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Lengenbachite

A valid IMA mineral species - grandfathered
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About LengenbachiteHide

Formula:
Ag4Cu2Pb18As12S39
Colour:
Steel-gray, iridescent tarnish at times
Lustre:
Metallic
Hardness:
1½ - 2
Specific Gravity:
5.8 - 5.85
Crystal System:
Triclinic
Name:
From the type locality, the Lengenbach quarry, Binntal, Valais, Switzerland.
This page provides mineralogical data about Lengenbachite.


Unique IdentifiersHide

Mindat ID:
2373
Long-form identifier:
mindat:1:1:2373:9

Similar NamesHide

GengenbachiteA valid IMA mineral speciesKFe33+(PO3OH)4[PO2(OH)2]2 · 6H2O

IMA Classification of LengenbachiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ag1+4Cu1+2Pb2+18As3+12S2-39
First published:
1904

Classification of LengenbachiteHide

2.HF.30

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
F : With SnS and PbS archetype structure units
3.3.7.1

3 : SULFOSALTS
3 : 3 <ø < 4
5.7.40

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
7 : Sulpharsenites etc. of Pb and other metals

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
LenIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of LengenbachiteHide

Metallic
Transparency:
Opaque
Colour:
Steel-gray, iridescent tarnish at times
Streak:
Brown-Black
Hardness:
1½ - 2 on Mohs scale
Hardness:
VHN100=35 - Vickers
Tenacity:
Malleable
Cleavage:
Perfect
Perfect on {100}; two others across the flat {100}
face.
Density:
5.8 - 5.85 g/cm3 (Measured)    5.78 g/cm3 (Calculated)

Optical Data of LengenbachiteHide

Anisotropism:
Weak
Reflectivity:
WavelengthR1 (%)R2 (%)
400nm38.9%40.0%
420nm38.5%39.8%
440nm38.2%39.4%
460nm37.6%39.0%
480nm37.3%38.7%
500nm36.8%38.3%
520nm36.3%37.9%
540nm35.9%37.4%
560nm35.5%36.9%
580nm35.3%36.5%
600nm35.1%36.1%
620nm34.7%35.7%
640nm34.2%35.2%
660nm33.5%34.4%
680nm32.8%33.7%
700nm32.0%32.9%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 40.0%.
R1 shown in black, R2 shown in red

Chemistry of LengenbachiteHide

Mindat Formula:
Ag4Cu2Pb18As12S39
Element Weights:
Element% weight
Pb57.933 %
S19.425 %
As13.965 %
Ag6.702 %
Cu1.974 %

Calculated from ideal end-member formula.
Common Impurities:
Fe,Sb

Crystallography of LengenbachiteHide

Crystal System:
Triclinic
Twinning:
On {100}; twin lamellae seen in polished section.
Comment:
Point Group: 1 or 1; Two subcells are recognized: the first (pseudotetragonal) has a = 36.892(20) b = 5.842(5) c = 5.847(5) α = 90.00◦ β = 92.00◦ γ = 91.01(1)◦ Z = 6 and the second (pseudohexagonal) has a = 36.892(20) b = 3.895(4) c = 6.378(7) α = 90.00◦ β = 90.00◦ γ = 91.01(1)◦ Z=6

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.06 Å(100)
2.84 Å(90)
4.60 Å(30)
2.93 Å(20)
2.04 Å(20)
9.31 Å(10)
7.69 Å(10)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])

Type Occurrence of LengenbachiteHide

Other Language Names for LengenbachiteHide

Common AssociatesHide

Associations Based on Photo Data:
34 photos of Lengenbachite associated with PyriteFeS2
32 photos of Lengenbachite associated with JordanitePb14As6S23
26 photos of Lengenbachite associated with DolomiteCaMg(CO3)2
16 photos of Lengenbachite associated with SphaleriteZnS
7 photos of Lengenbachite associated with RealgarAs4S4
6 photos of Lengenbachite associated with Tennantite SubgroupCu6(Cu4C2+2)As4S12S
5 photos of Lengenbachite associated with DufrénoysitePb2As2S5
4 photos of Lengenbachite associated with MarcasiteFeS2
3 photos of Lengenbachite associated with Wurtzite(Zn,Fe)S
2 photos of Lengenbachite associated with SmithiteAgAsS2

Related Minerals - Strunz-mindat GroupingHide

2.HF.RamositePb25.7Sn8.3Mn3.4Sb6.4S56.2Mon.
2.HF.20VrbaiteHg3Tl4As8Sb2S20Orth. mmm(2/m2/m2/m) : Cmca
2.HF.25bFranckeiteFe2+(Pb,Sn2+)6Sn4+2Sb2S14Tric. 1 : P1
2.HF.25aMerelaniiteMo4Pb4VSbS15Tric. 1
2.HF.25aAbramovitePb2SnInBiS7Tric. 1 : P1
2.HF.25aLévyclauditePb8Sn7Cu3(Bi,Sb)3S28Tric. 1
2.HF.25aCylindritePb3Sn4FeSb2S14Tric. 1 : P1
2.HF.25b'Potosíite'Pb6Sn3FeSb3S16Tric.
2.HF.25bCoiraite(Pb,Sn)12.5Sn5FeAs3S28Mon.
2.HF.25b v'Plumbostannite'Pb2Fe2Sn2Sb2S11

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for LengenbachiteHide

References for LengenbachiteHide

Localities for LengenbachiteHide

Showing 7 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Northwest Territories
    • North Slave Region
      • Yellowknife
RIDLAND (1941) +1 other reference
RIDLAND (1941)
Iran
 
  • Hamadan Province
    • Malayer County
حسینخانی; ملاصالحی (2015)
Russia
 
  • Zabaykalsky Krai
G.I. Shvedov et al. (2019)
    • Nerchinsky District
      • Adun-Cholon Range
Kasatkin et al. (2014)
Switzerland (TL)
 
  • Valais
    • Goms
      • Binn
        • Fäld
Nature (1904) +1 other reference
50. (in German) +1 other reference
 
and/or  
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