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Blatterite

A valid IMA mineral species
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About BlatteriteHide

07125160017271921663209.jpg
Fritz Blatter july 2019
Formula:
Sb5+3(Mn3+,Fe3+)9(Mn2+,Mg)35(BO3)16O32
Colour:
Black
Lustre:
Metallic, Sub-Metallic
Hardness:
6
Specific Gravity:
4.18 (Calculated)
Crystal System:
Orthorhombic
Name:
Named in honor of Fritz Blatter (1943– ), German mineral collector, who provided the original material.
First described as a new mineral by Raade et al. (1988) from Kitteln Mine, Nordmark, Sweden. The structure was solved and refined by Cooper & Hawthorne (1998).
At the type locality (Kitteln mine, Sweden), blatterite is found embedded in calcite or manganosite.
The mineral differs from the related minerals in the orthopinakiolite group by its large unit cell (a = 37.69 Å).


Unique IdentifiersHide

Mindat ID:
694
Long-form identifier:
mindat:1:1:694:9

Similar NamesHide

BaltoriteA rock subtype

IMA Classification of BlatteriteHide

Classification of BlatteriteHide

6.AB.40

6 : BORATES
A : Monoborates
B : BO3, with additional anions; 1(D) + OH, etc.
24.2.7.1

24 : ANHYDROUS BORATES
2 : A2BO2[XO3]
9.7.9

9 : Borates
7 : Borates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
BlaIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BlatteriteHide

Metallic, Sub-Metallic
Transparency:
Opaque
Colour:
Black
Streak:
Brown
Hardness:
Tenacity:
Very brittle
Cleavage:
Perfect
on {001}
Parting:
imperfect parting on {100}
Density:
4.18 g/cm3 (Calculated)

Optical Data of BlatteriteHide

Type:
Biaxial (-)
RI values:
nα = 1.91 nβ = 1.97 nγ = 2
Max. Birefringence:
δ = 0.090
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.

No measured or calculated 2V is on file for this mineral, so the value used here (69°) is estimated from its recorded refractive indices and optic sign, not from a direct 2V measurement.
Anisotropism:
Weak to distinct, in shades of grayish brown
Dispersion:
r < v
Optical Extinction:
X = a; Y = c; Z = b.
Reflectivity:
WavelengthR1 (%)R2 (%)
400nm11.1%12.4%
420nm10.9%12.2%
440nm10.7%12.0%
460nm10.5%11.9%
480nm10.4%11.8%
500nm10.3%11.7%
520nm10.2%11.6%
540nm10.1%11.5%
560nm10.0%11.4%
580nm9.98%11.4%
600nm9.97%11.3%
620nm9.95%11.3%
640nm9.93%11.2%
660nm9.91%11.2%
680nm9.88%11.1%
700nm9.86%11.1%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 12.4%.
R1 shown in black, R2 shown in red

Chemistry of BlatteriteHide

Mindat Formula:
Sb5+3(Mn3+,Fe3+)9(Mn2+,Mg)35(BO3)16O32
Element Weights:
Element% weight
Mn57.072 %
O30.220 %
Sb8.624 %
B4.084 %

Calculated from ideal end-member formula.
Mn
O
Sb
B

Crystallography of BlatteriteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pnnm
Setting:
Pnnm
Cell Parameters:
a = 37.69 Å, b = 12.62 Å, c = 6.25 Å
Ratio:
a:b:c = 2.987 : 1 : 0.495
Unit Cell V:
2,972.80 ų (Calculated from Unit Cell)
Z:
32
Morphology:
Crystals with a flat, diamond-shaped cross-section, prisms {110}: striated along the length. Often with dull surfaces.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005563BlatteriteCooper M A, Hawthorne F C (1998) The crystal structure of blatterite, Sb3(Mn,Fe)9(Mn,Mg)35(BO3)16O32, and structural hierarchy in Mn-bearing zigzag borates The Canadian Mineralogist 36 1171-119319980293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.605 Å(100)
5.243 Å(45)
2.721 Å(40)
2.621 Å(35)
1.564 Å(35)
2.520 Å(30)
5.621 Å(20)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits
Geological Setting:
Metamorphosed Fe–Mn orebodies

Type Occurrence of BlatteriteHide

General Appearance of Type Material:
Lath-like crystals to 5 mm long and 1 mm wide embedded in manganosite or calcite.
Place of Conservation of Type Material:
At the Mineralogical-Geological Museum, University of Oslo, Norway and as specimen BM 186, 112;E1168 in the British Museum (Natural History).
Empirical Formula of Type Material:
(Mn2+1.21Mg0.79)Σ2.00(Mn3+0.69Sb3+0.19Fe3+0.11)Σ0.99(B1.01O3)O2
Geological Setting of Type Material:
Metamorphosed manganese orebody.
Associated Minerals at Type Locality:

Synonyms of BlatteriteHide

Other Language Names for BlatteriteHide

Relationship of Blatterite to other SpeciesHide

Other Members of Orthopinakiolite Group:
ChestermaniteMg2(Fe3+,Mn3+,Al,Sb3+)(BO3)O2Orth. mmm(2/m2/m2/m)
Orthopinakiolite(Mg,Mn2+)2Mn3+(BO3)O2Orth. mmm(2/m2/m2/m) : Pnnm
Takéuchiite(Mg,Mn2+)2(Mn3+,Fe3+)(BO3)O2Orth. mmm(2/m2/m2/m) : Pnnm

Common AssociatesHide

Associations Based on Photo Data:
6 photos of Blatterite associated with PyrochroiteMn(OH)2
6 photos of Blatterite associated with CalciteCaCO3
1 photo of Blatterite associated with Katoptrite(Mn2+,Mg)13(Al,Fe3+)4Sb5+2(SiO4)2O20

Related Minerals - Strunz-mindat GroupingHide

6.AB.ChubaroviteKZn2(BO3)Cl2Trig. 32 : R32
6.AB.Rhabdoborite-(Mo)Mg12Mo6+1.33O6(BO3)6F2Hex. 6 : P63
6.AB.05HambergiteBe2(BO3)(OH)Orth. mmm(2/m2/m2/m) : Pbca
6.AB.10BerboriteBe2(BO3)(OH) · H2OTrig.
6.AB.15JeremejeviteAl6(BO3)5(F,OH)3Hex. 6/m : P63/m
6.AB.20YuanfuliiteMg(Fe3+,Al)O(BO3)Orth. mmm(2/m2/m2/m) : Pnma
6.AB.20Warwickite(Mg,Ti,Fe,Al)2O(BO3)Orth. mmm(2/m2/m2/m) : Pnma
6.AB.25Karlite(Mg,Al)6.5(BO3)3(OH)4(◻,Cl)0.5Orth. 222 : P21212
6.AB.30MarinaiteCu2Fe3+O2(BO3)Mon. 2/m : P21/b
6.AB.30SavelievaiteMg2Cr3+O2(BO3)Orth. mmm(2/m2/m2/m) : Pbam
6.AB.30FredrikssoniteMg2Mn3+O2(BO3)Orth. mmm(2/m2/m2/m) : Pbam
6.AB.30VonseniteFe2+2Fe3+(BO3)O2Orth. mmm(2/m2/m2/m) : Pbam
6.AB.30LudwigiteMg2Fe3+(BO3)O2Orth. mmm(2/m2/m2/m) : Pbam
6.AB.30Azoproite(Mg,Fe2+)2(Fe3+,Ti,Mg)(BO3)O2Orth. mmm(2/m2/m2/m) : Pbam
6.AB.30BonaccorditeNi2Fe3+(BO3)O2Orth. mmm(2/m2/m2/m) : Pbam
6.AB.35FolvikiteSb5+Mn3+(Mg,Mn2+)10O8(BO3)4Mon. 2 : P2
6.AB.35Pinakiolite(Mg,Mn2+)2Mn3+(BO3)O2Mon. 2/m : B2/m
6.AB.40Takéuchiite(Mg,Mn2+)2(Mn3+,Fe3+)(BO3)O2Orth. mmm(2/m2/m2/m) : Pnnm
6.AB.40Orthopinakiolite(Mg,Mn2+)2Mn3+(BO3)O2Orth. mmm(2/m2/m2/m) : Pnnm
6.AB.40ChestermaniteMg2(Fe3+,Mn3+,Al,Sb3+)(BO3)O2Orth. mmm(2/m2/m2/m)
6.AB.45Aluminomagnesiohulsite(Mg,Fe2+)2(Al,Mg,Sn)(BO3)O2Mon. 2/m : P2/m
6.AB.45HulsiteFe2+2Fe3+O2(BO3)Mon. 2/m : P2/m
6.AB.45MagnesiohulsiteMg2Fe3+O2(BO3)Mon. 2/m : P2/m
6.AB.50FluoboriteMg3(BO3)(F,OH)3Hex. 6/m : P63/m
6.AB.50HydroxylboriteMg3(BO3)(OH)3Hex. 6/m : P63/m
6.AB.55ShabyniteMg5(BO3)(OH)5(Cl,OH)2 · 4H2OMon.
6.AB.55WightmaniteMg5(BO3)O(OH)5 · 2H2OMon. 2/m
6.AB.60GaudefroyiteCa4Mn3+2-3(BO3)3(CO3)(O,OH)3Hex.
6.AB.65SakhaiteCa48Mg16(BO3)32(CO3)16 · 2(H2O,HCl)Iso. m3m(4/m32/m) : Fd3m
6.AB.70HarkeriteCa48Mg16[AlSi4O15(OH)]4(BO3)16(CO3)16 · 2(H2O,HCl)Trig. 3m(32/m) : R3m
6.AB.75Pertsevite-(F)Mg2(BO3)(F,OH)Orth. mm2 : Pna21
6.AB.75Pertsevite-(OH)Mg2(BO3)(OH)Orth. mmm(2/m2/m2/m) : Pnma
6.AB.80JacquesdietrichiteCu2(H2BO3)(OH)3Orth. mmm(2/m2/m2/m) : Pmna
6.AB.85Rhabdoborite-(V)Mg12(V5+,Mo6+,W6+)1.5O6{[BO3]6-x[(P,As)O4]xF2-x} (x < 1)Hex. 6 : P63
6.AB.85Rhabdoborite-(W)Mg12(W6+,V5+)1.5O6{[BO3]6-x[(P,As)O4]xF2-x} Hex. 6 : P63
6.AB.85PainiteCaZrAl9(BO3)O15Hex. 6/m : P63/m
6.AB.90Mengxianminite(Ca,Na)2Sn2(Mg,Fe)3Al8[(BO3)(BeO4)O6]2Orth. mm2 : Fdd2

Other InformationHide

Notes:
Crystals are altered to finegrained hausmannite, pyrochroite and an unidentified hydrated Fe-Mn-Mg mineral, along cleavages and grain boundaries.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BlatteriteHide

References for BlatteriteHide

Localities for BlatteriteHide

Showing 4 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Sweden
 
  • Värmland County
    • Filipstad
      • Långban Ore District
Mineralogical Society of America - ... +1 other reference
      • Nordmark Odal Field
Mineralogical Society of America - ... +1 other reference
Raade et al. (1988)
Bovin et al. (1996)
 
and/or  
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