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Rorisite

A valid IMA mineral species
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About RorisiteHide

00099500017271926285238.jpg
Dew
Formula:
CaFCl
Colour:
Colorless
Lustre:
Vitreous
Hardness:
2
Specific Gravity:
2.78
Crystal System:
Tetragonal
Name:
From Latin, "roris", for "dew", alluding to the transparent drops that form on the mineral in moist air, that look like dew.
Matlockite Group.

Unstable in air, leaving a residue of fluorite.


Unique IdentifiersHide

Mindat ID:
3446
Long-form identifier:
mindat:1:1:3446:9

Similar NamesHide

RuarsiteA valid IMA mineral species(Ru,Os)AsS

IMA Classification of RorisiteHide

Classification of RorisiteHide

3.DC.25

3 : HALIDES
D : Oxyhalides, hydroxyhalides and related double halides
C : With Pb (As,Sb,Bi), without Cu
9.2.11.2

9 : NORMAL HALIDES
2 : AX2
8.4.11

8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
4 : Halides of the alkaline earths and Mg

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
RrsIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of RorisiteHide

Vitreous
Transparency:
Transparent
Comment:
becoming turbid on exposure to moist air
Colour:
Colorless
Streak:
White
Hardness:
Tenacity:
Brittle
Cleavage:
Perfect
Perfect {110} and excellent {001}
Fracture:
Conchoidal
Comment:
Thin leaves exhibit a bit of elasticity
Density:
2.78(1) g/cm3 (Measured)    2.94 g/cm3 (Calculated)

Optical Data of RorisiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.668(2) nε = 1.635(2)
Max. Birefringence:
δ = 0.033
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of RorisiteHide

Mindat Formula:
CaFCl
Element Weights:
Element% weight
Ca42.397 %
Cl37.505 %
F20.098 %

Calculated from ideal end-member formula.
Common Impurities:
Mg

Crystallography of RorisiteHide

Crystal System:
Tetragonal
Class (H-M):
4/mmm(4/m2/m2/m) - Ditetragonal Dipyramidal
Space Group:
P4/nmm
Setting:
P4/nmm
Cell Parameters:
a = 3.890(1) Å, c = 6.810(1) Å
Ratio:
a:c = 1 : 1.751
Unit Cell V:
103.05 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Flattened on {001}, with {111} and {110} and occasionally {100}.
Comment:
by analogy to matlockite

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0009601RorisiteLiebich W, Nicollin D (1977) Refinement of the PbFCl types BaFI, BaFBr and CaFCl Acta Crystallographica B33 2790-27941977synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.557 Å(100)
6.81 Å(45)
2.267 Å(35)
2.138 Å(32)
1.560 Å(32)
3.396 Å(30)
1.363 Å(25)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
50 : Coal and/or oil shale minerals<0.36
Stage 10b: Anthropogenic minerals<10 Ka
54 : Coal and other mine fire minerals (see also #51 and #56)

Type Occurrence of RorisiteHide

General Appearance of Type Material:
Tabular crystals up to 1 mm in diameter. Most crystals have "fused" surfaces without well-expressed flat surfaces.
Place of Conservation of Type Material:
1) Mining Institute, St. Petersburg, Russia, 2073.
2) Il’menskii Preserve Museum, Miass, Russia, 5880.
3) A. E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, r460/1.
Geological Setting of Type Material:
Burnt coal dump
Associated Minerals at Type Locality:

Synonyms of RorisiteHide

Other Language Names for RorisiteHide

Dutch:Rorisiet
German:Rorisit
Spanish:Rorisita

Relationship of Rorisite to other SpeciesHide

Other Members of Matlockite Group:
BismocliteBiOClTet. 4/mmm(4/m2/m2/m) : P4/nmm
DaubréeiteBiO(OH)Tet. 4/mmm(4/m2/m2/m) : P4/nmm
LaurionitePbCl(OH)Orth. mmm(2/m2/m2/m)
MatlockitePbFClTet. 4/mmm(4/m2/m2/m) : P4/nmm
ParalaurionitePbCl(OH)Mon. 2/m : B2/m
Zavaritskite(BiO)FTet. 4/mmm(4/m2/m2/m) : P4/nmm

Related Minerals - Strunz-mindat GroupingHide

3.DC.GajardoiteKCa0.5As3+4O6Cl2 · 5H2OHex. 6/mmm(6/m2/m2/m) : P6/mmm
3.DC.Lucabindiite(K,NH4)As4O6(Cl,Br)Hex. 6/mmm(6/m2/m2/m) : P6/mmm
3.DC.Cuatrocapaite-(NH4)(NH4)3(NaMg◻)(As2O3)6Cl6 · 16H2OTrig. 3m(32/m) : R3m
3.DC.Cuatrocapaite-(K)K3(NaMg◻)(As2O3)6Cl6 · 16H2OTrig. 3m(32/m) : R3m
3.DC.NapoliitePb2OFClTet. 4/mmm(4/m2/m2/m) : P42/mcm
3.DC.TorrecillasiteNa(As,Sb)3+4O6ClOrth.
3.DC.05ParalaurionitePbCl(OH)Mon. 2/m : B2/m
3.DC.05LaurionitePbCl(OH)Orth. mmm(2/m2/m2/m)
3.DC.05Mauriziodiniite(NH4)(As2O3)2IHex. 6/mmm(6/m2/m2/m) : P6/mmm
3.DC.05Russoite(NH4)ClAs2O3(H2O)0.5Hex. 622 : P622
3.DC.10FiedleritePb3FCl4(OH) · H2OMon. 2/m
3.DC.15PenfielditePb2Cl3(OH)Hex. 6 : P6
3.DC.15TelluroperitePb3TeO4Cl2Orth. mmm(2/m2/m2/m)
3.DC.20LaurelitePb7F12Cl2Hex. 6 : P6
3.DC.25ZhangpeishaniteBaFClTet. 4/mmm(4/m2/m2/m) : P4/nmm
3.DC.25MatlockitePbFClTet. 4/mmm(4/m2/m2/m) : P4/nmm
3.DC.25Zavaritskite(BiO)FTet. 4/mmm(4/m2/m2/m) : P4/nmm
3.DC.25BismocliteBiOClTet. 4/mmm(4/m2/m2/m) : P4/nmm
3.DC.25VegrandisiteBaCl2Orth. mmm(2/m2/m2/m) : Pnma
3.DC.30NadoritePbSbClO2Orth. mmm(2/m2/m2/m) : Cmcm
3.DC.30PeritePbBiClO2Orth. mmm(2/m2/m2/m) : Cmcm
3.DC.40ThorikositePb3Cl2(OH)(SbO3,AsO3)Tet. 4/mmm(4/m2/m2/m) : I4/mmm
3.DC.45MereheaditePb47Cl25(OH)13O24(CO3)(BO3)2Mon. m
3.DC.50BlixitePb8O5(OH)2Cl4Orth.
3.DC.52RumseyitePb2OClF Tet. 4/mmm(4/m2/m2/m) : I4/mmm
3.DC.55Vladkrivovichevite[Pb32O18][Pb4Mn2O]Cl14(BO3)8 · 2H2O Orth. mmm(2/m2/m2/m) : Pmmn
3.DC.55PinalitePb3WO5Cl2Orth. mmm(2/m2/m2/m)
3.DC.57YeomanitePb2O(OH)ClOrth. mmm(2/m2/m2/m) : Pnma
3.DC.60SymesitePb10(SO4)O7Cl4 · H2OTric. 1 : P1
3.DC.60'Lorettoite'Pb7O6Cl2Orth.
3.DC.62'Sarawakite (of Frenzel)'Sb, O, Cl (?)
3.DC.65EcdemitePb6As3+2O7Cl4Mon. 2 : P21
3.DC.70MendipitePb3Cl2O2Orth. 222 : P212121
3.DC.75DamaraitePb3Cl(OH)O2Orth. mm2 : Pmc21
3.DC.80OnoratoiteSb8Cl2O11Tric. 1 : P1
3.DC.95BarstowitePb4Cl6(CO3) · H2OMon. 2/m : P21/m

Fluorescence of RorisiteHide

Weak violet fluorescence with 360 nm UV.

Other InformationHide

Thermal Behaviour:
Fusibility 1.5; red flame coloration. In closed tube, fuses and forms a colorless liquid that crystallizes into a white transparent substance three seconds after removing the flame.
Notes:
Soluble in H2O and hygroscopic.

In moist air the colorless plates become turbid and coated with colorless drops of CaCl2 solution; the turbid plates consist of fine-grained fluorite.

Slowly soluble in HCl and HNO3; dissolves glass when mixed with H2SO4.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for RorisiteHide

References for RorisiteHide

Localities for RorisiteHide

Showing 4 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia
 
  • Chelyabinsk Oblast
Cesnokov et al. (1998)
Chesnokov et al. (1990) +1 other reference
  • Kabardino-Balkaria
    • Elbrussky District
      • Tyrnyauz Urban Settlement
I. V. Kulikov et al. (1982) +1 other reference
Ukraine
 
  • Donetsk Oblast
    • Gorlovka
      • Kalinin coal mine
Шарыгин (2015)
 
and/or  
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