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Latiumite

A valid IMA mineral species - grandfathered
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About LatiumiteHide

Formula:
(Ca,K)4(Si,Al)5O11(SO4,CO3)
Colour:
White, may be zoned or mottled.
Lustre:
Vitreous
Hardness:
5½ - 6
Specific Gravity:
2.93
Crystal System:
Monoclinic
Member of:
Name:
Named in 1953 by C.E. Tilley and N.F.M. Henry for Latium, the region of central western Italy that includes the type locality; this is the Latin form of the name, the modern name is Lazio.
A 2D-zeolite that - alongside with the related tuscanite - may be considered a prototype of advanced ion-exchange & ion/proton conductivity materials.


Unique IdentifiersHide

Mindat ID:
2336
Long-form identifier:
mindat:1:1:2336:4

IMA Classification of LatiumiteHide

Classification of LatiumiteHide

9.EG.45

9 : SILICATES (Germanates)
E : Phyllosilicates
G : Double nets with 6-membered and larger rings
73.1.2.1

73 : PHYLLOSILICATES Condensed Tetrahedral Sheets
1 : Condensed Tetrahedral Sheets with double layers
17.10.6

17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
LatIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of LatiumiteHide

Vitreous
Transparency:
Transparent, Translucent
Colour:
White, may be zoned or mottled.
Hardness:
5½ - 6 on Mohs scale
Cleavage:
Perfect
{100}
Density:
2.93 g/cm3 (Measured)    2.92 g/cm3 (Calculated)

Optical Data of LatiumiteHide

Type:
Biaxial (+/-)
RI values:
nα = 1.600 - 1.603 nβ = 1.606 - 1.609 nγ = 1.614 - 1.615
2V:
Measured: 83° to 90°, Calculated: 84° to 88°
Max. Birefringence:
δ = 0.012 - 0.014
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v marked

Chemistry of LatiumiteHide

Mindat Formula:
(Ca,K)4(Si,Al)5O11(SO4,CO3)

Element Weights:
Element% weight
O41.898 %
Ca27.988 %
Si24.516 %
S5.598 %

Calculated from ideal end-member formula.
O
Ca
Si
S
Common Impurities:
Mn,Na,Cl,H20,C

Crystallography of LatiumiteHide

Crystal System:
Monoclinic
Class (H-M):
2 - Sphenoidal
Space Group:
P21
Setting:
P21
Cell Parameters:
a = 12.06(1) Å, b = 5.08(2) Å, c = 10.81(1) Å
β = 106.0°
Ratio:
a:b:c = 2.374 : 1 : 2.128
Unit Cell V:
636.62 ų (Calculated from Unit Cell)
Z:
2
Twinning:
On {100} common, simple or multiple.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000319LatiumiteCannillo E, Dal Negro A, Rossi G (1973) The crystal structure of latiumite, a new type of sheet silicate American Mineralogist 58 466-47019730293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.86 Å(s1)
3.06 Å(s2)
2.96 Å(s3)
2.54 Å(s)
4.6 Å(m)
4.5 Å(m)
3.83 Å(m)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
31 : Thermally altered carbonate, phosphate, and iron formations

Type Occurrence of LatiumiteHide

Other Language Names for LatiumiteHide

Dutch:Latiumiet
German:Latiumit
Spanish:Latiumita

Relationship of Latiumite to other SpeciesHide

Member of:
Other Members of Latiumite Group:
LevantiteKCa3Al2(SiO4)(Si2O7)(PO4)Mon. 2 : P21

Common AssociatesHide

Associations Based on Photo Data:
5 photos of Latiumite associated with Augite(CaxMgyFez)(Mgy1Fez1)Si2O6
3 photos of Latiumite associated with GrossularCa3Al2(SiO4)3
1 photo of Latiumite associated with CuspidineCa8(Si2O7)2F4
1 photo of Latiumite associated with 'Fayalite-Forsterite Series'

Related Minerals - Strunz-mindat GroupingHide

9.EG.05CymriteBaAl2Si2(O,OH)8 · H2OMon. 2 : P21
9.EG.10Naujakasite(Na,K)6(Fe2+,Mn2+,Ca)(Al,Fe)4Si8O26Mon.
9.EG.10ManganonaujakasiteNa6(Mn2+,Fe2+)Al4Si8O26Mon. 2/m : B2/m
9.EG.15DmisteinbergiteCa(Al2Si2O8)Trig. 32 : P312
9.EG.20KampfiteBa12(Si11Al5)O31(CO3)8Cl5Mon. m
9.EG.25VertumniteCa4Al4Si4O6(OH)24 · 3H2OMon. 2/m : P21/m
9.EG.25SträtlingiteCa2Al2SiO7 · 8H2OTrig. 3m : R3m
9.EG.30Eggletonite(Na,K,Ca)xMn6(Si,Al)10O24(OH)4 · nH2O (x = 1-2; n = 7-11)Mon.
9.EG.30Ganophyllite(K,Na)xMn2+6(Si,Al)10O24(OH)4 · nH2O (x = 1-2; n = 7-11)Mon. 2/m
9.EG.30Tamaite(Ca,K,Na)xMn6(Si,Al)10O24(OH)4 · nH2O (x = 1-2; n = 7-11)Mon. 2/m : P21/b
9.EG.35ZussmaniteK(Fe,Mg,Mn)13(Si,Al)18O42(OH)14Trig. 3 : R3
9.EG.35CoombsiteKMn2+13(Si,Al)18O42(OH)14Trig.
9.EG.40'Chalcodite'K(Fe3+,Mg,Fe2+)8(Si,Al)12(O,OH)27Tric. 1 : P1
9.EG.40Parsettensite(K,Na,Ca)7.5(Mn,Mg)49Si72O168(OH)50 · nH2OMon. 2/m : B2/m
9.EG.40LennilenapeiteK4Mn2+48[Si64Al8]O164(OH)52 · nH2OTric.
9.EG.40StilpnomelaneK4Fe2+48[Si64Al8]O164(OH)52 · nH2OTric. 1 : P1
9.EG.45LevantiteKCa3Al2(SiO4)(Si2O7)(PO4)Mon. 2 : P21
9.EG.45TuscaniteKCa6(Si,Al)10O22(SO4,CO3)2(OH) · H2OMon. 2/m : P21/b
9.EG.50JagoitePb18Fe3+4[Si4(Si,Fe3+)6][Pb4Si16(Si,Fe)4]O82Cl6Hex. 6m2 : P6c2
9.EG.50FriisitePb8Al3Si8O27Cl3Hex. 6m2 : P62c
9.EG.55WickenburgiteCaPb3Al2Si10O24(OH)6Trig. 3m : P31c
9.EG.60HyttsjöitePb18Ba2Ca5Mn2+2Fe3+2Si30O90Cl · 6H2OTrig. 3 : R3
9.EG.65ArmbrusteriteK5Na7Mn15[(Si9O22)4](OH)10 · 4H2OMon. 2/m : B2/m
9.EG.70RoymilleritePb24Mg9(Si10O28)(CO3)10(BO3)(SiO4)(OH)13O5Tric. 1 : P1
9.EG.70Britvinite[Pb7(OH)3F(BO3)2(CO3)][Mg4.5(OH)3(Si5O14)]Tric. 1 : P1
9.EG.75KayupovaiteNa2Mn10[(Si14Al2)O38(OH)8] · 7H2OMon. 2/m : B2/b
9.EG.75'UM1989-30-SiO:AlBaCaFeHKMgMn'(Ba,Ca)(Mn,Fe,Mg)22(Si,Al)32O76(OH)16 · 12H2O
9.EG.75Bannisterite(Ca,K,Na)(Mn2+,Fe2+)10(Si,Al)16O38(OH)8 · nH2OMon. 2/m : B2/b

Other InformationHide

Thermal Behaviour:
Fuses before the blowpipe. The resulting glass partly devitrifies at a low read heat to a fine grained product.
Notes:
Soluble in weak acids, leaving a silica residue.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for LatiumiteHide

References for LatiumiteHide

Localities for LatiumiteHide

Showing 12 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
France
 
  • Occitanie
    • Aveyron
      • Rodez
        • Sévérac-d'Aveyron
publication date: November 2018 +1 other reference
Israel
 
  • Southern District
    • Beersheba Subdistrict
      • Tamar Regional Council
Galuskina et al. (2026)
Italy (TL)
 
  • Lazio
    • Metropolitan City of Rome Capital
      • Albano Laziale
Tilley et al. (1953) +2 other references
De Michele (1974) +1 other reference
Rossano Carlini collection
      • Campagnano di Roma
      • Rocca di Papa
Tilley et al. (1953)
Dan Behnke Collection
    • Viterbo Province
      • Gradoli
Signoretti et al. (2001)
      • Onano
Cresta et al. (2002)
  • Tuscany
    • Grosseto Province
      • Pitigliano
Liotti (1991)
 
and/or  
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