Jianshuiite
A valid IMA mineral species
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About Jianshuiite
Formula:
(Mg,Mn,Ca)Mn3O7 · 3H2O
Colour:
Brown to brownish-black.
Hardness:
1½ - 2
Crystal System:
Trigonal
Member of:
Name:
Named in 1992 by G. Yan, S. Zhang, M. Zhao, J. Ding, D. Li for Jianshui county which includes the type locality.
Isostructural with:
In the structure Mg is in the interlayer space, above and below the vacant sites of the Mn-O octahedral sheet. Mg has octahedral coordination, being linked to 3 oxygen atoms of the octahedral layer and 3 ones belonging to interlayer-residing water. Some Ni and maybe Mn2+ may be located at the Mg site.
Unique Identifiers
Mindat ID:
2094
Long-form identifier:
mindat:1:1:2094:3
IMA Classification of Jianshuiite
Classification of Jianshuiite
4.FL.20
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
F : Hydroxides (without V or U)
L : Hydroxides with H2O +- (OH); sheets of edge-sharing octahedra
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
F : Hydroxides (without V or U)
L : Hydroxides with H2O +- (OH); sheets of edge-sharing octahedra
7.8.2.3
7 : MULTIPLE OXIDES
8 : AB3X7
7 : MULTIPLE OXIDES
8 : AB3X7
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Jia | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Jianshuiite
Colour:
Brown to brownish-black.
Hardness:
1½ - 2 on Mohs scale
Chemistry of Jianshuiite
Mindat Formula:
(Mg,Mn,Ca)Mn3O7 · 3H2O
Element Weights:
Elements listed:
Common Impurities:
Ca
Crystallography of Jianshuiite
Crystal System:
Trigonal
Class (H-M):
3 - Rhombohedral
Space Group:
R3
Cell Parameters:
a = 7.5409(4) Å, c = 20.8079(14) Å
Ratio:
a:c = 1 : 2.759
Unit Cell V:
1024.73 ų
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 6.965 Å | (100) |
| 5.539 Å | (3) |
| 4.086 Å | (8) |
| 3.483 Å | (11) |
| 2.449 Å | (7) |
| 2.396 Å | (6) |
| 2.230 Å | (23) |
Comments:
Nearly indistinguishable from chalcophanite and
aurorite.
aurorite.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47e : [Vanadates, chromates, manganates] |
Type Occurrence of Jianshuiite
Synonyms of Jianshuiite
Other Language Names for Jianshuiite
Relationship of Jianshuiite to other Species
Member of:
Other Members of Chalcophanite Group:
| Aurorite | Mn2+Mn4+3O7 · 3H2O | Trig. 3 : R3 |
| Chalcophanite | ZnMn4+3O7 · 3H2O | Trig. 3 : R3 |
| Ernienickelite | NiMn3O7 · 3H2O | Trig. 3 : R3 |
Common Associates
Associations Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
| 4.FL. | Trébeurdenite | Fe2+2Fe3+4O2(OH)10CO3 · 3H2O |
| 4.FL. | Mariakrite | [Ca4Al2(OH)12(H2O)4][Fe2S4] |
| 4.FL.05 | Muskoxite | Mg7Fe4O13 · 10H2O |
| 4.FL.05 | Jamborite | Ni2+1-xCo3+x(OH)2-x(SO4)x · nH2O |
| 4.FL.05 | Mössbauerite | Fe3+6O4(OH)8[CO3] · 3H2O |
| 4.FL.05 | Meixnerite | Mg6Al2(OH)16(OH)2 · 4H2O |
| 4.FL.05 | Woodallite | Mg6Cr2(OH)16Cl2 · 4H2O |
| 4.FL.05 | Fougèrite | Fe2+4Fe3+2(OH)12[CO3] · 3H2O |
| 4.FL.05 | Dritsite | Li2Al4(OH)12Cl2 · 3H2O |
| 4.FL.05 | Rotemite | Ca4Cr2(OH)12Cl2 · 4H2O |
| 4.FL.05 | Iowaite | Mg6Fe3+2(OH)16Cl2 · 4H2O |
| 4.FL.10 | Hydrocalumite | Ca4Al2(OH)12(Cl,CO3,OH)2 · 4H2O |
| 4.FL.15 | Kuzelite | Ca4Al2(OH)12[SO4] · 6H2O |
| 4.FL.20 | Ernienickelite | NiMn3O7 · 3H2O |
| 4.FL.20 | Aurorite | Mn2+Mn4+3O7 · 3H2O |
| 4.FL.20 | Chalcophanite | ZnMn4+3O7 · 3H2O |
| 4.FL.25 | Woodruffite | Zn2+x/2(Mn4+1-xMn3+x)O2 · yH2O |
| 4.FL.30 | Asbolane | (Ni,Co)2-xMn4+(O,OH)4 · nH2O |
| 4.FL.30 va | 'Lampadite' | Cu, Mn, O, H |
| 4.FL.35 | Buserite | Na4Mn14O27 · 21H2O |
| 4.FL.40 | Takanelite | (Mn,Ca)Mn4O9 · H2O |
| 4.FL.40 | Ranciéite | (Ca,Mn2+)0.2(Mn4+,Mn3+)O2 · 0.6H2O |
| 4.FL.45 | Birnessite | (Na,Ca)0.5(Mn4+,Mn3+)2O4 · 1.5H2O |
| 4.FL.55 | Cianciulliite | Mn(Mg,Mn)2Zn2(OH)10 · 2-4H2O |
| 4.FL.60 | Jensenite | Cu3[TeO6] · 2H2O |
| 4.FL.65 | Leisingite | Cu2MgTe6+O6 · 6H2O |
| 4.FL.70 | Magnesiohongruiite-(Fe3+) | (Mg2Fe3+)Fe3+NbO7(OH) |
| 4.FL.70 | Akdalaite | Al10O14(OH)2 |
| 4.FL.75 | Cafetite | CaTi2O5 · H2O |
| 4.FL.80 | Mourite | UMo5O12(OH)10 |
| 4.FL.85 | Deloryite | Cu4(UO2)(MoO4)2(OH)6 |
| 4.FL.90 | Lagalyite | Ca2xMn1-xO2 · 1.5-2H2O |
| 4.FL.95 | 'Tunnerite' | |
| 4.FL.100 | Carbocalumite | Ca4Al2(OH)12(CO3) · 6H2O |
| 4.FL.100 | Mampsisite | Ca4Al2(CO3)(OH)12 · 5H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Jianshuiite
mindat.org URL:
https://www.mindat.org/min-2094.html
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References for Jianshuiite
Reference List:
Localities for Jianshuiite
Showing 5 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Atlantic Ocean | |
| Post et al. (2016) |
Australia | |
| Putzolu et al. (2018) |
China (TL) | |
| Yan Guiyin et al. (1992) |
Poland | |
| Pieczka et al. (2015) +2 other references |
Spain | |
| Calvo Rebollar (2018) |
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Ojos Negros iron mines, Ojos Negros, Teruel, Aragon, Spain