Arsenopalladinite
A valid IMA mineral species - grandfathered
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About Arsenopalladinite
Formula:
Pd8(As,Sb)3
Colour:
Yellowish, creamy white in reflected light.
Lustre:
Metallic
Hardness:
4
Specific Gravity:
10.40
Crystal System:
Triclinic
Member of:
Name:
For its chemical composition
Type Locality:
Likely polymorphous with stillwaterite. One of several Pd arsenide minerals, comparable to, e.g., isomertieite, Unnamed (Pd Arsenide).
Also compare with UM1993-02-AsTe:Pd.
Also compare with UM1993-02-AsTe:Pd.
Unique Identifiers
Mindat ID:
303
Long-form identifier:
mindat:1:1:303:0
Classification of Arsenopalladinite
IMA Classification of Arsenopalladinite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Pd8As3
2.AC.10c
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
A : Alloys
C : Alloys of metalloids with PGE
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
A : Alloys
C : Alloys of metalloids with PGE
2.16.5.1
2 : SULFIDES
16 : Miscellaneous
2 : SULFIDES
16 : Miscellaneous
3.12.29
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
12 : Sulphides etc. of the platinum metals
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
12 : Sulphides etc. of the platinum metals
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Apdn | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Apd | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Arsenopalladinite
Metallic
Transparency:
Opaque
Colour:
Yellowish, creamy white in reflected light.
Hardness:
4 on Mohs scale
Hardness:
VHN100=379 - 449 kg/mm2 - Vickers
Tenacity:
Malleable
Density:
10.40 g/cm3 (Measured) 11.028 g/cm3 (Calculated)
Optical Data of Arsenopalladinite
Anisotropism:
Strong - red and golden brown to blue-gray - air; khaki-brown to blue gray and bright steel-gray in oil
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 400nm | 43.9% | 44.5% |
| 420nm | 44.7% | 45.8% |
| 440nm | 45.7% | 46.5% |
| 460nm | 46.8% | 47.8% |
| 480nm | 48.1% | 49.4% |
| 500nm | 49.4% | 50.8% |
| 520nm | 50.8% | 52.4% |
| 540nm | 52.1% | 53.9% |
| 560nm | 53.2% | 55.1% |
| 580nm | 54.4% | 56.4% |
| 600nm | 55.4% | 57.3% |
| 620nm | 56.4% | 58.1% |
| 640nm | 57.0% | 58.8% |
| 660nm | 57.7% | 59.2% |
| 680nm | 58.2% | 59.8% |
| 700nm | 58.8% | 60.0% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 60.0%.
R1 shown in black, R2 shown in red
Colour in reflected light:
White, with yellowish creamy tint
Chemistry of Arsenopalladinite
Mindat Formula:
Pd8(As,Sb)3
Elements listed:
Common Impurities:
Cu
Crystallography of Arsenopalladinite
Crystal System:
Triclinic
Class (H-M):
1 - Pedial
Space Group:
P1
Cell Parameters:
a = 7.43 Å, b = 13.95 Å, c = 7.35 Å
α = 92.88°, β = 119.5°, γ = 87.85°
α = 92.88°, β = 119.5°, γ = 87.85°
Ratio:
a:b:c = 0.533 : 1 : 0.527
Unit Cell V:
662.14 ų (Calculated from Unit Cell)
Z:
6
Morphology:
Rounded grains to 1.8 mm
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 2.34 Å | (60) |
| 2.28 Å | (20) |
| 2.19 Å | (20) |
| 2.13 Å | (100) |
| 1.41 Å | (40) |
| 1.24 Å | (30) |
| 1.21 Å | (30) |
Comments:
Itabira, Brazil.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Near-surface Processes | |
| 26 : Hadean detrital minerals | |
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) | |
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 37 : Layered igneous intrusions and related PGE minerals |
Geological Setting:
Gold deposits
Type Occurrence of Arsenopalladinite
Place of Conservation of Type Material:
The Natural History Museum, London, England, 1934,72, 1977,258; Royal Ontario Museum, Toronto, Canada, M34726; National Museum of Natural History, Washington, D.C., USA, 142504.
Associated Minerals at Type Locality:
Other Language Names for Arsenopalladinite
Dutch:Arsenopalladiniet
French:Arsénopalladinite
German:Arsenopalladinit
Norwegian:Arsenopalladinitt
Spanish:Arsenopalladinita
Relationship of Arsenopalladinite to other Species
Common Associates
Associations Based on Photo Data:
| 2 photos of Arsenopalladinite associated with Native Gold | Au |
| 1 photo of Arsenopalladinite associated with Bornite | Cu5FeS4 |
| 1 photo of Arsenopalladinite associated with Palladinite | PdO |
| 1 photo of Arsenopalladinite associated with Atheneite | Pd2As0.75Hg0.25 |
| 1 photo of Arsenopalladinite associated with Native Platinum | Pt |
| 1 photo of Arsenopalladinite associated with Isomertieite | Pd11Sb2As2 |
Related Minerals - Strunz-mindat Grouping
| 2.AC. | Vadlazarenkovite | Pd8Bi1.5Te1.25As0.25 |
| 2.AC. | Törnroosite | Pd11As2Te2 |
| 2.AC.05b | Vincentite | Pd3As |
| 2.AC.05a | Atheneite | Pd2As0.75Hg0.25 |
| 2.AC.10b | Mertieite | Pd8Sb2.5As0.5 |
| 2.AC.10a | Stillwaterite | Pd8As3 |
| 2.AC.15a | Isomertieite | Pd11Sb2As2 |
| 2.AC.15a | Miessiite | Pd11Te2Se2 |
| 2.AC.15b | Pseudomertieite | Pd11(Sb,As)4 |
| 2.AC.20c | Menshikovite | Pd3Ni2As3 |
| 2.AC.20a | Stibiopalladinite | Pd5Sb2 |
| 2.AC.20b | Palarstanide | Pd5(Sn,As)2 |
| 2.AC.25c | Palladodymite | (Pd,Rh)2As |
| 2.AC.25d | Naldrettite | Pd2Sb |
| 2.AC.25b | Rhodarsenide | (Rh,Pd)2As |
| 2.AC.25e | Majakite | PdNiAs |
| 2.AC.25a | Palladoarsenide | Pd2As |
| 2.AC.25f | Palladobismutharsenide | Pd2(As,Bi) |
| 2.AC.30 | 'UM1999-02-As:NiRh' | (Rh,Ni)7As4 |
| 2.AC.30 | Polkanovite | Rh12As7 |
| 2.AC.35b | Ungavaite | Pd4Sb3 |
| 2.AC.35a | Genkinite | Pt4Sb3 |
| 2.AC.40 | Polarite | Pd(Bi,Pb) |
| 2.AC.45a | Froodite | α-PdBi2 |
| 2.AC.50 | Viteite | Pd5InAs |
| 2.AC.50 | Nipalarsite | Ni8Pd3As4 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Industrial Uses:
Palladium ore
Internet Links for Arsenopalladinite
mindat.org URL:
https://www.mindat.org/min-303.html
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References for Arsenopalladinite
Reference List:
Clark, A. M., Criddle, A. J., Fejer, E. E. (1974) Palladium arsenide-antimonides from Itabira, Minas Gerais, Brazil. Mineralogical Magazine, 39 (305). 528-543 doi:10.1180/minmag.1974.039.305.05
Fleischer, Michael, Chao, George Y., Mandarino, J. A. (1979) New mineral names. American Mineralogist, 64 (5-6) 652-659
Localities for Arsenopalladinite
Showing 50 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
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The
Itabira, Minas Gerais, Brazil