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Bakhchisaraitsevite

A valid IMA mineral species
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About BakhchisaraitseviteHide

07206170017271928881727.jpg
Alexander Y. Bakhchisaraitsev
Formula:
Na2Mg5(PO4)4 · 7H2O
Colour:
Light yellow, colourless or greenish
Lustre:
Vitreous
Hardness:
2 - 2½
Specific Gravity:
2.50
Crystal System:
Monoclinic
Name:
Named in honor of Alexander Yuryevich Bakhchisaraitsev (Александр Юрьевич Бахчисарайцев) (1947–1998), crystallographer from the Geological Institute of the Kola Scientific Center of the Russian Academy of Sciences, Apatity.
Structurally related to rimkorolgite and liversidgeite.


Unique IdentifiersHide

Mindat ID:
7074
Long-form identifier:
mindat:1:1:7074:0

IMA Classification of BakhchisaraitseviteHide

Classification of BakhchisaraitseviteHide

8.CH.50

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
H : With large and medium-sized cations, RO4:H2O < 1:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
BkcIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of BakhchisaraitseviteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of BakhchisaraitseviteHide

Vitreous
Transparency:
Transparent
Colour:
Light yellow, colourless or greenish
Streak:
White
Hardness:
2 - 2½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
{001} perfect
Density:
2.50(2) g/cm3 (Measured)    2.499 g/cm3 (Calculated)
Comment:
Calculated value from Yakubovich et al. (2000).

Optical Data of BakhchisaraitseviteHide

Type:
Biaxial (+)
RI values:
nα = 1.538(1) nβ = 1.54(1) nγ = 1.543(1)
2V:
Calculated: 72.5°
Max. Birefringence:
δ = 0.005
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
None to Very Low
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
none

Chemistry of BakhchisaraitseviteHide

Mindat Formula:
Na2Mg5(PO4)4 · 7H2O
Element Weights:
Element% weight
O54.638 %
P18.396 %
Mg18.044 %
Na6.827 %
H2.095 %

Calculated from ideal end-member formula.
O
P
Mg
Na
H

Crystallography of BakhchisaraitseviteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 8.3086(8) Å, b = 12.906(1) Å, c = 17.486(2) Å
β = 102.01(1)°
Ratio:
a:b:c = 0.644 : 1 : 1.355
Unit Cell V:
1834 ų
Z:
4
Twinning:
None observed
Comment:
From Yakubovich et al. (2000).

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005687BakhchisaraitseviteYakubovich O V, Massa W, Liferovich R P, Pakhomovsky Y A (2000) The crystal structure of bakhchisaraitsevite, [Na2(H2O)2]{(Mg4.5Fe0.5)(PO4)4(H2O)5}, a new mineral species of hydrothermal origin from the Kovdor phoscorite - carbonatite complex, Russia The Canadian Mineralogist 38 831-8382000Kovdor phoscorite - carbonatite complex, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.31 Å(33)
8.56 Å(100)
3.496 Å(23)
3.314 Å(23)
2.849 Å(33)
2.675 Å(25)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47)
Stage 4b: Highly evolved igneous rocks>3.0
36 : Carbonatites, kimberlites, and related igneous rocks
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
49 : Oxic cellular biomineralization (see also #44)<0.54
50 : Coal and/or oil shale minerals<0.36
Stage 10b: Anthropogenic minerals<10 Ka
54 : Coal and other mine fire minerals (see also #51 and #56)

Type Occurrence of BakhchisaraitseviteHide

General Appearance of Type Material:
Fan-shaped aggregates or as single bladed tabular crystals up to 0.5 × 1.5 × 2 mm.
Place of Conservation of Type Material:
Mining Museum of the Saint Petersburg Mining Institute, Russia, and at the Geological Museum of the University of Oulu, Finland.
Geological Setting of Type Material:
In voids within veins of vuggy dolomite carbonatite
Associated Minerals at Type Locality:

Synonyms of BakhchisaraitseviteHide

Other Language Names for BakhchisaraitseviteHide

Common AssociatesHide

Associations Based on Photo Data:
6 photos of Bakhchisaraitsevite associated with DolomiteCaMg(CO3)2
4 photos of Bakhchisaraitsevite associated with GirvasiteNaCa2Mg3(PO4)3(CO3)(H2O)6
2 photos of Bakhchisaraitsevite associated with MinyuliteKAl2(PO4)2F · 4H2O

Related Minerals - Strunz-mindat GroupingHide

8.CH.GeorgeliuiteCa2Mn3+3O2(AsO4)3(H2O)2 · H2OMon. m : Bm
8.CH.05Natrowalentaite[Fe3+0.5Na0.5(H2O)6][NaAs3+2(Fe3+2.33W6+0.67)(PO4)2O7]Orth. mmm(2/m2/m2/m) : Imma
8.CH.05Walentaite[Mn2+(H2O)6][◻As3+3Fe3+3(PO4)2O7]Orth. mmm(2/m2/m2/m) : Imma
8.CH.05Halilsarpite[Mg(H2O)6][CaAs3+2(Fe3+2.67Mo6+0.33)(AsO4)2O7]Orth. mmm(2/m2/m2/m) : Imma
8.CH.10AnapaiteCa2Fe2+(PO4)2 · 4H2OTric. 1 : P1
8.CH.15PicropharmacoliteCa4Mg(AsO4)2(HAsO4)2 · 11H2OTric. 1 : P1
8.CH.20Dittmarite(NH4)Mg(PO4) · H2OOrth. mm2 : Pmn21
8.CH.20Niahite(NH4)Mn2+(PO4) · H2OOrth. mm2 : Pmn21
8.CH.25TaranakiteK3Al5(PO3OH)6(PO4)2 · 18H2OTrig. 3m(32/m) : R3c
8.CH.25FrancoanelliteK3Al5(PO3OH)6(PO4)2 · 12H2OTrig.
8.CH.25Macivorite(NH4)3Al5(PO3OH)6(PO4)2 · 18H2OTrig. 3m(32/m) : R3c
8.CH.30Schertelite(NH4)2MgH2(PO4)2 · 4H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CH.35Hannayite(NH4)2Mg3H4(PO4)4 · 8H2OTric. 1 : P1
8.CH.40HazeniteKNaMg2(PO4)2 · 14H2OOrth. mmm(2/m2/m2/m)
8.CH.40Struvite-(K)KMg(PO4) · 6H2OOrth. mm2 : Pmn21
8.CH.40Struvite(NH4)Mg(PO4) · 6H2OOrth. mm2 : Pmn21
8.CH.45Rimkorolgite(Mg,Mn)5(Ba,Sr,Ca)(PO4)4 · 8H2OOrth.
8.CH.55SmolyaninoviteCo3Fe3+2(AsO4)4 · 11H2OOrth.
8.CH.55FahleiteCaZn5Fe3+2(AsO4)6 · 14H2OOrth.
8.CH.60Barahonaite-(Fe)(Ca,Cu,Na,Fe3+,Al)12Fe3+2(AsO4)8(OH,Cl)x · nH2OMon. 2/m : P2/b
8.CH.60Barahonaite-(Al)(Ca,Cu,Na,Fe3+,Al)12Al2(AsO4)8(OH,Cl)x · nH2OMon. 2/m : P2/b
8.CH.70EpifanoviteNaCaCu5(PO4)4[AsO2(OH)2] · 7H2OMon. 2/m : P21/m
8.CH.75Esdanaite-(Ce)NaMnCe(PO4)2 · 4H2OOrth. 222 : P212121

Fluorescence of BakhchisaraitseviteHide

Not fluorescent

Other InformationHide

Notes:
Soluble in 10% HCl
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BakhchisaraitseviteHide

References for BakhchisaraitseviteHide

Reference List:

Localities for BakhchisaraitseviteHide

Showing 5 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Chile
 
  • Antofagasta
    • Antofagasta Province
      • Mejillones
Joy Desor material. EDS verified. Jason ...
XRD by Joachim Lorenz +1 other reference
Russia
 
  • Chelyabinsk Oblast
    • Korkinsky District
      • Korkino
  • Murmansk Oblast
    • Kovdorsky District
Belovitskaya et al. (2004) +1 other reference
Liferovich et al. (2000) +4 other references
 
and/or  
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