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Arsenuranylite

A valid IMA mineral species - grandfathered
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About ArsenuranyliteHide

Formula:
Ca(UO2)4(AsO4)2(OH)4 · 6H2O
Colour:
Orange
Hardness:
2 - 3
Specific Gravity:
4.25 (Calculated)
Crystal System:
Orthorhombic
Name:
Named in allusion to its composition, containing ARSENic and URANium, and probable relation to phosphuranylite.
This page provides mineralogical data about Arsenuranylite.


Unique IdentifiersHide

Mindat ID:
374
Long-form identifier:
mindat:1:1:374:8

IMA Classification of ArsenuranyliteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca(U6+O2)4(As5+O4)2(OH)4·6H2O

Classification of ArsenuranyliteHide

8.EC.10

8 : PHOSPHATES, ARSENATES, VANADATES
E : Uranyl phosphates and arsenates
C : UO2:RO4 = 3:2
42.4.9.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
4 : (AB)5(XO4)2Zq·xH2O
20.7.8

20 : Arsenates (also arsenates with phosphate, but without other anions)
7 : Arsenates of U

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
AuyIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ArsenuranyliteHide

Transparency:
Translucent
Colour:
Orange
Hardness:
2 - 3 on Mohs scale
Cleavage:
Perfect
One, perfect
Density:
4.25 g/cm3 (Calculated)

Optical Data of ArsenuranyliteHide

Type:
Biaxial (-)
RI values:
nα = 1.738 nβ = 1.761 nγ = 1.774
Max. Birefringence:
δ = 0.036
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Dispersion:
r > v moderate
Comments:
yellow in transmitted light.

Chemistry of ArsenuranyliteHide

Mindat Formula:
Ca(UO2)4(AsO4)2(OH)4 · 6H2O
Element Weights:
Element% weight
U60.485 %
O26.426 %
As9.519 %
Ca2.546 %
H1.025 %

Calculated from ideal end-member formula.

Crystallography of ArsenuranyliteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Cell Parameters:
a = 15.40 Å, b = 17.40 Å, c = 13.77 Å
Ratio:
a:b:c = 0.885 : 1 : 0.791
Unit Cell V:
3,689.81 ų (Calculated from Unit Cell)
Z:
6
Comment:
Space Group: Bmmb.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.72 Å(10)
3.85 Å(10)
8.41 Å(8)
3.13 Å(8)
3.42 Å(7)
1.778 Å(7)
1.729 Å(7)

Geological EnvironmentHide

Type Occurrence of ArsenuranyliteHide

General Appearance of Type Material:
As fine scales and lichenlike incrustations of elongated crystals, to 0.5 mm.
Place of Conservation of Type Material:
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia,
64434.
Geological Setting of Type Material:
oxidized zone of a uranium deposit containing arsenic-bearing sulfides
Associated Minerals at Type Locality:

Other Language Names for ArsenuranyliteHide

Common AssociatesHide

Associations Based on Photo Data:
2 photos of Arsenuranylite associated with MetazeuneriteCu(UO2)2(AsO4)2 · 8H2O
2 photos of Arsenuranylite associated with Schoepite(UO2)8O2(OH)12 · 12H2O

Related Minerals - Strunz-mindat GroupingHide

8.EC.05UpaliteAl(UO2)3(PO4)2O(OH) · 7H2OMon. 2/m : P21/b
8.EC.05Françoisite-(Nd)(Nd,Ce,Sm)(UO2)3(PO4)2O(OH) · 6H2OMon. 2/m
8.EC.05Françoisite-(Ce)(Ce,Nd,Ca)(UO2)3(PO4)2O(OH) · 6H2OMon. 2/m : P21/b
8.EC.05PhuralumiteAl2[(UO2)3(PO4)2O(OH)](OH)3(H2O)9Mon. 2/m
8.EC.10YingjiangiteK2Ca(UO2)7(PO4)4(OH)6 · 6H2OOrth. mmm(2/m2/m2/m) : Cmcm
8.EC.10RenarditePb(UO2)4(PO4)2(OH)4 · H2OOrth.
8.EC.10PhosphuranyliteKCa(H3O)3(UO2)7(PO4)4O4 · 8H2OOrth. mmm(2/m2/m2/m) : Cmcm
8.EC.10'Kivuite'Th(UO2)4(PO3OH)2(OH)8 · 7H2O
8.EC.10DewindtiteH2Pb3(UO2)6O4(PO4)4 · 12H2OOrth. mmm(2/m2/m2/m) : Cmma
8.EC.15DumontitePb2(UO2)3O2(PO4)2 · 5H2OMon. 2/m : P21/m
8.EC.15HügelitePb2(UO2)3(AsO4)2O2 · 5H2OMon. 2/m : P21/m
8.EC.20VanmeersscheiteU6+(UO2)3(PO4)2(OH)6 · 4H2OOrth. mmm(2/m2/m2/m)
8.EC.20ArsenovanmeersscheiteU6+(UO2)3(AsO4)2(OH)6 · 4H2OOrth. mm2 : Pmn21
8.EC.20MetavanmeersscheiteU6+(UO2)3(PO4)2(OH)6 · 2H2OOrth. mmm(2/m2/m2/m) : Fddd
8.EC.25AlthupiteAlTh(UO2)7(PO4)4(OH)5O2 · 15H2OTric. 1 : P1
8.EC.30MunditeAl(UO2)3(PO4)2(OH)3 · 5.5H2OOrth.
8.EC.35PhurcaliteCa2(UO2)3(PO4)2O2 · 7H2OOrth. mmm(2/m2/m2/m) : Pbca
8.EC.40BergeniteCa2Ba4(UO2)9(PO4)6O6 · 16H2OMon. 2/m : P21/b

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 60.4845% 15,121,125 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 0.0000% 0 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

Notes:
Radioactive
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ArsenuranyliteHide

References for ArsenuranyliteHide

Localities for ArsenuranyliteHide

Showing 7 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Waldshut
        • St Blasien
          • Menzenschwand
Walenta (1992)
  • Rhineland-Palatinate
    • Birkenfeld
      • Birkenfeld
        • Ellweiler
Aufschluss 69/ (7+8) +1 other reference
  • Saxony
    • Vogtlandkreis
      • Bergen
Wittern (2001)
South Africa
 
  • Western Cape
    • Central Karoo District Municipality
      • Beaufort West Local Municipality
Cairncross et al. (1995)
Spain
 
  • Catalonia
    • Lleida
      • Pallars Jussà
        • La Vall Fosca
          • La Torre de Cabdella
            • Castell-estaó
Joan Abella i Creus and Joan Viñals i Olià (2012)
USA
 
  • Alaska
    • Yukon-Koyukuk Census Area
      • Sheenjek Mining District
- (2008)
Uzbekistan (TL)
 
  • Namangan Region
    • Pop District
Belova (1958) +3 other references
 
and/or  
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