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Monteregianite-(Y)

A valid IMA mineral species
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About Monteregianite-(Y)Hide

Formula:
(Na,K)6(Y,Ca)2Si16O38 · 10H2O
Colour:
Colorless, white, grey, rarely mauve or pale green
Lustre:
Vitreous, Silky
Hardness:
Specific Gravity:
2.42
Crystal System:
Monoclinic
Member of:
Name:
Originally named monteregianite by George Y. Chao in 1978 after the Monteregian Hills, a series of monadnocks or prominent hills on an otherwise flat landscape in eastern Quebec, Canada. The type locality for the mineral, Poudrette Quarry, Mont Saint-Hilaire, is on one of these hills. The suffix/modifier follows the Levinson rule, indicating that the predominant essential REE is yttrium. It was added by the IMA in 1987.

Before being described, the mineral was referred to as UK-6 in Mont Saint-Hilaire related literature.
Monteregianite-(Y)-Wickenburgite Series.

Several synthetic REE analogues have been prepared.


Unique IdentifiersHide

Mindat ID:
2765
Long-form identifier:
mindat:1:1:2765:2

Similar NamesHide

Monteregianite-(Y)-Wickenburgite SeriesA solid-solution series between two end-member minerals

IMA Classification of Monteregianite-(Y)Hide

Approved
IMA status notes:
Renamed by the IMA
IMA Formula:
KNa2YSi8O19·5H2O
Approval year:
1972
First published:
1978

Classification of Monteregianite-(Y)Hide

9.EB.15

9 : SILICATES (Germanates)
E : Phyllosilicates
B : Double nets with 4- and 6-membered rings
72.5.1.2

72 : PHYLLOSILICATES Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings
5 : Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings with corrugated and complex layers
14.8.7

14 : Silicates not Containing Aluminum
8 : Silicates of Group III metals other than Al

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
Mreg-YIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Monteregianite-(Y)Hide

Vitreous, Silky
Transparency:
Transparent, Translucent, Opaque
Colour:
Colorless, white, grey, rarely mauve or pale green
Streak:
White
Hardness:
3½ on Mohs scale
Cleavage:
Perfect
{010} perfect, {001} very good,{100} fair.
Density:
2.42 g/cm3 (Measured)    2.391 g/cm3 (Calculated)

Optical Data of Monteregianite-(Y)Hide

Type:
Biaxial (+)
RI values:
nα = 1.51 nβ = 1.513 nγ = 1.517
Max. Birefringence:
δ = 0.007
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Low (negative)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.

No measured or calculated 2V is on file for this mineral, so the value used here (82°) is estimated from its recorded refractive indices and optic sign, not from a direct 2V measurement.
Dispersion:
none
Optical Extinction:
X = c; Y = a; Z = b.

Chemistry of Monteregianite-(Y)Hide

Mindat Formula:
(Na,K)6(Y,Ca)2Si16O38 · 10H2O
Element Weights:
Element% weight
O49.443 %
Si28.931 %
Y11.448 %
Na8.881 %
H1.298 %

Calculated from ideal end-member formula.
O
Si
Y
Na
H

Crystallography of Monteregianite-(Y)Hide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 9.512(2) Å, b = 23.956(4) Å, c = 9.617(2) Å
β = 93.85(1)°
Ratio:
a:b:c = 0.397 : 1 : 0.401
Unit Cell V:
2,186.48 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Bounded by {010}, {001} and {100}. Some also show {101}.
Comment:
Space group P21/n.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0001072Monteregianite-(Y)Ghose S, Sen Gupta P K, Campana C F (1987) Symmetry and crystal structure of monteregianite, Na4K2Y2Si16O38.10H2O, a double-sheet silicate with zeolitic properties no longer have the original data, so they cannot check American Mineralogist 72 365-37419870293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
12.00 Å(100)
7.03 Å(100)
6.55 Å(40)
6.02 Å(50)
4.42 Å(100)
3.405 Å(50)
3.026 Å(50)
2.873 Å(80)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of Monteregianite-(Y)Hide

General Appearance of Type Material:
Needle-shaped crystals in radiating clusters and as groups of tabular crystals.
Place of Conservation of Type Material:
Canadian Museum of Nature, Ottawa, Canada, 37130.
National Museum of Natural History, Washington, D.C., USA, 145548.
Geological Setting of Type Material:
Miarolitic cavities and thermally metamorphosed inclusions and rheomorphic breccias in nepheline syenite.
Associated Minerals at Type Locality:

Synonyms of Monteregianite-(Y)Hide

Other Language Names for Monteregianite-(Y)Hide

Relationship of Monteregianite-(Y) to other SpeciesHide

Member of:
Other Members of Rhodesite Group:
Delhayelite(Na,K)10Ca5Al6Si32O80(Cl2,F2,SO4)3 · 18H2OOrth.
FivegiteK4Ca2[AlSi7O17(O2-xOHx)][(H2O)2-xOHx]ClOrth. mm2 : Pmn21
HydrodelhayeliteKCa2AlSi7O17(OH)2 · 6H2OOrth. mm2
MelansoniteNa◻KZrSi8O19 · 5H2OOrth. mmm(2/m2/m2/m) : Pmma
NatromelansoniteNa3Zr[Si7AlO19] · 4H2OMon. 2/m : P21/m
RhodesiteKHCa2Si8O19 · 5H2OOrth. mmm(2/m2/m2/m)
Forms a series with:

Common AssociatesHide

Associations Based on Photo Data:
32 photos of Monteregianite-(Y) associated with CalciteCaCO3
15 photos of Monteregianite-(Y) associated with AlbiteNa(AlSi3O8)
13 photos of Monteregianite-(Y) associated with QuartzSiO2
11 photos of Monteregianite-(Y) associated with LeucospheniteBaNa4Ti2B2Si10O30
10 photos of Monteregianite-(Y) associated with PectoliteNaCa2Si3O8(OH)
7 photos of Monteregianite-(Y) associated with FluoriteCaF2
4 photos of Monteregianite-(Y) associated with FluorapatiteCa5(PO4)3F
4 photos of Monteregianite-(Y) associated with Arfvedsonite Root Name GroupANa2(C2+4Fe3+}Si8O22W2
3 photos of Monteregianite-(Y) associated with VinogradoviteNa4Ti4(Si2O6)2[(Si,Al)4O10]O4 · (H2O,Na,K)3
2 photos of Monteregianite-(Y) associated with Chabazite-Na(Na2,K2,Ca,Sr,Mg)2[Al2Si4O12]2 · 12H2O

Related Minerals - Strunz-mindat GroupingHide

9.EB.NatromelansoniteNa3Zr[Si7AlO19] · 4H2OMon. 2/m : P21/m
9.EB.05MelansoniteNa◻KZrSi8O19 · 5H2OOrth. mmm(2/m2/m2/m) : Pmma
9.EB.05RhodesiteKHCa2Si8O19 · 5H2OOrth. mmm(2/m2/m2/m)
9.EB.05MacdonalditeBaCa4Si16O36(OH)2 · 10H2OOrth.
9.EB.10HydrodelhayeliteKCa2AlSi7O17(OH)2 · 6H2OOrth. mm2
9.EB.10Delhayelite(Na,K)10Ca5Al6Si32O80(Cl2,F2,SO4)3 · 18H2OOrth.
9.EB.20CarletoniteKNa4Ca4Si8O18(CO3)4(OH,F) · H2OTet. 4/mmm(4/m2/m2/m) : P4/mbm
9.EB.20FluorcarletoniteKNa4Ca4Si8O18(CO3)4F · H2OTet.
9.EB.25Günterblassite(K,Ca,Ba)2(Fe,Ca,Mg,Na)[(Si,Al)13O25(OH)4] · 7H2O · Orth. mm2 : Pmn21
9.EB.25Hillesheimite(K,Ca,Ba,◻)2(Mg,Fe,Ca,◻)2[(Si,Al )13O23(OH)6](OH) · 8H2OOrth. mmm(2/m2/m2/m) : Pmmn
9.EB.25UmbrianiteK7Na2Ca2[Al3Si10O29]F2Cl2 Orth. mmm(2/m2/m2/m) : Pmmn
9.EB.30FivegiteK4Ca2[AlSi7O17(O2-xOHx)][(H2O)2-xOHx]ClOrth. mm2 : Pmn21

Fluorescence of Monteregianite-(Y)Hide

Fluoresces green under SW UV.

Other InformationHide

IR Spectrum:
Infrared spectra confirm the presence of H2O in the mineral.
Thermal Behaviour:
Three distinct stages of dehydration at 25-80, 80-200, and 200-400 °C.
Notes:
Readily etched by 1:l HCl, HNO3, and H2SO4.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Monteregianite-(Y)Hide

References for Monteregianite-(Y)Hide

Localities for Monteregianite-(Y)Hide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada (TL)
 
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
Chao (1978) +2 other references
 
and/or  
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