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Opal-AG

A variety of 'Opal-A' [Opal]
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About Opal-AGHide

Formula:
SiO2 · nH2O
Lustre:
Vitreous, Sub-Vitreous, Greasy
Member of:
Name:
A stands for amorphous and G for gel-like.
The origin of the word "opal" is uncertain. It may be from the Sanskrit "upala", meaning "stone" or "precious stone" or from opalus, the ancient Latin name for the gem (Pliny the Elder, 75-79). Pliny may have also referred to the gem as paederos, but a modern commentary by Kostov (2008) questions if that name was actually applied to the opal in the modern sense.
A type of Opal consisting of aggregated spheres of amorphous silica, with water filling the gaps in between. Precious Opal and Potch Opal consist of this kind of structure - the difference being in the regularity of the sizes of the spheres and packing.

05041360017272471332761.jpg
Precious opal
"Precious Opal" shows a play of colours ("opalescence") in white light that is due to diffraction from the regular packing of silica spheres of roughly equal size (Jones et al., 1964; Sanders, 1964). Although the packing of the spheres may be regular, there is neither short-range nor long-range order in this material, and the X-ray powder diffraction pattern is characterized by a distinct broad hump and a possible weak second hump indicative of material that is "X-ray amorphous" (Jones and Segnit, 1971). Since the packing of the spheres is similar to the structure of a gel, the subscript G ("gel-like") has been added (Flörke et al., 1991; Graetsch, 1994). Not all precious opal is opal-AG: The diffracting structure and the resulting opalescence may be preserved to some degree when opal-AG transforms to opal-CT by crystallization (Sanders, 1975).


Opal that shows no play of colours is also composed of the same spherical clusters, but they are non-uniform in size and do not pack in an orderly manner, thus cancel out any possible diffraction of the light (Jones et al., 1964; Sanders, 1964). This type of opal is termed collectively "potch opal" and includes the massive varieties. Porous varieties of inorganic origin such as geyserite and materials composed of tests of microorganisms such as diatomite and radiolarite are also recognized. The X-ray powder diffraction pattern is essentially identical for of all these types of opal, regardless of their origin.





Unique IdentifiersHide

Mindat ID:
32187 (as Opal-AG)
3004 (as Opal)
Long-form identifier:
mindat:1:1:32187:5 (as Opal-AG)
mindat:1:1:3004:1 (as Opal)

Similar NamesHide

Opal-AA variety of OpalSiO2 · nH2O
Opal-ANA variety of 'Opal-A' [Opal]SiO2 · nH2O
Opal-CA variety of OpalSiO2 · nH2O
OpalasA synonym of Opal

Pronunciation of Opal-AGHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of Opal-AGHide

Vitreous, Sub-Vitreous, Greasy
Transparency:
Transparent, Translucent
Comment:
greasy to vitreous on freshly broken surfaces

Chemistry of Opal-AGHide

Mindat Formula:
SiO2 · nH2O
Element Weights:
Element% weight
O61.458 %
Si35.961 %
H2.581 %

Calculated from ideal end-member formula.

Synonyms of Opal-AGHide

Relationship of Opal-AG to other SpeciesHide

Member of:
Other Members of Silica:
ChibaiteSiO2 · n(CH4, C2H6, C3H8, i-C4H10) (n = 3/17 (max))Iso. m3(2/m3) : Fd3
CoesiteSiO2Mon. 2/m : B2/b
CristobaliteSiO2Tet. 422 : P41212
'Keatite'SiO2Tet. 422 : P43212
LechatelieriteSiO2Amor.
Melanophlogite46SiO2 · 6(N2,CO2) · 2(CH4,N2)Tet. 4/mmm(4/m2/m2/m)
MogániteSiO2Mon. 2/m
'Opal-AN'SiO2 · nH2O
'Opal-C'SiO2 · nH2O
'Opal-CT'SiO2 · nH2O
QuartzSiO2Trig. 32 : P3121
'Quartz-beta'SiO2Hex. 622 : P6422
StishoviteSiO2Tet. 4/mmm(4/m2/m2/m) : P42/mnm
TridymiteSiO2Tric. 1
'β-Cristobalite'SiO2Iso. m3m(4/m32/m) : Fd3m
'β-Tridymite'SiO2

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Opal-AG associated with GypsumCaSO4 · 2H2O

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Opal-AGHide

References for Opal-AGHide

Localities for Opal-AGHide

Showing 6 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • New South Wales
    • Finch Co.
www.mindat.org (n.d.)
        • Three Mile
Identified by mine guide
Belgium
 
  • Wallonia
    • Hainaut
      • La Louvière
        • Strépy-Bracquegnies
Mélon et al. (1976)
France
 
  • Auvergne-Rhône-Alpes
    • Puy-de-Dôme
      • Ambert
Japan
 
  • Kagoshima Prefecture
    • Kagoshima District
      • Mishima village
        • Satsuma-Ioujima (Satsuma-Iwojima; Iou island)
          • Iodake (Iwodake; Ioudake)
PXRD by Alfredo Petrov
USA
 
  • California
    • Napa County
      • Knoxville Mining District
        • Knoxville
Gissler et al. (2024)
 
and/or  
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