Cupromolybdite
A valid IMA mineral species
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About Cupromolybdite
Formula:
Cu3O(MoO4)2
Colour:
Honey-yellow to chestnut-brown or dark brown; bright yellow
Lustre:
Adamantine
Hardness:
3
Specific Gravity:
4.512 (Calculated)
Crystal System:
Orthorhombic
Name:
For the chemical composition.
Type Locality:
Isostructural with:
S-free analogue of vergasovaite. May form via topotactic transformation of the latter (Nazarchuk et al., 2023).
Unique Identifiers
Mindat ID:
41953
Long-form identifier:
mindat:1:1:41953:2
IMA Classification of Cupromolybdite
Approved
IMA Formula:
Cu2+3O(Mo6+O4)2
Approval year:
2011
First published:
2012
Type description reference:
Zelenski, Michael E., Zubkova, Natalia V., Pekov, Igor V., Polekhovsky, Yuri S., Pushcharovsky, Dmitry Y.U. (2012) Cupromolybdite, Cu3O(MoO4)2, a new fumarolic mineral from the Tolbachik volcano, Kamchatka Peninsula, Russia. European Journal of Mineralogy, 24 (4) 749-757 doi:10.1127/0935-1221/2012/0024-2221
Classification of Cupromolybdite
7.BB.30
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
B : With medium-sized cations
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
B : With medium-sized cations
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Cmyb | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Cupromolybdite
Adamantine
Transparency:
Translucent
Colour:
Honey-yellow to chestnut-brown or dark brown; bright yellow
Streak:
Yellow or light brown
Hardness:
3 on Mohs scale
Hardness:
VHN50=189 kg/mm2 - Vickers
Comment:
Mohs hardness derived from VHN.
Tenacity:
Brittle
Cleavage:
Distinct/Good
Fracture:
Irregular/Uneven, Splintery
Density:
4.512 g/cm3 (Calculated)
Optical Data of Cupromolybdite
Anisotropism:
Distinct
Bireflectance:
Weak
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 400nm | 17.0% | 18.5% |
| 420nm | 16.3% | 17.7% |
| 440nm | 15.7% | 17.1% |
| 460nm | 15.2% | 16.5% |
| 480nm | 14.7% | 16.1% |
| 500nm | 14.3% | 15.7% |
| 520nm | 13.9% | 15.3% |
| 540nm | 13.5% | 15.0% |
| 560nm | 13.1% | 14.6% |
| 580nm | 12.9% | 14.3% |
| 600nm | 12.4% | 13.8% |
| 620nm | 12.2% | 13.6% |
| 640nm | 12.15% | 13.5% |
| 660nm | 11.9% | 13.2% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 18.5%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Grey, with a weak bluish hue
Internal Reflections:
Orange-red or orange-brown
Pleochroism:
Non-pleochroic
Comments:
The reflectivity data for 680 and 700 nm, given in the type description, are in error (they duplicate 400 and 420 nm).
Chemistry of Cupromolybdite
Mindat Formula:
Cu3O(MoO4)2
Element Weights:
Elements listed:
Crystallography of Cupromolybdite
Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pnma
Setting:
Pnma
Cell Parameters:
a = 7.6638(1) Å, b = 6.8670(1) Å, c = 14.5554(2) Å
Ratio:
a:b:c = 1.116 : 1 : 2.12
Unit Cell V:
766.01 ų
Z:
4
Morphology:
Prismatic to acicular.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0019362 | Cupromolybdite | Zelenski M E, Zubkova N V, Pekov I V, Polekhovsky Y S, Pushcharovsky D Y (2012) Cupromolybdite, Cu3O(MoO4)2, a new fumarolic mineral from the Tolbachik volcano, Kamchatka Peninsula, Russia European Journal of Mineralogy 24 749-757 | 2012 | the Tolbachik volcano, Kamchatka Peninsula, Russia | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 7.312 Å | (67) |
| 3.842 Å | (37) |
| 3.701 Å | (38) |
| 3.664 Å | (30) |
| 3.518 Å | (55) |
| 3.436 Å | (100) |
| 3.301 Å | (99) |
| 3.065 Å | (79) |
| 2.556 Å | (62) |
| 2.506 Å | (66) |
Reference:
Zelenski, Michael E., Zubkova, Natalia V., Pekov, Igor V., Polekhovsky, Yuri S., Pushcharovsky, Dmitry Y.U. (2012) Cupromolybdite, Cu3O(MoO4)2, a new fumarolic mineral from the Tolbachik volcano, Kamchatka Peninsula, Russia. European Journal of Mineralogy, 24 (4) 749-757 doi:10.1127/0935-1221/2012/0024-2221
Comments:
Yadovitaya fumarole, Tolbachik volcano, Kamchatka Krai, Russia. The data are from the type description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 45a : [Sulfates, arsenates, selenates, antimonates] | |
| 45b : [Other oxidized fumarolic minerals] |
Type Occurrence of Cupromolybdite
General Appearance of Type Material:
Prismatic or acicular crystals up to 0.15 mm in length; radiating aggregates.
Place of Conservation of Type Material:
Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, Russia: registration number is 4072/1.
Geological Setting of Type Material:
Within 2-5 cm thick sublimate crusts, along with other fumarolic minerals.
Associated Minerals at Type Locality:
Reference:
Zelenski, Michael E., Zubkova, Natalia V., Pekov, Igor V., Polekhovsky, Yuri S., Pushcharovsky, Dmitry Y.U. (2012) Cupromolybdite, Cu3O(MoO4)2, a new fumarolic mineral from the Tolbachik volcano, Kamchatka Peninsula, Russia. European Journal of Mineralogy, 24 (4) 749-757 doi:10.1127/0935-1221/2012/0024-2221
Synonyms of Cupromolybdite
Other Language Names for Cupromolybdite
Dutch:Cupromolybdiet
German:Cupromolybdit
Common Associates
Associations Based on Photo Data:
| 4 photos of Cupromolybdite associated with Starovaite | KCu5O(VO4)3 |
| 2 photos of Cupromolybdite associated with Lammerite | Cu3(AsO4)2 |
| 1 photo of Cupromolybdite associated with Pseudolyonsite | Cu3(VO4)2 |
| 1 photo of Cupromolybdite associated with Piypite | K4Cu4O2(SO4)4 · (Na,Cu)Cl |
Related Minerals - Strunz-mindat Grouping
| 7.BB. | Iskandarovite | Sb6O7(SO4)2 |
| 7.BB. | Brumadoite | Cu3(Te6+O4)(OH)4 · 5H2O |
| 7.BB. | Novikovite | (NH4)4Mo6+2Mo5+2O8(SO4)5 |
| 7.BB.10 | Hauckite | Fe3+3(Mg,Mn2+)24Zn18(SO4)4(CO3)2(OH)81 |
| 7.BB.15 | Antlerite | Cu3(SO4)(OH)4 |
| 7.BB.20 | Dolerophanite | Cu2(SO4)O |
| 7.BB.25 | Brochantite | Cu4(SO4)(OH)6 |
| 7.BB.25 | Ramaccioniite | Cu4[SeO4](OH)6 |
| 7.BB.30 | Vergasovaite | Cu3(SO4)(MoO4,SO4)O |
| 7.BB.35 | Klebelsbergite | Sb4O4(SO4)(OH)2 |
| 7.BB.35 | Tavagnascoite | Bi4O4(SO4)(OH)2 |
| 7.BB.40 | Schuetteite | Hg2+3O2(SO4) |
| 7.BB.45 | Paraotwayite | Ni(OH)2-x(SO4,CO3)0.5x |
| 7.BB.50 | Xocomecatlite | Cu3(TeO4)(OH)4 |
| 7.BB.55 | Pauflerite | (V4+O)SO4 |
| 7.BB.60 | Grandviewite | Cu3Al2(SO4)(OH)10 · H2O |
| 7.BB.65 | Timroseite | Pb2Cu5(TeO6)2(OH)2 |
| 7.BB.70 | Glikinite | Zn3O(SO4)2 |
| 7.BB.80 | Mojaveite | Cu6[Te6+O4(OH)2](OH)7Cl |
| 7.BB.85 | Paratimroseite | Pb2Cu4(TeO6)2(H2O)2 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Cupromolybdite
mindat.org URL:
https://www.mindat.org/min-41953.html
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References for Cupromolybdite
Reference List:
Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2011. CNMNC Newsletter No 9. Mineralogical Magazine, 75 (4) 2535-2540 doi:10.1180/minmag.2011.075.4.2535
Zelenski, Michael E., Zubkova, Natalia V., Pekov, Igor V., Polekhovsky, Yuri S., Pushcharovsky, Dmitry Y.U. (2012) Cupromolybdite, Cu3O(MoO4)2, a new fumarolic mineral from the Tolbachik volcano, Kamchatka Peninsula, Russia. European Journal of Mineralogy, 24 (4) 749-757 doi:10.1127/0935-1221/2012/0024-2221
Ismagilova, Reseda M., Zhitova, Elena S., Zolotarev, Andrey A., Krivovichev, Sergey V. (2019) Jahn–Teller distortion and thermal expansion anisotropy: temperature-dependent behavior of lindgrenite, Cu3(MoO4)2(OH)2, szenicsite, Cu3(MoO4)(OH)4, and cupromolybdite, Cu3O(MoO4)2. Physics and Chemistry of Minerals, 46 (5) 437-447 doi:10.1007/s00269-018-1014-6
Localities for Cupromolybdite
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Russia (TL) | |
| Williams et al. (2011) +2 other references |
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The
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough, Great Fissure eruption, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia