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Nalipoite

A valid IMA mineral species
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About NalipoiteHide

Formula:
NaLi2PO4
Colour:
pale yellow, white, pale blue
Lustre:
Vitreous
Hardness:
4
Specific Gravity:
2.58
Crystal System:
Orthorhombic
Name:
For Na, Li and P and O in its chemical composition.
This page provides mineralogical data about Nalipoite.


Unique IdentifiersHide

Mindat ID:
2833
Long-form identifier:
mindat:1:1:2833:8

IMA Classification of NalipoiteHide

Classification of NalipoiteHide

8.AA.25

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
A : With small cations (some also with larger ones)
38.4.10.3

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
4 : AXO4
19.1.5

19 : Phosphates
1 : Phosphates of the alkali metals

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
NlpIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of NalipoiteHide

Vitreous
Transparency:
Transparent, Translucent
Colour:
Pale yellow, white, pale blue
Streak:
White
Hardness:
Tenacity:
Very brittle
Cleavage:
Distinct/Good
{100}, {010}, {001}, {110} good; distinct on probable
{101}.
Fracture:
Irregular/Uneven
Density:
2.58(1) g/cm3 (Measured)    2.587 g/cm3 (Calculated)

Optical Data of NalipoiteHide

Type:
Biaxial (-)
RI values:
nα = 1.533(1) nβ = 1.540(1) nγ = 1.541(1)
2V:
Measured: 49° (1), Calculated: 41°
Max. Birefringence:
δ = 0.008
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
None to Very Low
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
weak
Pleochroism:
Non-pleochroic
Comments:
X = a, Y = c, Z = b

Chemistry of NalipoiteHide

Mindat Formula:
NaLi2PO4
Element Weights:
Element% weight
O48.541 %
P23.493 %
Na17.437 %
Li10.529 %

Calculated from ideal end-member formula.
O
P
Na
Li

Crystallography of NalipoiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Cell Parameters:
a = 6.884(2) Å, b = 9.976(4) Å, c = 4.927(2) Å
Ratio:
a:b:c = 0.69 : 1 : 0.494
Unit Cell V:
338.36 ų (Calculated from Unit Cell)
Z:
4
Morphology:
anhedral to subhedral blocky grains, to 2 mm.
Comment:
Space Group: Pmnb.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005274NalipoiteErcit T S (1991) The crystal structure of nalipoite The Canadian Mineralogist 29 569-57319910293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.02 Å(100)
3.507 Å(100)
3.441 Å(100)
2.833 Å(40)
2.712 Å(40)
2. 493 Å(90)
2. 462 Å(90)
1.721 Å(40)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
9 : Lava/xenolith minerals (hornfels, sanidinite facies)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of NalipoiteHide

General Appearance of Type Material:
Anhedral to subhedral blocky grains up to 2 mm in sodalite or analcime and as irregular grains (0.2 mm) in cavities in sodalite syenite xenoliths in the nepheline syenite.
Place of Conservation of Type Material:
Canadian Museum of Nature, Ottawa - CT (2)
Royal Ontario Museum, Toronto - CT
Geological Setting of Type Material:
Sodalite syenite xenoliths in nepheline syenite
Associated Minerals at Type Locality:

Synonyms of NalipoiteHide

Other Language Names for NalipoiteHide

Dutch:Nalipoiet
German:Nalipoit
Simplified Chinese:磷钠锂石
Spanish:Nalipoita
Traditional Chinese:磷鈉鋰石

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Nalipoite associated with UssingiteNa2AlSi3O8OH
1 photo of Nalipoite associated with Wurtzite(Zn,Fe)S
1 photo of Nalipoite associated with VuonnemiteNa11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH)

Related Minerals - Strunz-mindat GroupingHide

8.AA.05AlarsiteAlAsO4Trig. 32 : P3121
8.AA.05BerliniteAlPO4Trig. 32 : P3121
8.AA.10BerylloniteNaBePO4Mon. 2/m : P21/b
8.AA.15HurlbutiteCaBe2(PO4)2Mon. 2/m : P21/b
8.AA.20LithiophosphateLi3PO4Orth. mm2 : Pmn21
8.AA.30OlympiteNa5Li(PO4)2Orth. 222 : P212121

Fluorescence of NalipoiteHide

Not fluorescent

Other InformationHide

Notes:
Readily in 1:1 HNO3, less readily in 1:1 HCl and slowly in 1:1 H2SO4.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for NalipoiteHide

References for NalipoiteHide

Localities for NalipoiteHide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada (TL)
 
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
Chao et al. (1991)
Russia
 
  • Murmansk Oblast
    • Lovozersky District
      • Karnasurt Mountain
        • Karnasurt mine
Pekov (2005)
 
and/or  
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