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Nalivkinite

A valid IMA mineral species

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Nalivkinite

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Nalivkinite

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Nalivkinite

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Nalivkinite

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Nalivkinite

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Nalivkinite

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Nalivkinite

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Nalivkinite

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

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About NalivkiniteHide

Dimitri V. Nalivkin

Formula:

Li₂NaFe²⁺₇Ti₂[Si₄O₁₂]₂O₂(OH)₄F(H₂O)₂

Colour:

Brown with a bronze hue

Lustre:

Vitreous

Hardness:

Specific Gravity:

3.32

Crystal System:

Triclinic

Member of:

Astrophyllite Group > Astrophyllite Supergroup

Name:

Named by Yulia A. Uvarova, Elena Sokolova, Frank C. Hawthorne, Atila A. Agakhanov, and Leonid A. Pautov in 2008 in honor of Dimitri Vasilievich Nalivkin (Дмитрий Васильевич Наливкин) (25 August 1889, Petersburg, Russia – 3 March 1982, Komarovo, Russia), Soviet geologist. His most significant achievement was the creation of the index geological maps of the USSR.

Type Locality:

ⓘ Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Astrophyllite Group.

Unique IdentifiersHide

Mindat ID:

31307

Long-form identifier:

mindat:1:1:31307:0

IMA Classification of NalivkiniteHide

IMA status:

Approved

IMA Formula:

Li₂NaFe²⁺₇Ti⁴⁺₂(Si₄O₁₂)₂O₂(OH)₄F(H₂O)₂

Approval year:

2006

First published:

2008

Type description reference:

Agakhanov, A. A., Pautov, L. A., Uvarova, Y. A., Sokolova, E., Hawthorne, F. C., Karpenko, V. Y. (2008) Nalivkinite, Li₂NaFe²⁺₇Ti₂(Si₈O₂₄)O₂(OH)₄F, a new mineral of the astrophyllite group from the Darai-Pioz Massif, Tadjikistan. New Data on Minerals, 43. Moscow. 5-12

Classification of NalivkiniteHide

Strunz-mindat (2026):

9.DC.05

9 : SILICATES (Germanates)
D : Inosilicates
C : Inosilicates with branched 2-periodic single chains; Si₂O₆ + 2SiO₃ Si₄O₁₂

Dana 8th ed.:

69.1.1.5

69 : INOSILICATES Chains with Side Branches or Loops
1 : Chains with Side Branches or Loops with (P=2, and N=4, 2 branches)

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

Symbol	Source	Reference for Standard
Nlv	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
Nlv	Warr (2020)	Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of NalivkiniteHide

Lustre:

Vitreous

Transparency:

Transparent

Colour:

Brown with a bronze hue

Hardness:

3 on Mohs scale

Density:

3.32(2) g/cm³ (Measured) 3.293 g/cm³ (Calculated)

Chemistry of NalivkiniteHide

Mindat Formula:

Li₂NaFe²⁺₇Ti₂[Si₄O₁₂]₂O₂(OH)₄F(H₂O)₂

Element Weights:

Element	% weight
O	39.773 %
Fe	30.368 %
Si	17.455 %
Ti	7.437 %
Na	1.786 %
F	1.476 %
Li	1.078 %
H	0.626 %

Calculated from ideal end-member formula.

Elements listed:

F, Fe, H, Li, Na, O, Si, Ti - search for minerals with similar chemistry

Crystallography of NalivkiniteHide

Crystal System:

Triclinic

Class (H-M):

1 - Pinacoidal

Space Group:

Cell Parameters:

a = 5.3745(6) Å, b = 11.9299(15) Å, c = 11.6509(4) Å
α = 113.325°, β = 94.524°, γ = 103.08°

Ratio:

a:b:c = 0.451 : 1 : 0.977

Unit Cell V:

656.2 Å³

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0006189	Nalivkinite	Uvarova Y A, Sokolova E, Hawthorne F C, Agakhanov A A, Pautov L A (2008) The crystal structure of nalivkinite, a new lithium member of the astrophyllite group The Canadian Mineralogist 46 651-659		2008	Tien-Shan Mountains, northern Tajikistan	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Nalivkinite'
loop_
_publ_author_name
'Uvarova Y A'
'Sokolova E'
'Hawthorne F C'
'Agakhanov A A'
'Pautov L A'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 46 
_journal_year 2008
_journal_page_first 651
_journal_page_last 659
_publ_section_title
;
 The crystal structure of nalivkinite, a new lithium member of the astrophyllite group
;
_database_code_amcsd 0006189
_chemical_compound_source 'Tien-Shan Mountains, northern Tajikistan'
_chemical_formula_sum 'Fe5.64 Ca.29 Pb.02 Mn.9 Sn.09 Mg.04 Zn.04 (Ti1.56 Nb.24 Zr.16 Ta.04) (Si7.848 Al.152) K.75 Li1.14 Cs.09 Na.8 O30 F H4'
_cell_length_a 5.3745
_cell_length_b 11.9299
_cell_length_c 11.6509
_cell_angle_alpha 113.325
_cell_angle_beta 94.524
_cell_angle_gamma 103.080
_cell_volume 656.214
_exptl_crystal_density_diffrn      3.311
_symmetry_space_group_name_H-M 'P -1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
FeM1   0.84900   0.20530   0.47960   0.85500   0.00810
CaM1   0.84900   0.20530   0.47960   0.03500   0.00810
PbM1   0.84900   0.20530   0.47960   0.01000   0.00810
FeM2   0.28040   0.06734   0.48950   1.00000   0.00750
FeM3   0.42250   0.35177   0.48480   0.55000   0.00760
MnM3   0.42250   0.35177   0.48480   0.45000   0.00760
FeM4   0.00000   0.50000   0.50000   0.83000   0.00730
SnM4   0.00000   0.50000   0.50000   0.09000   0.00730
MgM4   0.00000   0.50000   0.50000   0.04000   0.00730
ZnM4   0.00000   0.50000   0.50000   0.04000   0.00730
TiD   0.07810   0.08560   0.19760   0.78000   0.01050
NbD   0.07810   0.08560   0.19760   0.12000   0.01050
ZrD   0.07810   0.08560   0.19760   0.08000   0.01050
TaD   0.07810   0.08560   0.19760   0.02000   0.01050
SiT1   0.67670   0.27030   0.23080   0.98100   0.00770
AlT1   0.67670   0.27030   0.23080   0.01900   0.00770
SiT2   0.81440   0.54670   0.25640   0.98100   0.00810
AlT2   0.81440   0.54670   0.25640   0.01900   0.00810
SiT3   0.38020   0.67670   0.25840   0.98100   0.00590
AlT3   0.38020   0.67670   0.25840   0.01900   0.00590
SiT4   0.50490   0.93090   0.23470   0.98100   0.00740
AlT4   0.50490   0.93090   0.23470   0.01900   0.00740
KA1a   0.14640   0.28600   0.99770   0.37500   0.02900
LiA1a   0.14640   0.28600   0.99770   0.07000   0.02900
CsA1a   0.14640   0.28600   0.99770   0.04500   0.02900
NaA1a   0.14640   0.28600   0.99770   0.01000   0.02900
LiA1b   0.08700   0.17700   0.00000   0.50000   0.02900
NaB   0.50000   0.00000   0.00000   0.78000   0.00740
CaB   0.50000   0.00000   0.00000   0.22000   0.00740
O1   0.72520   0.31580   0.38400   1.00000   0.00740
O2   0.14620   0.16000   0.37230   1.00000   0.00760
O3   0.12610   0.38950   0.59020   1.00000   0.00730
O4   0.29980   0.46260   0.40030   1.00000   0.00930
O5   0.99130   0.11710   0.59170   1.00000   0.00930
O6   0.55710   0.25540   0.58720   1.00000   0.00700
O7   0.57300   0.01620   0.38850   1.00000   0.00800
O8   0.07490   0.58980   0.20250   1.00000   0.01590
O9   0.24910   0.04210   0.83030   1.00000   0.02260
O10   0.42730   0.41310   0.79720   1.00000   0.01470
O11   0.12660   0.80750   0.83170   1.00000   0.02300
O12   0.26100   0.95570   0.16960   1.00000   0.02210
O13   0.27060   0.60620   0.80330   1.00000   0.01800
O14   0.57420   0.22110   0.80020   1.00000   0.01880
O15   0.38200   0.18890   0.16640   1.00000   0.02060
F   0.00000   0.00000   0.00000   1.00000   0.01740
H1   0.21000   0.41600   0.30900   1.00000   0.01120
H2   0.05000   0.16700   0.68600   1.00000   0.01120
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
FeM1 0.00780 0.00650 0.01250 0.00290 0.00320 0.00580
CaM1 0.00780 0.00650 0.01250 0.00290 0.00320 0.00580
PbM1 0.00780 0.00650 0.01250 0.00290 0.00320 0.00580
FeM2 0.00660 0.00650 0.01270 0.00280 0.00350 0.00680
FeM3 0.00720 0.00550 0.01350 0.00350 0.00380 0.00610
MnM3 0.00720 0.00550 0.01350 0.00350 0.00380 0.00610
FeM4 0.00590 0.00470 0.01310 0.00230 0.00240 0.00520
SnM4 0.00590 0.00470 0.01310 0.00230 0.00240 0.00520
MgM4 0.00590 0.00470 0.01310 0.00230 0.00240 0.00520
ZnM4 0.00590 0.00470 0.01310 0.00230 0.00240 0.00520
TiD 0.00660 0.00870 0.01910 0.00430 0.00380 0.00740
NbD 0.00660 0.00870 0.01910 0.00430 0.00380 0.00740
ZrD 0.00660 0.00870 0.01910 0.00430 0.00380 0.00740
TaD 0.00660 0.00870 0.01910 0.00430 0.00380 0.00740
SiT1 0.00590 0.01040 0.01210 0.00370 0.00350 0.00910
AlT1 0.00590 0.01040 0.01210 0.00370 0.00350 0.00910
SiT2 0.00810 0.00600 0.01270 0.00240 0.00210 0.00610
AlT2 0.00810 0.00600 0.01270 0.00240 0.00210 0.00610
SiT3 0.00610 0.00410 0.00940 0.00190 0.00170 0.00460
AlT3 0.00610 0.00410 0.00940 0.00190 0.00170 0.00460
SiT4 0.00780 0.00600 0.01130 0.00290 0.00190 0.00610
AlT4 0.00780 0.00600 0.01130 0.00290 0.00190 0.00610
KA1a 0.01860 0.05890 0.00000 0.01170 0.00080 0.00280
LiA1a 0.01860 0.05890 0.00000 0.01170 0.00080 0.00280
CsA1a 0.01860 0.05890 0.00000 0.01170 0.00080 0.00280
NaA1a 0.01860 0.05890 0.00000 0.01170 0.00080 0.00280
LiA1b 0.01860 0.05890 0.00000 0.01170 0.00080 0.00280
NaB 0.01190 0.00820 0.00370 0.00410 0.00130 0.00360
CaB 0.01190 0.00820 0.00370 0.00410 0.00130 0.00360
O1 0.00920 0.00920 0.00670 0.00370 0.00200 0.00580
O2 0.01050 0.00630 0.00530 0.00290 0.00080 0.00150
O3 0.00490 0.00460 0.01360 0.00130 0.00160 0.00490
O4 0.01250 0.00650 0.01210 0.00480 0.00290 0.00590
O5 0.00960 0.00850 0.01370 0.00440 0.00500 0.00710
O6 0.00640 0.00900 0.01000 0.00350 0.00290 0.00760
O7 0.00900 0.00600 0.01150 0.00300 0.00190 0.00570
O8 0.01320 0.01770 0.01490 0.00100 0.00430 0.00670
O9 0.01830 0.02190 0.01840 -0.00480 0.00800 0.00410
O10 0.01690 0.01730 0.01260 0.01070 0.00290 0.00590
O11 0.02970 0.03120 0.02060 0.02430 0.01050 0.01400
O12 0.02860 0.02040 0.01670 0.01910 -0.00290 0.00210
O13 0.02780 0.00990 0.01860 0.00480 0.00420 0.00860
O14 0.03120 0.01050 0.01760 0.00500 0.00410 0.00930
O15 0.01350 0.03050 0.01230 -0.00810 -0.00280 0.01230
F 0.01770 0.01490 0.02110 0.00520 0.00220 0.00910

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
10.56 Å	(100)
3.50 Å	(100)
2.780 Å	(80)
2.648 Å	(45)
2.578 Å	(70)
2.474 Å	(15)
2.295 Å	(30)
2.106 Å	(35)
1.760 Å	(30)
1.660 Å	(15)

Locality:

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Reference:

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 4b: Highly evolved igneous rocks	>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of NalivkiniteHide

Type Locality:

ⓘ Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Place of Conservation of Type Material:

Fersman Mineralоgical Museum, Russian Academy of Sciences, Moscow.

Associated Minerals at Type Locality:

Aegirine	Bafertisite	Calcybeborosilite-(Y)	Fluorite	Microcline
Polylithionite	Quartz	Thorite

Reference:

Synonyms of NalivkiniteHide

IMA2006-038

Other Language Names for NalivkiniteHide

Dutch:Nalivkiniet

German:Nalivkinit

Relationship of Nalivkinite to other SpeciesHide

Member of:

Astrophyllite Group > Astrophyllite Supergroup

Other Members of Astrophyllite Group:

Astrophyllite	K₂NaFe²⁺₇Ti₂[Si₄O₁₂]₂O₂(OH)₄F	Tric. 1 : P1
Bulgakite	Li₂CaFe²⁺₇Ti₂[Si₄O₁₂]₂O₂(OH)₄O(H₂O)₂	Tric. 1 : P1
'Hydroastrophyllite'	[H₃O]⁺₂CaFe²⁺₇Ti₂[Si₄O₁₂]₂O₂(OH)₄O	Tric.
Niobophyllite	K₂NaFe²⁺₇(NbTi)[Si₄O₁₂]₂O₂(OH)₄O	Tric.
Tarbagataite	(K◻)CaFe²⁺₇Ti₂[Si₄O₁₂]₂O₂(OH)₄(OH)	Tric. 1 : P1
Zircophyllite	K₂NaFe²⁺₇Zr₂[Si₄O₁₂]₂O₂(OH)₄F	Tric.

Related Minerals - Strunz-mindat Grouping Hide

9.DC.	Bulgakite	Li₂CaFe²⁺₇Ti₂[Si₄O₁₂]₂O₂(OH)₄O(H₂O)₂	Tric. 1 : P1
9.DC.05	Devitoite	Ba₄Ba₂Fe²⁺₇Fe³⁺₂[Si₄O₁₂]₂[PO₄]₂[CO₃]O₂(OH)₄◻₂	Tric. 1 : P1
9.DC.05	Zircophyllite	K₂NaFe²⁺₇Zr₂[Si₄O₁₂]₂O₂(OH)₄F	Tric.
9.DC.05	Sveinbergeite	(H₂O)₂[Ca(H₂O)](Fe²⁺₆Fe³⁺)Ti₂[Si₄O₁₂]₂O₂(OH)₄[(OH)(H₂O)]	Tric. 1 : P1
9.DC.05	Niobophyllite	K₂NaFe²⁺₇(NbTi)[Si₄O₁₂]₂O₂(OH)₄O	Tric.
9.DC.05	Heyerdahlite	Na₂NaMn²⁺₇Ti₂[Si₄O₁₂]₂O₂(OH)₄F(H₂O)₂	Tric. 1 : P1
9.DC.05	Tarbagataite	(K◻)CaFe²⁺₇Ti₂[Si₄O₁₂]₂O₂(OH)₄(OH)	Tric. 1 : P1
9.DC.05	Astrophyllite	K₂NaFe²⁺₇Ti₂[Si₄O₁₂]₂O₂(OH)₄F	Tric. 1 : P1
9.DC.05	'Hydroastrophyllite'	[H₃O]⁺₂CaFe²⁺₇Ti₂[Si₄O₁₂]₂O₂(OH)₄O	Tric.
9.DC.05	Lobanovite	K₂Na(Fe²⁺₄Mg₂Na)Ti₂[Si₄O₁₂]₂O₂(OH)₄◻	Mon. 2/m : B2/m
9.DC.05	Niobokupletskite	K₂NaMn²⁺₇(NbTi)[Si₄O₁₂]₂O₂(OH)₄O	Tric. 1 : P1
9.DC.05	Kupletskite-(Cs)	Cs₂NaMn²⁺₇Ti₂[Si₄O₁₂]₂O₂(OH)₄F	Tric. 1 : P1
9.DC.05	Kupletskite	K₂NaMn²⁺₇Ti₂[Si₄O₁₂]₂O₂(OH)₄F	Tric. 1 : P1
9.DC.05	Laverovite	K₂NaMn²⁺₇Zr₂[Si₄O₁₂]₂O₂(OH)₄F	Tric. 1 : P1

Other InformationHide

IR Spectrum:

Lines at 3600, 1621, 1077(sh), 1056, 975, 929, 696, 649, 566, 441, 438

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for NalivkiniteHide

mindat.org URL:

https://www.mindat.org/min-31307.html
Please feel free to link to this page.

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External Links:

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

Mineral Dealers:

Buy from D. Joyce minerals

References for NalivkiniteHide

Reference List:

Uvarova, Y. A., Sokolova, E., Hawthorne, F. C., Agakhanov, A. A., Pautov, L. A. (2008) The crystal structure of nalivkinite, a new lithium member of the astrophyllite group. The Canadian Mineralogist, 46 (3) 651-659 doi:10.3749/canmin.46.3.651

Cámara, Fernando; Sokolova, Elena; Abdu, Yassir; Hawthorne, Frank C. (2010) The crystal structures of niobophyllite, kupletskite-(Cs) and Sn-rich astrophyllite: revisions to the crystal chemistry of the astrophyllite-group minerals. The Canadian Mineralogist, 48 (1). 1-16 doi:10.3749/canmin.48.1.1

Sokolova, E. (2012) Further developments in the structure topology of the astrophyllite-group minerals. Mineralogical Magazine, 76 (4) 863-882 doi:10.1180/minmag.2012.076.4.04

Agakhanov, Atali A., Pautov, Leonid A., Sokolova, Elena, Abdu, Yassir A., Karpenko, Vladimir Y. (2016) Two Astrophyllite-Supergroup Minerals: Bulgakite, A New Mineral From the Darai-Pioz Alkaline Massif, Tajikistan and Revision of the Crystal Structure and Chemical Formula of Nalivkinite. The Canadian Mineralogist, 54 (1) 33-48 doi:10.3749/canmin.1500085

Cámara, Fernando; Gagne, Olivier C.; Belakovskiy, Dmitriy I. (2017) New Mineral Names. American Mineralogist, 102 (5). 1143-1148 doi:10.2138/am-2017-nmn10258

(2017) Nalivkinite. Handbook of Mineralogy. Mineralogical Society of America

Sokolova, Elena, Cámara, Fernando, Hawthorne, Frank C., Ciriotti, Marco E. (2017) The astrophyllite supergroup: nomenclature and classification. Mineralogical Magazine, 81 (1) 143-153 doi:10.1180/minmag.2016.080.077

Localities for NalivkiniteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Tajikistan (TL)

Districts of Republican Subordination

ⓘ Dara-i-Pioz Massif (TL)

Agakhanov et al. (2008) +2 other references

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Nalivkinite

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