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Vigezzite

A valid IMA mineral species
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About VigezziteHide

Formula:
CaNb2O6
Previously given as (Ca,Ce)(Nb,Ta,Ti)2O6. Redefined in 2025.
Colour:
Orange-yellow
Hardness:
4½ - 5
Specific Gravity:
5.54 (Calculated)
Crystal System:
Orthorhombic
Name:
Named after its discovery locality in the Vigezzo valley, Piedmont, Italy.
Dimorph of:
Aeschynite Group. The Nb analogue of UM2001-09-O:CaNbREESiTiY.

Compare Fersmite.


Unique IdentifiersHide

Mindat ID:
4177
Long-form identifier:
mindat:1:1:4177:1

Similar NamesHide

VogesiteA rock classification type

IMA Classification of VigezziteHide

Approved
IMA Formula:
CaNb5+2O6
Approval year:
1977
First published:
1979

Classification of VigezziteHide

4.DF.05

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
F : With large (+- medium-sized) cations; dimers and trimers of edgesharing octahedra
8.3.7.1

8 : MULTIPLE OXIDES CONTAINING NIOBIUM,TANTALUM OR TITANIUM
3 : AB2O6
18.2.19

18 : Niobates and Tantalates
2 : Niobates and tantalates containing rare earths but not U

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
VgzIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of VigezziteHide

Transparency:
Transparent
Colour:
Orange-yellow
Streak:
White
Hardness:
4½ - 5 on Mohs scale
Hardness:
VHN50=396 kg/mm2 - Vickers
Tenacity:
Very brittle
Cleavage:
Distinct/Good
{010}, distinct
Fracture:
Conchoidal
Density:
5.54 g/cm3 (Calculated)

Optical Data of VigezziteHide

Type:
Biaxial (+)
RI values:
nα = 2.14(2) nγ = 2.315(2)
Max. Birefringence:
δ = 0.175
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.

No measured or calculated 2V is on file for this mineral, so the value used here (93°) is estimated from its recorded refractive indices and optic sign, not from a direct 2V measurement.
Dispersion:
extreme
Optical Extinction:
X = a; Y = b; Z = c.

Chemistry of VigezziteHide

Mindat Formula:
CaNb2O6

Previously given as (Ca,Ce)(Nb,Ta,Ti)2O6. Redefined in 2025.
Element Weights:
Element% weight
Nb57.726 %
O29.823 %
Ca12.451 %

Calculated from ideal end-member formula.
Nb
O
Ca
Common Impurities:
Ta

Crystallography of VigezziteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pnma
Cell Parameters:
a = 7.55 Å, b = 11.03 Å, c = 5.36 Å
Ratio:
a:b:c = 0.684 : 1 : 0.486
Unit Cell V:
446.36 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Euhedral, flattened prismatic crystals, strongly striated on {010} parallel to prism axis. The prisms are terminated only by the pinacoid {100}.
Comment:
Space group Pnmb (non-standard setting).

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014844VigezziteGiuseppetti G, Tadini P (1990) The crystal structure of vigezzite, (Ca,Ce)(Nb,Ta,Ti)2O6, intermediate term of the aeschynite series Neues Jahrbuch fur Mineralogie, Monatshefte 1990 301-3081990Vigezzo Valley, Novara, Italy0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.036 Å(100)
2.974 Å(100)
4.821 Å(90)
3.784 Å(80)
1.6018 Å(70)
1.7128 Å(60)
2.864 Å(40)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites
36 : Carbonatites, kimberlites, and related igneous rocks

Type Occurrence of VigezziteHide

General Appearance of Type Material:
Euhedral, flat prismatic crystals up to 2-3 mm in length.
Place of Conservation of Type Material:
Mineralogical Institute, University of Basel, Basel; Natural History Museum, Basel, Switzerland, MB27:336.
Geological Setting of Type Material:
In cavities of an albitic rock.
Associated Minerals at Type Locality:

Synonyms of VigezziteHide

Other Language Names for VigezziteHide

Relationship of Vigezzite to other SpeciesHide

Other Members of Aeschynite Group:
Aeschynite-(Ce)Ce(TiNb)O6Orth. mmm(2/m2/m2/m) : Pmna
Aeschynite-(Nd)Nd(TiNb)O6Orth. mmm(2/m2/m2/m)
Aeschynite-(Y)Y(TiNb)O6Orth. mmm(2/m2/m2/m) : Pmna
RynersoniteCaTa2O6Orth. mmm(2/m2/m2/m)
Tantalaeschynite-(Ce)Ce(TiTa)O6Orth. mmm(2/m2/m2/m) : Pnma
Tantalaeschynite-(Y)Y(TiTa)O6Orth. mmm(2/m2/m2/m)
'UM2001-09-O:CaNbREESiTiY'(Ca,Y,REE)(Ti,Nb,Si)2(O,OH)6
YuliniteSrNb2O6Mon. 2/m : P21/b

Common AssociatesHide

Associations Based on Photo Data:
6 photos of Vigezzite associated with 'Actinolite-Tremolite Series'
2 photos of Vigezzite associated with Actinolite◻Ca2(Mg4.5-2.5Fe0.5-2.5)Si8O22(OH)2
2 photos of Vigezzite associated with QuartzSiO2
1 photo of Vigezzite associated with AegirineNaFe3+Si2O6

Related Minerals - Strunz-mindat GroupingHide

4.DF.05Aeschynite-(Ce)Ce(TiNb)O6Orth. mmm(2/m2/m2/m) : Pmna
4.DF.05Aeschynite-(Nd)Nd(TiNb)O6Orth. mmm(2/m2/m2/m)
4.DF.05Aeschynite-(Y)Y(TiNb)O6Orth. mmm(2/m2/m2/m) : Pmna
4.DF.05Tantalaeschynite-(Y)Y(TiTa)O6Orth. mmm(2/m2/m2/m)
4.DF.05RynersoniteCaTa2O6Orth. mmm(2/m2/m2/m)
4.DF.05YuliniteSrNb2O6Mon. 2/m : P21/b
4.DF.10ChangbaiitePbNb2O6Trig. 3m : R3m
4.DF.15Murataite-(Y)(Y,Na)6Zn(Zn,Fe3+)4(Ti,Nb,Na)12O29(O,F,OH)10F4 Iso. m3m(4/m32/m) : Fm3m

Fluorescence of VigezziteHide

Not fluorescent with SW or LW UV, however, a quartz-lamp produces a brilliant green fluorescence, characteristic of cerium-bearing minerals.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for VigezziteHide

References for VigezziteHide

Reference List:

Localities for VigezziteHide

Showing 22 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Angola
 
  • Huíla Province
    • Quilengues
Amores-Casals et al. (2019)
Brazil
 
  • São Paulo
    • Cajati
Oliveira et al. (2020)
Menezes Filho et al. (2015)
Canada
 
  • Ontario
    • Renfrew County
      • Brudenell-Lyndoch-and-Raglan
        • Lyndoch Township
          • Quadeville area
ontariominerals.com
Czech Republic
 
  • Vysočina Region
    • Třebíč District
      • Kožichovice
Výravský et al. (2017)
Italy
 
  • Piedmont
    • Verbano-Cusio-Ossola Province
      • Baveno
        • Oltrefiume
          • Mount Camoscio
Sergio Varvello collection
      • Druogno
        • Orcesco
Graeser et al. (1979) +1 other reference
      • Omegna
        • Agrano
Varvello et al. (2013)
      • Trontano
        • Pizzo Marcio
Mattioli (1979 a) +8 other references
Madagascar
 
  • Vakinankaratra
    • Betafo District
      • Andrembesoa
        • Tetezantsio-Andoabatokely Pegmatite Field
Pezzotta (2007)
Mozambique
 
  • Zambezia Province
    • Alto Mólocuè District
Gomes et al. (2022)
Norway
 
  • Nordland
    • Hamarøy
      • Drag
Husdal (2019)
Husdal (2023)
Russia
 
  • Chelyabinsk Oblast
    • Kaslinsky District
      • Kasli
webmineral.ru (2021)
    • Miass
Sorokina et al. (2019)
  • Irkutsk Oblast
    • Vitim Plateau
      • Biraya and Bya Rivers confluence area (Chara Basin)
Koneva A.A. et al. (2010)
  • Murmansk Oblast
    • Kovdorsky District
  • Republic of Karelia
    • Loukhsky District
Sorokhtina et al. (2018)
Spain
 
  • Community of Madrid
Garcia-Guinea et al. (2005)
    • Cadalso de los Vidrios
Sainz de Baranda Graf et al. (2026)
    • La Cabrera
Tánago et al. (2012)
Switzerland
 
  • Grisons
    • Moesa Region
      • San Vittore
        • Monticello
 
and/or  
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