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Bergenite

A valid IMA mineral species - grandfathered
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About BergeniteHide

Formula:
Ca2Ba4(UO2)9(PO4)6O6 · 16H2O
Colour:
Yellow
Specific Gravity:
4.82 (Calculated)
Crystal System:
Monoclinic
Name:
Named in 1959 by Hans Wilhelm Bültemann and Gunter Harald Moh for the region near type locality Bergen, Saxony, Germany. The artificial compound was synthesized in 1956 by V. Ross and was called barium-phosphuranylite.
This page provides mineralogical data about Bergenite.


Unique IdentifiersHide

Mindat ID:
631
Long-form identifier:
mindat:1:1:631:0

Classification of BergeniteHide

04582630017697764655689.jpg
Phosphuranylite sheet topology

The sheet topology exhibited by members of the phosphuranylite group.

IMA Classification of BergeniteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca2Ba4(U6+O2)9O6(PO4)6·16H2O
First published:
1959
8.EC.40

8 : PHOSPHATES, ARSENATES, VANADATES
E : Uranyl phosphates and arsenates
C : UO2:RO4 = 3:2
42.4.5.3

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
4 : (AB)5(XO4)2Zq·xH2O
19.11.20

19 : Phosphates
11 : Phosphates of U

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
BgnIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BergeniteHide

Transparency:
Translucent
Colour:
Yellow
Streak:
Pale yellow
Density:
4.82 g/cm3 (Calculated)

Optical Data of BergeniteHide

Type:
Biaxial (-)
RI values:
nα = 1.66 nβ = 1.7 - 1.71 nγ = 1.722
Max. Birefringence:
δ = 0.062
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.

No measured or calculated 2V is on file for this mineral, so the value used here (62°) is estimated from its recorded refractive indices and optic sign, not from a direct 2V measurement.
Dispersion:
weak

Chemistry of BergeniteHide

Mindat Formula:
Ca2Ba4(UO2)9(PO4)6O6 · 16H2O
Element Weights:
Element% weight
U53.373 %
O25.511 %
Ba13.686 %
P4.630 %
Ca1.997 %
H0.804 %

Calculated from ideal end-member formula.
U
O
Ba
P
Ca
H

Crystallography of BergeniteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Cell Parameters:
a = 10.092 Å, b = 17.245 Å, c = 17.355 Å
β = 113.678°
Ratio:
a:b:c = 0.585 : 1 : 1.006
Unit Cell V:
2766.2 ų
Z:
2
Morphology:
Thin tabular.
Comment:
Data from Locock and Burns (2003)

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005828BergeniteLocock A J, Burns P C (2003) The crystal structure of bergenite, a new geometrical isomer of the phosphuranylite group The Canadian Mineralogist 41 91-10120030293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.73 Å(100)
3.837 Å(80)
3.054 Å(60)
2.874 Å(50)
2.826 Å(50)
8.54 Å(40)
3.742 Å(40)

Geological EnvironmentHide

Paragenetic Mode(s):

Type Occurrence of BergeniteHide

Synonyms of BergeniteHide

Other Language Names for BergeniteHide

Dutch:Bergeniet
German:Bergenit
Spanish:Bergenita

Relationship of Bergenite to other SpeciesHide

Other Members of Phosphuranylite Group:
AlthupiteAlTh(UO2)7(PO4)4(OH)5O2 · 15H2OTric. 1 : P1
DewindtiteH2Pb3(UO2)6O4(PO4)4 · 12H2OOrth. mmm(2/m2/m2/m) : Cmma
DumontitePb2(UO2)3O2(PO4)2 · 5H2OMon. 2/m : P21/m
Françoisite-(Ce)(Ce,Nd,Ca)(UO2)3(PO4)2O(OH) · 6H2OMon. 2/m : P21/b
Françoisite-(Nd)(Nd,Ce,Sm)(UO2)3(PO4)2O(OH) · 6H2OMon. 2/m
HügelitePb2(UO2)3(AsO4)2O2 · 5H2OMon. 2/m : P21/m
PhosphuranyliteKCa(H3O)3(UO2)7(PO4)4O4 · 8H2OOrth. mmm(2/m2/m2/m) : Cmcm
PhuralumiteAl2[(UO2)3(PO4)2O(OH)](OH)3(H2O)9Mon. 2/m
PhurcaliteCa2(UO2)3(PO4)2O2 · 7H2OOrth. mmm(2/m2/m2/m) : Pbca
UpaliteAl(UO2)3(PO4)2O(OH) · 7H2OMon. 2/m : P21/b
VanmeersscheiteU6+(UO2)3(PO4)2(OH)6 · 4H2OOrth. mmm(2/m2/m2/m)
YingjiangiteK2Ca(UO2)7(PO4)4(OH)6 · 6H2OOrth. mmm(2/m2/m2/m) : Cmcm

Common AssociatesHide

Associations Based on Photo Data:
9 photos of Bergenite associated with QuartzSiO2
1 photo of Bergenite associated with BaryteBaSO4
1 photo of Bergenite associated with FluoriteCaF2

Related Minerals - Strunz-mindat GroupingHide

8.EC.05UpaliteAl(UO2)3(PO4)2O(OH) · 7H2OMon. 2/m : P21/b
8.EC.05Françoisite-(Nd)(Nd,Ce,Sm)(UO2)3(PO4)2O(OH) · 6H2OMon. 2/m
8.EC.05Françoisite-(Ce)(Ce,Nd,Ca)(UO2)3(PO4)2O(OH) · 6H2OMon. 2/m : P21/b
8.EC.05PhuralumiteAl2[(UO2)3(PO4)2O(OH)](OH)3(H2O)9Mon. 2/m
8.EC.10YingjiangiteK2Ca(UO2)7(PO4)4(OH)6 · 6H2OOrth. mmm(2/m2/m2/m) : Cmcm
8.EC.10RenarditePb(UO2)4(PO4)2(OH)4 · H2OOrth.
8.EC.10PhosphuranyliteKCa(H3O)3(UO2)7(PO4)4O4 · 8H2OOrth. mmm(2/m2/m2/m) : Cmcm
8.EC.10ArsenuranyliteCa(UO2)4(AsO4)2(OH)4 · 6H2OOrth. mmm(2/m2/m2/m)
8.EC.10'Kivuite'Th(UO2)4(PO3OH)2(OH)8 · 7H2O
8.EC.10DewindtiteH2Pb3(UO2)6O4(PO4)4 · 12H2OOrth. mmm(2/m2/m2/m) : Cmma
8.EC.15DumontitePb2(UO2)3O2(PO4)2 · 5H2OMon. 2/m : P21/m
8.EC.15HügelitePb2(UO2)3(AsO4)2O2 · 5H2OMon. 2/m : P21/m
8.EC.20VanmeersscheiteU6+(UO2)3(PO4)2(OH)6 · 4H2OOrth. mmm(2/m2/m2/m)
8.EC.20ArsenovanmeersscheiteU6+(UO2)3(AsO4)2(OH)6 · 4H2OOrth. mm2 : Pmn21
8.EC.20MetavanmeersscheiteU6+(UO2)3(PO4)2(OH)6 · 2H2OOrth. mmm(2/m2/m2/m) : Fddd
8.EC.25AlthupiteAlTh(UO2)7(PO4)4(OH)5O2 · 15H2OTric. 1 : P1
8.EC.30MunditeAl(UO2)3(PO4)2(OH)3 · 5.5H2OOrth.
8.EC.35PhurcaliteCa2(UO2)3(PO4)2O2 · 7H2OOrth. mmm(2/m2/m2/m) : Pbca

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 53.3726% 13,343,150 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 0.0000% 0 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Fluorescence of BergeniteHide

Weak orange-brown in short- and long-wave ultraviolet light.

Other InformationHide

Notes:
Radioactive
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BergeniteHide

References for BergeniteHide

Localities for BergeniteHide

Showing 9 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
France
 
  • Auvergne-Rhône-Alpes
    • Allier
      • Vichy
        • Échassières
          • Montmins mining district
Kolitsch et al. (2009)
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Waldshut
        • St Blasien
          • Menzenschwand
Hochleitner (1982)
  • Saxony
    • Erzgebirgskreis
Wittern (2001)
      • Marienberg
        • Lauta
Hajek (2010)
    • Vogtlandkreis
      • Bergen
Bültemann et al. (1959)
      • Neuensalz
        • Mechelgrün
Tröger (2006) +1 other reference
      • Theuma
"Sigurd Stordal" Collection (E-Rocks)
Wittern (2001)
USA
 
  • Utah
    • Emery County
Min News 13:7 p2
 
and/or  
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