Sigismundite
A valid IMA mineral species
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About Sigismundite
Formula:
(Ba◻)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2
Colour:
Grayish-green
Lustre:
Greasy
Specific Gravity:
3.544 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
After Pietro Sigismund (1874 - 10 July 1962), a well known collector of minerals from Valtellina, Italy, especially Val Malenco. Among other contributions, he discovered the species artinite. From 2005 to 2022 it was renamed by the IMA to arrojadite-(BaFe) (IMA 05-D) but then the historic name was revalidated (IMA 22-C).
Type Locality:
Unique Identifiers
Mindat ID:
7294
Long-form identifier:
mindat:1:1:7294:2
IMA Classification of Sigismundite
Approved
IMA Formula:
BaFe2+(CaNa2)Fe2+13Al(PO4)11(PO3OH)(OH)2
Approval year:
1994
First published:
1996
Approval history:
CNMMN redefinition 05-D, October 2005.
Historical name reapproved, IMA voting proposal 22-C.
Historical name reapproved, IMA voting proposal 22-C.
Classification of Sigismundite
8.BF.
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
F : With medium-sized and large cations, (OH, etc.):RO4< 0.5:1
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
F : With medium-sized and large cations, (OH, etc.):RO4< 0.5:1
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Ajd-BaFe | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Sigismundite
Greasy
Transparency:
Translucent
Colour:
Grayish-green
Streak:
White
Tenacity:
Brittle
Cleavage:
Distinct/Good
Two different cleavage planes, one more distinct than the other, making an angle of about 110 degrees.
Two different cleavage planes, one more distinct than the other, making an angle of about 110 degrees.
Fracture:
Irregular/Uneven
Density:
3.544 g/cm3 (Calculated)
Optical Data of Sigismundite
Type:
Biaxial
Optical Extinction:
Extinction angle is about 25 deg with respect to the elongation.
Pleochroism:
Not Visible
Chemistry of Sigismundite
Mindat Formula:
(Ba◻)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2
Element Weights:
Chemical Analysis
Oxide wt%:
| 1 | |
|---|---|
| P2O5 | 39.34 % |
| Al2O3 | 1.96 % |
| Fe2O3 | 1.34 % |
| FeO | 19.36 % |
| MgO | 2.80 % |
| MnO | 19.45 % |
| CaO | 2.28 % |
| BaO | 5.36 % |
| Na2O | 4.97 % |
| K2O | 0.63 % |
| LiO | 0.20 % |
| H2O+ | 1.45 % |
| H2O- | 0.10 % |
| F | 0.47 % |
| Total: | 99.71 % |
Crystallography of Sigismundite
Crystal System:
Monoclinic
Class (H-M):
m - Domatic
Space Group:
Bb
Setting:
Cc
Cell Parameters:
a = 16.406(5) Å, b = 9.945(3) Å, c = 24.470(5) Å
β = 105.73(2)°
β = 105.73(2)°
Ratio:
a:b:c = 1.65 : 1 : 2.461
Unit Cell V:
3,842.95 ų (Calculated from Unit Cell)
Z:
4
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0005505 | Sigismundite | Demartin F, Gramaccioli C M, Pilati T, Sciesa E (1996) Sigismundite, (Ba,K,Pb)Na3(Ca,Sr)(Fe,Mg,Mn)14Al(OH)2(PO4)12, a new Ba-rich member of the arrojadite group from Spluga Valley, Italy The Canadian Mineralogist 34 827-834 | ![]() | 1996 | Spluga Valley, Italy | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.010 Å | (100) |
| 3.178 Å | (51) |
| 2.678 Å | (42) |
| 2.523 Å | (27) |
| 2.805 Å | (25) |
| 4.519 Å | (23) |
| 2.775 Å | (21) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites |
Type Occurrence of Sigismundite
General Appearance of Type Material:
Small grayish-green lump, ~4 cm in size, somewhat similar to massive apatite, directly included in the rock.
Place of Conservation of Type Material:
Civic Museum of Natural History, Morbegno, Sondrio, Italy.
Geological Setting of Type Material:
In phengitic quartzite.
Associated Minerals at Type Locality:
Synonyms of Sigismundite
Other Language Names for Sigismundite
Relationship of Sigismundite to other Species
Member of:
Other Members of Arrojadite Group:
| Arrojadite-(BaNa) | (Ba◻)(NaNa)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 | Mon. 2/m : B2/b |
| Arrojadite-(KFe) | (KNa)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 | Mon. m : Bb |
| 'Arrojadite-(KFeNa)' | (KNa)(Fe2+◻)Ca(Na2Na)Fe2+13Al(PO4)11(PO4)(OH)2 | |
| Arrojadite-(KNa) | (KNa)(NaNa)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 | Mon. m : Bb |
| 'Arrojadite-(NaFe)' | (NaNa)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 | |
| Arrojadite-(PbFe) | (Pb◻)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 | Mon. m : Bb |
| Arrojadite-(SrFe) | (Sr◻)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 | Mon. m : Bb |
| Dickinsonite-(KMnNa) | (KNa)(Mn2+◻)Ca(Na2Na)Mn2+13Al(PO4)11(PO4)(OH)2 | Mon. 2/m : B2/b |
| 'Ferri-arrojadite-(BaNa)' | (Ba◻)(NaNa)Ca(Na2◻)Fe2+13Fe3+(PO4)11(PO3OH)(OH)2 | |
| Fluorarrojadite-(BaFe) | (Ba◻)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)F2 | Mon. m : Bb |
| Fluorarrojadite-(BaNa) | (Ba◻)(NaNa)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)F2 | Mon. m : Bb |
| 'Fluorarrojadite-(KNa)' | (KNa)(NaNa)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)F2 | |
| 'Fluorarrojadite-(NaFe)' | (NaNa)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)F2 | |
| Fluorcarmoite-(BaNa) | (Ba◻)(NaNa)Ca(Na2◻)Mg13Al(PO4)11(PO3OH)F2 | Mon. m : Bb |
| Manganoarrojadite-(KNa) | (KNa)(NaNa)Mn2+(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 | Mon. m : Bb |
Common Associates
Associations Based on Photo Data:
| 2 photos of Sigismundite associated with Fluorapatite | Ca5(PO4)3F |
| 2 photos of Sigismundite associated with Kulanite | Ba(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3 |
| 2 photos of Sigismundite associated with Gormanite | (Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O |
| 2 photos of Sigismundite associated with Barićite | (Mg,Fe)3(PO4)2 · 8H2O |
Related Minerals - Strunz-mindat Grouping
| 8.BF. | Manganoarrojadite-(KNa) | (KNa)(NaNa)Mn2+(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 |
| 8.BF.05 | Dickinsonite-(KMnNa) | (KNa)(Mn2+◻)Ca(Na2Na)Mn2+13Al(PO4)11(PO4)(OH)2 |
| 8.BF.05 | Arrojadite-(KNa) | (KNa)(NaNa)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 |
| 8.BF.05 | Fluorarrojadite-(BaNa) | (Ba◻)(NaNa)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)F2 |
| 8.BF.05 | Arrojadite-(KFe) | (KNa)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 |
| 8.BF.05 | Arrojadite-(PbFe) | (Pb◻)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 |
| 8.BF.05 | Fluorarrojadite-(BaFe) | (Ba◻)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)F2 |
| 8.BF.05 | 'Unnamed (Ba-dominant member of dickinsonite group)' | |
| 8.BF.05 | 'Unnamed (Pb-dominant member of dickinsonite group)' | |
| 8.BF.05 | Arrojadite-(SrFe) | (Sr◻)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 |
| 8.BF.05 | 'Arrojadite-(NaFe)' | (NaNa)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 |
| 8.BF.05 | Arrojadite-(BaNa) | (Ba◻)(NaNa)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)(OH)2 |
| 8.BF.05 | 'Arrojadite-(KFeNa)' | (KNa)(Fe2+◻)Ca(Na2Na)Fe2+13Al(PO4)11(PO4)(OH)2 |
| 8.BF.05 | 'Ferri-arrojadite-(BaNa)' | (Ba◻)(NaNa)Ca(Na2◻)Fe2+13Fe3+(PO4)11(PO3OH)(OH)2 |
| 8.BF.05 | 'Fluorarrojadite-(KNa)' | (KNa)(NaNa)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)F2 |
| 8.BF.05 | 'Fluorarrojadite-(NaFe)' | (NaNa)(Fe2+◻)Ca(Na2◻)Fe2+13Al(PO4)11(PO3OH)F2 |
| 8.BF.05 | Fluorcarmoite-(BaNa) | (Ba◻)(NaNa)Ca(Na2◻)Mg13Al(PO4)11(PO3OH)F2 |
| 8.BF.10 | Samuelsonite | (Ca,Ba)Ca8Fe2+2Mn2+2Al2(PO4)10(OH)2 |
| 8.BF.15 | Griphite | Na4Li2Ca6(Mn2+,Fe2+,Mg)19Al8(PO4)24(F,OH)8 |
| 8.BF.20 | Nabiasite | BaMn9(VO4)6(OH)2 |
| 8.BF.25 | Starovaite | KCu5O(VO4)3 |
| 8.BF.30 | Achyrophanite | (K,Na)3(Fe3+,Ti,Al,Mg)5O2(AsO4)5 |
| 8.BF.35 | Cryptochalcite | K2Cu5O(SO4)5 |
| 8.BF.35 | Cesiodymite | CsKCu5O(SO4)5 |
Fluorescence of Sigismundite
None
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Sigismundite
mindat.org URL:
https://www.mindat.org/min-7294.html
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References for Sigismundite
Reference List:
Demartin, F., Gramaccioli, C. M., Pilati, T., Sciesa, E. (1996) Sigismundite, (Ba,K,Pb)Na3(Ca,Sr)(Fe,Mg,Mn)14Al(OH)2(PO4)12, a new Ba-rich member of the arrojadite group from Spluga Valley, Italy. The Canadian Mineralogist, 34 (4) 827-834
Camara, F. (2006) The arrojadite enigma: I. A new formula and a new model for the arrojadite structure. American Mineralogist, 91 (8) 1249-1259 doi:10.2138/am.2006.2189
Chopin, Christian, Oberti, Roberta, Cámara, Fernando (2006) The arrojadite enigma: II. Compositional space, new members, and nomenclature of the group. American Mineralogist, 91 (8). 1260-1270 doi:10.2138/am.2006.2190
Localities for Sigismundite
Showing 7 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Canada | |
| Pavel Kartachov |
| www.mindat.org (n.d.) | |
Finland | |
| Ilkka Mikkola collection |
Germany | |
| Mücke et al. (2011) |
Italy (TL) | |
| Demartin et al. (1996) |
Rwanda | |
| von Knorring (1969) +2 other references |
USA | |
| Loomis (2011) |
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P-K pegmatite, Seinäjoki, South Ostrobothnia, Finland