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Gupeiite

A valid IMA mineral species
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About GupeiiteHide

06679620017271923645871.jpg
The Gubeikou (Gupeikou) Great Wall
Formula:
Fe3Si
Colour:
Black to steel-gray
Lustre:
Metallic
Hardness:
5
Specific Gravity:
7.29 (Calculated)
Crystal System:
Isometric
Name:
Named by Yu Zuxiang for an eastern passageway, Gubeikou (Gupeikou), of the Great Wall of China. Gupeiite was found with and described at the same time as xifengite, named for another passageway of the Great Wall.
One of many natural Fe-Si phases; beside the approved species (listed below) you may want to compare Unnamed (Fe silicide I), Unnamed (Fe silicide II) and UM2000-60-Si:Fe.


Unique IdentifiersHide

Mindat ID:
1780
Long-form identifier:
mindat:1:1:1780:6

IMA Classification of GupeiiteHide

Classification of GupeiiteHide

1.BB.30

1 : ELEMENTS (Metals and intermetallic alloys; metalloids and nonmetals; carbides, silicides, nitrides, phosphides)
B : Metallic Carbides, Silicides, Nitrides, Phosphides and Hydrides
B : Silicides
Dana 7th ed.:
1.1.33.5
1.1.23.2

1 : NATIVE ELEMENTS AND ALLOYS
1 : Metals, other than the Platinum Group
2.7

2 : Carbides, Nitrides, Silicides and Phosphides

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
GupIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of GupeiiteHide

Metallic
Transparency:
Opaque
Colour:
Black to steel-gray
Streak:
Black
Hardness:
Hardness:
VHN50=494 - 514 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
None Observed
Density:
7.29 g/cm3 (Calculated)
Comment:
Dunn gives calc = 7.15

Optical Data of GupeiiteHide

Type:
Isotropic
Reflectivity:
WavelengthR1 (%)
402nm48.4%
439nm48.4%
480nm51.0%
495nm51.2%
546nm53.5%
590nm53.4%
624nm53.9%
644nm54.0%
657nm54.3%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 54.3%.
Colour in reflected light:
Grayish white with a yellow tint
Internal Reflections:
None

Chemistry of GupeiiteHide

Mindat Formula:
Fe3Si
Element Weights:
Element% weight
Fe85.643 %
Si14.357 %

Calculated from ideal end-member formula.

Crystallography of GupeiiteHide

Crystal System:
Isometric
Class (H-M):
m3m(4/m32/m) - Hexoctahedral
Space Group:
Fm3m
Setting:
Fm3m
Cell Parameters:
a = 5.670(5) Å
Unit Cell V:
182.28 ų (Calculated from Unit Cell)
Z:
4
Comment:
Space Group: [(by analogy to synthetic Fe3Si).

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0019761GupeiiteKanematsu K (1986) Stability of crystal structure of (Fe,V)3M and (Fe,Ni)3M (M=Si,Ge,Sn) and its analysis based on rigid band model Transactions of the Japan Institute of Metals 27 225-2321986synthetic0293
0019762GupeiiteBuschow K H J, van Engen P G, Jongebreur R (1983) Magneto-optical properties of metallic ferromagnetic materials Journal of Magnetism and Magnetic Materials 38 1-221983synthetic0293
0019760GupeiiteFarquhar M C M, Lipson H, Weill A R (1945) An X-ray study of iron-rich iron-silicon alloys Journal of the Iron and Steel Institute 152 457-4721945synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.26 Å(30)
2.83 Å(30)
2.00 Å(90)
1.706 Å(20)
1.415 Å(60)
1.156 Å(100)
1.003 Å(70)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
7 : Ultramafic igneous rocks
Near-surface Processes
26 : Hadean detrital minerals

Type Occurrence of GupeiiteHide

General Appearance of Type Material:
Cores of spheres 0.1-0.5 mm in diameter.
Place of Conservation of Type Material:
Institute of Geology, Chinese Academy of Geological Sciences, Beijing, China.
Geological Setting of Type Material:
Found in a placer deposit, but thought to be of extraterrestrial origin.
Associated Minerals at Type Locality:

Synonyms of GupeiiteHide

Other Language Names for GupeiiteHide

Dutch:Gupeiiet
German:Gupeiit
Simplified Chinese:古北矿
Spanish:Gupeiita

Common AssociatesHide

Associations Based on Photo Data:
5 photos of Gupeiite associated with XifengiteFe5Si3
5 photos of Gupeiite associated with NaquiteFeSi
1 photo of Gupeiite associated with JingsuiiteTiB2
1 photo of Gupeiite associated with CorundumAl2O3
1 photo of Gupeiite associated with ToledoiteTiFeSi
1 photo of Gupeiite associated with OsborniteTiN
1 photo of Gupeiite associated with ZiroiteZrO2

Related Minerals - Strunz-mindat GroupingHide

1.BB.ToledoiteTiFeSiOrth. mm2 : Ima2
1.BB.ZangboiteTiFeSi2Orth. mmm(2/m2/m2/m) : Pbam
1.BB.KangjinlaiteTi11Si10Tet. 4/mmm(4/m2/m2/m) : I4/mmm
1.BB.BrownleeiteMnSiIso. 23 : P213
1.BB.YeiteTiSiOrth. mmm(2/m2/m2/m) : Pnma
1.BB.05MavlyanoviteMn5Si3Hex. 6/mmm(6/m2/m2/m) : P63/mcm
1.BB.05SuessiteFe3SiIso. m3m(4/m32/m) : Im3m
1.BB.10'UM2001-18-Si:CuPtSn'(Cu,Pt)4Si
1.BB.10Perryite(Ni,Fe)5(Si,P)2Trig. 3m : R3c
1.BB.15NaquiteFeSiIso. 23 : P213
1.BB.20LinzhiiteFeSi2Tet. 4/mmm(4/m2/m2/m) : P4/mmm
1.BB.25LuobusaiteFe0.84Si2Orth. mmm(2/m2/m2/m) : Cmca
1.BB.35HapkeiteFe2SiIso. m3m(4/m32/m) : Pm3m
1.BB.40XifengiteFe5Si3Hex. 6/mmm(6/m2/m2/m) : P63/mcm
1.BB.45CarletonmooreiteNi3SiIso. m3m(4/m32/m) : Pm3m
1.BB.55PalladosilicidePd2SiHex. 6m2 : P62m
1.BB.65ZhiqiniteTiSi2Orth. mmm(2/m2/m2/m) : Fddd

Other InformationHide

Notes:
Strongly magnetic
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for GupeiiteHide

References for GupeiiteHide

Localities for GupeiiteHide

Showing 11 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Bulgaria
 
  • Vidin Province
    • Vidin Municipality
      • Koshava
Rappenglück (2022)
China (TL)
 
  • Hebei
    • Chengde
Yu (1984)
Israel
 
  • Haifa District
    • Kishon river
      • Kishon Mid Reach zone 2
        • Mount Carmel
Griffin et al. (2016) +1 other reference
Poland
 
  • Lower Silesian Voivodeship
    • Kłodzko County
Kruszewski et al. (2014)
      • Nowa Ruda
        • Piast Mine
Kruszewski et al. (2014)
Russia
 
  • Bashkortostan
    • Ishimbaysky District
Rappenglück (2022)
  • Sverdlovsk Oblast
    • Nizhnyaya Tura
Pavel M. Kartashov (n.d.) +1 other reference
  • Zabaykalsky Krai
    • Tungokochensky District
Rappenglück (2022) +1 other reference
Tajikistan
 
  • Districts of Republican Subordination
Rappenglück (2022)
Ukraine
 
  • Donetsk Oblast
    • Makiivka
Steffen Möckel EDS analysis (2005)
Uzbekistan
 
  • Tashkent
    • Chatkal-Kuraminskii Range
      • Arashan Mountain
Tony Nikischer EDS/SEM analysis
 
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