Anthrax

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Ruby

Mysore District, Karnataka, India

Ruby

John Saul mine, Tsavo West, Voi, Taita-Taveta County, Kenya

Ruby

Mysore corundum deposits, Karnataka, India

Ruby

Mysore District, Karnataka, India

Ruby

John Saul mine, Tsavo West, Voi, Taita-Taveta County, Kenya

Ruby

Mysore corundum deposits, Karnataka, India

Ruby

Mysore District, Karnataka, India

Ruby

John Saul mine, Tsavo West, Voi, Taita-Taveta County, Kenya

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About AnthraxHide

Synonym of:

Ruby, Spinel

A name used for Ruby and Red Spinel

Unique IdentifiersHide

Mindat ID:

8448

Long-form identifier:

mindat:1:1:8448:8

Chemical AnalysisHide

Oxide wt%:

	2	3	4	5	6	7
SiO₂	0.08 %		0.01 %	0.03 %	0.03 %	0.03 %
TiO₂	0.10 %	0.01 %	0.41 %	0.01 %
Al₂O₃	59.42 %	69.75 %	63.77 %	69.41 %	55.61 %	62.21 %
Ga₂O₃	0.01 %	0.01 %	0.04 %	0.02 %	0.02 %
V₂O₃	0.06 %	0.01 %	0.23 %	0.08 %	0.01 %
Cr₂O₃	8.66 %		0.85 %	0.11 %	10.68 %
Fe₂O₃*	0.60 %			0.06 %	0.70 %
FeO*	9.70 %	6.19 %	20.16 %	7.74 %	15.64 %
MnO	0.09 %	0.23 %	0.11 %	0.13 %	0.39 %	0.07 %
CoO	0.02 %		0.05 %		0.11 %
NiO	0.40 %		0.02 %	0.01 %	0.16 %
ZnO	0.08 %	0.01 %	0.23 %	0.38 %	0.71 %
MgO	20.40 %	23.89 %	14.40 %	22.98 %	15.48 %	13.00 %
FeO						22.54 %
CaO						0.12 %
Total:	99.62 %	100.1 %	100.28 %	100.96 %	99.54 %	97.97 %

Empirical formulas:

Sample ID	Empirical Formula
1	(Mg_0.69Fe_0.34)Al_1.92Si_0.04O₄
2	(Mg_0.78Fe²⁺_0.21Ni_0.01)(Al_1.80Cr_0.18Fe³⁺_0.01)O₄
3	(Mg_0.87Fe²⁺_0.13)(Al_2.00)O₄
4	(Mg_0.56Fe²⁺_0.44)(Al_1.96Cr_0.02Ti_0.01)O₄
5	(Mg_0.83Fe²⁺_0.16Zn_0.01)Al_1.99O₄
6	(Mg_0.62Fe²⁺_0.35Mn²⁺_0.01Zn_0.01)(Al_1.76Cr_0.23Fe³⁺_0.01)O₄

Sample references:

ID	Locality	Reference	Notes
1	Kjøde, Selje, Stad, Vestland, Norway	Wikstr	A coarse-grained spinel-plagioclase symplectite in a kyanite-eclogite. Sample has been taken from Eskola's (1921)original material.
2	Kilbourne Hole, Doña Ana County, New Mexico, USA	Frank K. Mazdab collection; sample FKM-162; https://www.rockptx.com/fkm-151-to-fkm-175/#FKM-162	deep green (in thin section) spinel accompanying forsterite, enstatite and diopside, in lherzolite xenolith in basalt
3	Andranokaolo thorianite deposit, Tranomaro, Amboasary Sud District, Anosy, Madagascar	Frank K. Mazdab collection; sample FKM-191; https://www.rockptx.com/fkm-176-to-fkm-200/#FKM-191	spinel with hibonite and abundant corundum and anorthite, in Ca-Al-rich granulite
4	Pennycross sapphire occurrence, Loch Scridain area, Isle of Mull, Argyll and Bute, Scotland, UK	Frank K. Mazdab collection; sample FKM-189; https://www.rockptx.com/fkm-176-to-fkm-200/#FKM-189	scattered spinel with corundum, cordierite, mullite, sanidine, plagioclase, glass, and additional oxides in clots of sanidinite-facies metapelite ("buchite")
5	Edenville, Town of Warwick, Orange County, New York, USA	Frank K. Mazdab collection; sample FKM-184; https://www.rockptx.com/fkm-176-to-fkm-200/#FKM-184	spinel with warwickite, forsterite and clinohumite in high-grade magnesian marble
6	Longido District, Arusha Region, Tanzania	Frank K. Mazdab Collection	sparse partially-relict(?) Cr-bearing spinel as tiny inclusions within zoisite, in a zoisite+pargasite+corundum high-grade meta-gabbroid
7	Danmarkshavn eclogites, Danmarkshavn, Northeast Greenland National Park, Greenland	Cao, Wentao (2016) Metamorphic pressure-temperature paths of eclogites from The North-East Greenland Caledonides. PhD Thesis, The University of Iowa. doi:10.17077/etd.tbxxgcs0	Retrograde spinel from a sapphirine+spinel+plagioclase symplectite after kyanite in a kyanite-eclogite. EMPA analysis.

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Year	Temp (K)
0001398	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	293
0001399	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	293
0001400	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	873
0001401	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	923
0001402	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	973
0001403	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	973
0001404	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	1023
0001405	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	1073
0001406	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	1073
0001407	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	1123
0001408	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	1173
0001409	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	1173
0001410	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	1273
0001411	Spinel	Peterson R C, Lager G A, Hitterman R L (1991) A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures up to 1273 K American Mineralogist 76 1455-1458	1991	1273
0001459	Spinel	Ross C R, Armbruster T, Canil D (1992) Crystal structure refinement of a spinelloid in the system Fe3O4-Fe2SiO4 American Mineralogist 77 507-511	1992	293
0002106	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	299
0002107	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	683
0002108	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	707
0002109	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	766
0002110	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	837
0002111	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	903
0002112	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	969
0002113	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1035
0002114	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1100
0002115	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1164
0002116	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1228
0002117	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1291
0002118	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1355
0002119	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1418
0002120	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1481
0002121	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1544
0002122	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1606
0002123	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1644
0002124	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1662
0002125	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1650
0002126	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1595
0002127	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1532
0002128	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1468
0002129	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1405
0002130	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1278
0002131	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1214
0002132	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1152
0002133	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1088
0002134	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1024
0002135	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	961
0002136	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	898
0002137	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	834
0002138	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	770
0002139	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	710
0002140	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	610
0002141	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	516
0002142	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	464
0002143	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	405
0002144	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	298
0002145	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	473
0002146	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	673
0002147	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	773
0002148	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	873
0002149	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	973
0002150	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	1073
0002151	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	1173
0002152	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	1273
0002153	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	1373
0002154	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	1473
0002155	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	1573
0002156	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	1673
0002157	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	1773
0002158	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at ISIS, Rutherford Appleton Laboratory, U.K. American Mineralogist 84 299-310	1999	1873
0002159	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	364
0002160	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	374
0002161	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	420
0002162	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	502
0002163	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	563
0002164	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	636
0002165	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	707
0002166	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	778
0002167	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	848
0002168	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	916
0002169	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	984
0002170	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1080
0002171	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1116
0002172	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1182
0002173	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1232
0002174	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1311
0002175	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1376
0002176	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1441
0002177	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1506
0002178	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1573
0002179	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1639
0002180	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1676
0002181	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1671
0002182	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1622
0002183	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1557
0002184	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1492
0002185	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1427
0002186	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1362
0002187	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1299
0002188	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1235
0002189	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1171
0002190	Spinel	Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 C from in situ neutron diffraction Data collected at IPNS, Argonne National Laboratory, American Mineralogist 84 299-310	1999	1107

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Spinel'
loop_
_publ_author_name
'Peterson R C'
'Lager G A'
'Hitterman R L'
_journal_name_full 'American Mineralogist'
_journal_volume 76 
_journal_year 1991
_journal_page_first 1455
_journal_page_last 1458
_publ_section_title
;
 A time-of-flight neutron powder diffraction study of MgAl2O4 at temperatures
 up to 1273 K
 sample W, T = 293 K
;
_database_code_amcsd 0001398
_chemical_formula_sum '(Mg Al2) O4'
_cell_length_a 8.08435
_cell_length_b 8.08435
_cell_length_c 8.08435
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 528.367
_exptl_crystal_density_diffrn      3.577
_symmetry_space_group_name_H-M 'F d 3 m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2+y,1/2+z'
  '1/2+x,y,1/2+z'
  '1/2+x,1/2+y,z'
  '3/4+z,1/2-x,1/4+y'
  '3/4+z,-x,3/4+y'
  '1/4+z,1/2-x,3/4+y'
  '1/4+z,-x,1/4+y'
  '3/4-y,1/2+z,1/4-x'
  '3/4-y,+z,3/4-x'
  '1/4-y,1/2+z,3/4-x'
  '1/4-y,+z,1/4-x'
  '3/4+x,1/2-y,1/4+z'
  '3/4+x,-y,3/4+z'
  '1/4+x,1/2-y,3/4+z'
  '1/4+x,-y,1/4+z'
  '3/4-z,1/2+x,1/4-y'
  '3/4-z,+x,3/4-y'
  '1/4-z,1/2+x,3/4-y'
  '1/4-z,+x,1/4-y'
  '3/4+y,1/2-z,1/4+x'
  '3/4+y,-z,3/4+x'
  '1/4+y,1/2-z,3/4+x'
  '1/4+y,-z,1/4+x'
  '3/4-x,1/2+y,1/4-z'
  '3/4-x,+y,3/4-z'
  '1/4-x,1/2+y,3/4-z'
  '1/4-x,+y,1/4-z'
  '1/2+x,3/4-z,1/4-y'
  '1/2+x,1/4-z,3/4-y'
  '+x,3/4-z,3/4-y'
  '+x,1/4-z,1/4-y'
  '1/2-z,3/4+y,1/4+x'
  '1/2-z,1/4+y,3/4+x'
  '-z,3/4+y,3/4+x'
  '-z,1/4+y,1/4+x'
  '1/2+y,3/4-x,1/4-z'
  '1/2+y,1/4-x,3/4-z'
  '+y,3/4-x,3/4-z'
  '+y,1/4-x,1/4-z'
  '1/2-x,3/4+z,1/4+y'
  '1/2-x,1/4+z,3/4+y'
  '-x,3/4+z,3/4+y'
  '-x,1/4+z,1/4+y'
  '1/2+z,3/4-y,1/4-x'
  '1/2+z,1/4-y,3/4-x'
  '+z,3/4-y,3/4-x'
  '+z,1/4-y,1/4-x'
  '1/2-y,3/4+x,1/4+z'
  '1/2-y,1/4+x,3/4+z'
  '-y,3/4+x,3/4+z'
  '-y,1/4+x,1/4+z'
  'x,1/2+z,1/2+y'
  'x,+z,+y'
  '1/2+x,1/2+z,+y'
  '1/2+x,+z,1/2+y'
  '-z,1/2-y,1/2-x'
  '-z,-y,-x'
  '1/2-z,1/2-y,-x'
  '1/2-z,-y,1/2-x'
  'y,1/2+x,1/2+z'
  'y,+x,+z'
  '1/2+y,1/2+x,+z'
  '1/2+y,+x,1/2+z'
  '-x,1/2-z,1/2-y'
  '-x,-z,-y'
  '1/2-x,1/2-z,-y'
  '1/2-x,-z,1/2-y'
  'z,1/2+y,1/2+x'
  'z,+y,+x'
  '1/2+z,1/2+y,+x'
  '1/2+z,+y,1/2+x'
  '-y,1/2-x,1/2-z'
  '-y,-x,-z'
  '1/2-y,1/2-x,-z'
  '1/2-y,-x,1/2-z'
  '3/4+z,1/4+x,1/2-y'
  '3/4+z,3/4+x,-y'
  '1/4+z,1/4+x,-y'
  '1/4+z,3/4+x,1/2-y'
  '3/4-y,1/4-z,1/2+x'
  '3/4-y,3/4-z,+x'
  '1/4-y,1/4-z,+x'
  '1/4-y,3/4-z,1/2+x'
  '3/4+x,1/4+y,1/2-z'
  '3/4+x,3/4+y,-z'
  '1/4+x,1/4+y,-z'
  '1/4+x,3/4+y,1/2-z'
  '3/4-z,1/4-x,1/2+y'
  '3/4-z,3/4-x,+y'
  '1/4-z,1/4-x,+y'
  '1/4-z,3/4-x,1/2+y'
  '3/4+y,1/4+z,1/2-x'
  '3/4+y,3/4+z,-x'
  '1/4+y,1/4+z,-x'
  '1/4+y,3/4+z,1/2-x'
  '3/4-x,1/4-y,1/2+z'
  '3/4-x,3/4-y,+z'
  '1/4-x,1/4-y,+z'
  '1/4-x,3/4-y,1/2+z'
  '-z,3/4+x,3/4+y'
  '-z,1/4+x,1/4+y'
  '1/2-z,3/4+x,1/4+y'
  '1/2-z,1/4+x,3/4+y'
  'y,3/4-z,3/4-x'
  'y,1/4-z,1/4-x'
  '1/2+y,3/4-z,1/4-x'
  '1/2+y,1/4-z,3/4-x'
  '-x,3/4+y,3/4+z'
  '-x,1/4+y,1/4+z'
  '1/2-x,3/4+y,1/4+z'
  '1/2-x,1/4+y,3/4+z'
  'z,3/4-x,3/4-y'
  'z,1/4-x,1/4-y'
  '1/2+z,3/4-x,1/4-y'
  '1/2+z,1/4-x,3/4-y'
  '-y,3/4+z,3/4+x'
  '-y,1/4+z,1/4+x'
  '1/2-y,3/4+z,1/4+x'
  '1/2-y,1/4+z,3/4+x'
  'x,3/4-y,3/4-z'
  'x,1/4-y,1/4-z'
  '1/2+x,3/4-y,1/4-z'
  '1/2+x,1/4-y,3/4-z'
  '1/4-x,1/2+z,3/4-y'
  '1/4-x,+z,1/4-y'
  '3/4-x,1/2+z,1/4-y'
  '3/4-x,+z,3/4-y'
  '1/4+z,1/2-y,3/4+x'
  '1/4+z,-y,1/4+x'
  '3/4+z,1/2-y,1/4+x'
  '3/4+z,-y,3/4+x'
  '1/4-y,1/2+x,3/4-z'
  '1/4-y,+x,1/4-z'
  '3/4-y,1/2+x,1/4-z'
  '3/4-y,+x,3/4-z'
  '1/4+x,1/2-z,3/4+y'
  '1/4+x,-z,1/4+y'
  '3/4+x,1/2-z,1/4+y'
  '3/4+x,-z,3/4+y'
  '1/4-z,1/2+y,3/4-x'
  '1/4-z,+y,1/4-x'
  '3/4-z,1/2+y,1/4-x'
  '3/4-z,+y,3/4-x'
  '1/4+y,1/2-x,3/4+z'
  '1/4+y,-x,1/4+z'
  '3/4+y,1/2-x,1/4+z'
  '3/4+y,-x,3/4+z'
  '3/4-x,3/4-z,y'
  '3/4-x,1/4-z,1/2+y'
  '1/4-x,3/4-z,1/2+y'
  '1/4-x,1/4-z,y'
  '3/4+z,3/4+y,-x'
  '3/4+z,1/4+y,1/2-x'
  '1/4+z,3/4+y,1/2-x'
  '1/4+z,1/4+y,-x'
  '3/4-y,3/4-x,z'
  '3/4-y,1/4-x,1/2+z'
  '1/4-y,3/4-x,1/2+z'
  '1/4-y,1/4-x,z'
  '3/4+x,3/4+z,-y'
  '3/4+x,1/4+z,1/2-y'
  '1/4+x,3/4+z,1/2-y'
  '1/4+x,1/4+z,-y'
  '3/4-z,3/4-y,x'
  '3/4-z,1/4-y,1/2+x'
  '1/4-z,3/4-y,1/2+x'
  '1/4-z,1/4-y,x'
  '3/4+y,3/4+x,-z'
  '3/4+y,1/4+x,1/2-z'
  '1/4+y,3/4+x,1/2-z'
  '1/4+y,1/4+x,-z'
  '-z,-x,-y'
  '-z,1/2-x,1/2-y'
  '1/2-z,-x,1/2-y'
  '1/2-z,1/2-x,-y'
  'y,z,x'
  'y,1/2+z,1/2+x'
  '1/2+y,z,1/2+x'
  '1/2+y,1/2+z,x'
  '-x,-y,-z'
  '-x,1/2-y,1/2-z'
  '1/2-x,-y,1/2-z'
  '1/2-x,1/2-y,-z'
  'z,x,y'
  'z,1/2+x,1/2+y'
  '1/2+z,x,1/2+y'
  '1/2+z,1/2+x,y'
  '-y,-z,-x'
  '-y,1/2-z,1/2-x'
  '1/2-y,-z,1/2-x'
  '1/2-y,1/2-z,-x'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Mg   0.12500   0.12500   0.12500   0.68000   0.00304
Al   0.12500   0.12500   0.12500   0.32000   0.00304
Al   0.50000   0.50000   0.50000   0.84000   0.00887
Mg   0.50000   0.50000   0.50000   0.16000   0.00887
O   0.26148   0.26148   0.26148   1.00000   0.00671