • Zorzone
[Plattnerite]
      • Parre
[Plattnerite] Maida (2002)
  • Tuscany
    • Livorno Province
      • Campo nell'Elba
        • San Piero in Campo
[Cassiterite] Alessandro Genazzani collection
    • Lucca Province
      • Pietrasanta
        • Valdicastello Carducci
[Rutile] Baldi M.
[Rutile] Biagioni C. (Alpi Apuane, Lucca)
[Rutile] Biagioni C. (Alpi Apuane, Lucca)
Mexico
 
  • Sonora
    • Cananea Municipality
      • Cananea
[Paratellurite] Amer.Min. (1960)
    • Moctezuma Municipality
      • Moctezuma
[Paratellurite] Switzer et al. (1960)
Peru
 
  • Tumbes
[Rutile] Guido del Castillo (2004)
Portugal
 
[Cassiterite] 335-354 +8 other references
  • Setúbal
    • Santiago do Cacém
      • Cercal do Alentejo
[Pyrolusite] Nunes (n.d.)
Russia
 
  • Chelyabinsk Oblast
    • Ilmen Mountains
[Rutile var: Ilmenorutile] Pekov (1998)
  • Chukotka Autonomous Okrug
    • Iultinsky District
      • Iultinsky Mining Complex
[Cassiterite] Evseev (1973) +3 other references
Spain
 
  • Community of Madrid
    • Horcajuelo de la Sierra
[Rutile] Calderón (1910)
UK
 
  • England
    • Cornwall
      • Camborne
[Cassiterite] Henwood (1843) +4 other references
        • Troon
          • Grenville United Mines
[Cassiterite] Dale Foster Photo & specimen
      • Chacewater
[Cassiterite] Henwood (1843) +2 other references
      • Gwennap
        • St Day United Mines (Poldice Mines)
[Cassiterite] Henwood (1843) +2 other references
      • Perranzabuloe
        • Perranporth
          • Cligga Head
[Cassiterite] Reid et al. (1906) +2 other references
      • St Agnes
        • St Agnes Consols (Polberro Consols)
[Cassiterite] Rocks and Minerals 16 +1 other reference
[Cassiterite var: Wood Tin] Foster (n.d.)
[Cassiterite, Cassiterite var: Wood Tin] Henwood (1843) +3 other references
[Cassiterite] Collins (1871) +2 other references
      • St Just
        • Pendeen
[Cassiterite] Darnley et al. (1965)
  • Scotland
    • South Lanarkshire
[Plattnerite] Haidinger W (1845)
USA
 
  • Connecticut
    • Litchfield County
      • Salisbury
[Pyrolusite] Schairer (1931)
    • Middlesex County
      • Haddam
        • Haddam Neck
[Cassiterite] Scovil (1992) +1 other reference
  • Georgia
    • Lincoln County
[Rutile] Palache et al. (1951)
  • Maine
    • Oxford County
      • Buckfield
[Cassiterite] King et al. (1994)
  • North Carolina
    • Catawba County
      • Hickory
[Rutile] K. Wood collection
  • Pennsylvania
    • Chester County
      • Sadsbury Township
[Rutile] Second Geological Survey of ...
    • Lancaster County
[Rutile] Ref.1
    • Philadelphia County
      • Hestonville
[Rutile] pg. 234 +1 other reference
  • Rhode Island
    • Newport County
      • Tiverton
[Rutile] Michael W. Kieron collection
    • Providence County
      • North Smithfield
[Rutile] Michael W. Kieron collection
  • Virginia
    • Powhatan County
      • Flat Rock
[Cassiterite] Rocks & Min.:60:168.
  • Washington
    • King County
      • Snoqualmie Mining District
        • Hansen Creek area
[Rutile] Eric He's Collection +1 other reference
 
and/or  
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