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Wickenburgite

A valid IMA mineral species
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About WickenburgiteHide

01179070017271927809272.jpg
Wickenburg, Arizona, USA
Formula:
CaPb3Al2Si10O24(OH)6
Colour:
Colorless, white, pink
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
3.85
Crystal System:
Trigonal
Name:
Named after the town of Wickenburg, Arizona, USA, near the discovery locality - the Potter-Cramer claim.
Monteregianite-(Y)-Wickenburgite Series (as such, probably belongs to rhodesite group). Chemically similar to maricopaite and 'UM1985-25-SiO:AlCaMgPb'.


Unique IdentifiersHide

Mindat ID:
4282
Long-form identifier:
mindat:1:1:4282:2

IMA Classification of WickenburgiteHide

Approved
IMA Formula:
Pb2+3CaAl2Si10O27·4H2O
Approval year:
1968
First published:
1968

Classification of WickenburgiteHide

9.EG.55

9 : SILICATES (Germanates)
E : Phyllosilicates
G : Double nets with 6-membered and larger rings
Dana 7th ed.:
74.2.1.1
74.2.1.1

74 : PHYLLOSILICATES Modulated Layers
2 : Modulated Layers
16.14.14

16 : Silicates Containing Aluminum and other Metals
14 : Aluminosilicates of Ti, Zr, Sn and Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
WbuIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of WickenburgiteHide

Vitreous
Transparency:
Transparent
Colour:
Colorless, white, pink
Streak:
White
Hardness:
Tenacity:
Brittle
Cleavage:
Distinct/Good
Distinct on the {0001}
Density:
3.85 g/cm3 (Measured)    3.84 g/cm3 (Calculated)

Optical Data of WickenburgiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.6918 nε = 1.648
Max. Birefringence:
δ = 0.044
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of WickenburgiteHide

Mindat Formula:
CaPb3Al2Si10O24(OH)6
Element Weights:
Element% weight
Pb41.928 %
O32.376 %
Si18.944 %
Al3.640 %
Ca2.703 %
H0.408 %

Calculated from ideal end-member formula.
Pb
O
Si
Al
Ca
H

Crystallography of WickenburgiteHide

Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
P31c
Cell Parameters:
a = 8.555(2) Å, c = 20.190(5) Å
Ratio:
a:c = 1 : 2.36
Unit Cell V:
1,279.70 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Type material:
Most crystals exhibit only {0001} and {1011} with traces of {1010}. Rare forms include {3032}, {1124}, {6.1.7.12}, {1012}, {3144}, {4150}.
Twinning:
None observed

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005382WickenburgiteLam A E, Groat L A (1994) The crystal structure of wickenburgite, Pb3CaAl[AlSi10O27](H2O)3, a sheet structure The Canadian Mineralogist 32 525-53219940293
0005381WickenburgiteLam A E, Groat L A (1994) The crystal structure of wickenburgite, Pb3CaAl[AlSi10O27](H2O)3, a sheet structure The Canadian Mineralogist 32 525-53219940293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.1 Å(100)
3.26 Å(80)
3.93 Å(60)
3.36 Å(40)
2.639 Å(40)
5.96 Å(30)
5.04 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]

Type Occurrence of WickenburgiteHide

General Appearance of Type Material:
Well crystallized to granular and massive. Crystals from 0.2 - 1.5 mm in diameter.
Place of Conservation of Type Material:
Harvard University, Cambridge, Massachusetts, USA, 119099.
National Museum of Natural History, Washington, D.C., USA, 122875.
Geological Setting of Type Material:
Oxide zone mineral derived from lead ores.

Synonyms of WickenburgiteHide

Other Language Names for WickenburgiteHide

Relationship of Wickenburgite to other SpeciesHide

Common AssociatesHide

Associations Based on Photo Data:
58 photos of Wickenburgite associated with MimetitePb5(AsO4)3Cl
32 photos of Wickenburgite associated with FluoriteCaF2
31 photos of Wickenburgite associated with WillemiteZn2SiO4
18 photos of Wickenburgite associated with FornacitePb2Cu(CrO4)(AsO4)(OH)
10 photos of Wickenburgite associated with CerussitePbCO3
9 photos of Wickenburgite associated with QuartzSiO2
8 photos of Wickenburgite associated with PhoenicochroitePb2(CrO4)O
8 photos of Wickenburgite associated with MurdochiteCu12Pb2O15Cl2
8 photos of Wickenburgite associated with CreaseyitePb2Cu2Fe3+2(Si4.67Al0.33)O15.33(OH)3 · H2O
8 photos of Wickenburgite associated with DuftitePbCu(AsO4)(OH)

Related Minerals - Strunz-mindat GroupingHide

9.EG.05CymriteBaAl2Si2(O,OH)8 · H2OMon. 2 : P21
9.EG.10Naujakasite(Na,K)6(Fe2+,Mn2+,Ca)(Al,Fe)4Si8O26Mon.
9.EG.10ManganonaujakasiteNa6(Mn2+,Fe2+)Al4Si8O26Mon. 2/m : B2/m
9.EG.15DmisteinbergiteCa(Al2Si2O8)Trig. 32 : P312
9.EG.20KampfiteBa12(Si11Al5)O31(CO3)8Cl5Mon. m
9.EG.25VertumniteCa4Al4Si4O6(OH)24 · 3H2OMon. 2/m : P21/m
9.EG.25SträtlingiteCa2Al2SiO7 · 8H2OTrig. 3m : R3m
9.EG.30Eggletonite(Na,K,Ca)xMn6(Si,Al)10O24(OH)4 · nH2O (x = 1-2; n = 7-11)Mon.
9.EG.30Ganophyllite(K,Na)xMn2+6(Si,Al)10O24(OH)4 · nH2O (x = 1-2; n = 7-11)Mon. 2/m
9.EG.30Tamaite(Ca,K,Na)xMn6(Si,Al)10O24(OH)4 · nH2O (x = 1-2; n = 7-11)Mon. 2/m : P21/b
9.EG.35ZussmaniteK(Fe,Mg,Mn)13(Si,Al)18O42(OH)14Trig. 3 : R3
9.EG.35CoombsiteKMn2+13(Si,Al)18O42(OH)14Trig.
9.EG.40'Chalcodite'K(Fe3+,Mg,Fe2+)8(Si,Al)12(O,OH)27Tric. 1 : P1
9.EG.40Parsettensite(K,Na,Ca)7.5(Mn,Mg)49Si72O168(OH)50 · nH2OMon. 2/m : B2/m
9.EG.40LennilenapeiteK4Mn2+48[Si64Al8]O164(OH)52 · nH2OTric.
9.EG.40StilpnomelaneK4Fe2+48[Si64Al8]O164(OH)52 · nH2OTric. 1 : P1
9.EG.45Latiumite(Ca,K)4(Si,Al)5O11(SO4,CO3)Mon. 2 : P21
9.EG.45LevantiteKCa3Al2(SiO4)(Si2O7)(PO4)Mon. 2 : P21
9.EG.45TuscaniteKCa6(Si,Al)10O22(SO4,CO3)2(OH) · H2OMon. 2/m : P21/b
9.EG.50JagoitePb18Fe3+4[Si4(Si,Fe3+)6][Pb4Si16(Si,Fe)4]O82Cl6Hex. 6m2 : P6c2
9.EG.50FriisitePb8Al3Si8O27Cl3Hex. 6m2 : P62c
9.EG.60HyttsjöitePb18Ba2Ca5Mn2+2Fe3+2Si30O90Cl · 6H2OTrig. 3 : R3
9.EG.65ArmbrusteriteK5Na7Mn15[(Si9O22)4](OH)10 · 4H2OMon. 2/m : B2/m
9.EG.70RoymilleritePb24Mg9(Si10O28)(CO3)10(BO3)(SiO4)(OH)13O5Tric. 1 : P1
9.EG.70Britvinite[Pb7(OH)3F(BO3)2(CO3)][Mg4.5(OH)3(Si5O14)]Tric. 1 : P1
9.EG.75KayupovaiteNa2Mn10[(Si14Al2)O38(OH)8] · 7H2OMon. 2/m : B2/b
9.EG.75'UM1989-30-SiO:AlBaCaFeHKMgMn'(Ba,Ca)(Mn,Fe,Mg)22(Si,Al)32O76(OH)16 · 12H2O
9.EG.75Bannisterite(Ca,K,Na)(Mn2+,Fe2+)10(Si,Al)16O38(OH)8 · nH2OMon. 2/m : B2/b

Fluorescence of WickenburgiteHide

Dull orange under SW UV

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for WickenburgiteHide

References for WickenburgiteHide

Localities for WickenburgiteHide

Showing 16 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Germany
 
  • Rhineland-Palatinate
    • Rhein-Lahn-Kreis
      • Lahnstein
        • Friedrichssegen
Schnorrer (1993)
USA
 
  • Arizona
    • La Paz County
      • Silver Mining District
Bancroft et al. (1990) +1 other reference
Bancroft et al. (1990) +2 other references
Southern California Micromounters ...
    • Maricopa County
      • Belmont Mountains
Williams (1968)
      • Osborn Mining District
        • Hummingbird Springs
Anthony et al. (1995)
        • Tonopah
          • Tiger Wash
Richard Dale Collection +1 other reference
Yang et al. (2013)
      • Vulture Mining District
Minerals identified by the mine owners (2024)
Williams (1968) +2 other references
      • Wickenburg
- (1970)
    • Mohave County
      • Artillery Mountains
        • Artillery Peak
Williams (1982)
        • Rawhide Wash
Joan Rosell (2019)
            • Rawhide mine area
Williams (1982) +1 other reference
Anthony et al. (1995)
  • Nevada
    • Eureka County
Castor et al. (2004)
 
and/or  
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