Wöhlerite Group
A group of related mineral species
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About Wöhlerite Group
Formula:
X8(Si2O7)2W4
X = Na+, Ca2+, Mn2+,Ti4+, Zr4+ and Nb5+;
W = F-, O2-.
W = F-, O2-.
A group formally established by IMA in September 2020 (Proposal 20-D).
It has its name after the first described mineral of the group, wöhlerite (Scheerer, 1843). It includes 12 minerals (as of September 2024) with both monoclinic and triclinic structures. They occurs as accessory phases in various geological environments as nepheline syenites, alkali feldspar granite and skarns and calc-silicate marbles from different localities worldwide.
Formerly also known as 'Cuspidine Group.'
See also the related Rosenbuschite Group.
It has its name after the first described mineral of the group, wöhlerite (Scheerer, 1843). It includes 12 minerals (as of September 2024) with both monoclinic and triclinic structures. They occurs as accessory phases in various geological environments as nepheline syenites, alkali feldspar granite and skarns and calc-silicate marbles from different localities worldwide.
Formerly also known as 'Cuspidine Group.'
See also the related Rosenbuschite Group.
Name Encoding
ASCII-7:
Wohlerite Group
Unique Identifiers
Mindat ID:
35647
Long-form identifier:
mindat:1:1:35647:3
IMA Classification of Wöhlerite Group
IMA status notes:
IMA Approved Group Name
Chemistry of Wöhlerite Group
Mindat Formula:
X8(Si2O7)2W4
X = Na+, Ca2+, Mn2+,Ti4+, Zr4+ and Nb5+;
W = F-, O2-.
X = Na+, Ca2+, Mn2+,Ti4+, Zr4+ and Nb5+;
W = F-, O2-.
Chemical Analysis
Oxide wt%:
| 1 | 2 | 3 | 4 | 5 | 6 | |
|---|---|---|---|---|---|---|
| SiO2 | 29.63 % | 26.93 % | 28.9 % | 29.72 % | 30.12 % | 30.62 % |
| TiO2 | 2.35 % | 4.30 % | 3.2 % | 3.22 % | 0.42 % | |
| ZrO2 | 28.79 % | 21.70 % | 27.2 % | 27.40 % | 16.11 % | 15.17 % |
| Fe2O3 | 4.73 % | 0.48 % | ||||
| (Nb, Ta)2O5 | 5.20 % | |||||
| MnO | 5.59 % | 11.66 % | 5.3 % | 5.54 % | 1.00 % | 1.55 % |
| CaO | 9.70 % | 7.74 % | 8.2 % | 8.32 % | 26.95 % | 26.08 % |
| Na2O | 10.77 % | 10.59 % | 11.9 % | 12.44 % | 7.50 % | 8.08 % |
| LOI | 2.24 % | |||||
| Nb2O5 | 6.10 % | 6.0 % | 4.73 % | 12.85 % | 14.47 % | |
| HfO2 | 0.36 % | 0.7 % | ||||
| ThO2 | 0.03 % | |||||
| Y2O3 | 0.19 % | 0.83 % | 0.23 % | |||
| Ce2O3 | 0.06 % | |||||
| Pr2O3 | 0.04 % | |||||
| Nd2O3 | 0.03 % | |||||
| Sm2O3 | 0.12 % | |||||
| Gd2O3 | 0.09 % | |||||
| Dy2O3 | 0.07 % | |||||
| Er2O3 | 0.06 % | |||||
| Yb2O3 | 0.06 % | |||||
| MgO | 0.09 % | 0.11 % | 0.12 % | 0.12 % | 0.42 % | |
| FeO | 2.48 % | 3.6 % | 3.86 % | 1.26 % | 2.12 % | |
| F | 5.60 % | 3.44 % | 4.68 % | 2.98 % | ||
| O=F | -2.36 % | -1.45 % | -1.97 % | |||
| Al2O3 | 0.02 % | |||||
| Ta2O5 | 0.2 % | |||||
| REE2O3 | 0.47 % | 0.66 % | ||||
| H2O | 0.74 % | 0.24 % | ||||
| -O=F | -1.26 % | |||||
| Total: | 99 % | 95.94 % | 98.62 % | 98.29 % | 99.93 % | 98.75 % |
Empirical formulas:
| Sample ID | Empirical Formula |
|---|---|
| 7 | Na2.00(Ca1.74Na0.26)Σ2.00(Fe1.00Mn0.52Ca0.49Zr0.05)Σ2.06(Ti1.69Zr0.14Mg0.09Nb0.08)Σ2.00(Si2O7)2.00O1.84F2.16 |
Sample references:
| ID | Type | Locality | Reference | Notes |
|---|---|---|---|---|
| 1 | Natrolittodden, Vesle Arøya, Larvik Commune, Vestfold, Norway | wet-chemical analysis by Cleve | ||
| 2 | Los Archipelago, Conakry Region, Guinea | Electron microprobe | ||
| 3 | Natrolittodden, Vesle Arøya, Larvik Commune, Vestfold, Norway | EMPA + ICPMS data. 5mm brown, elongated crystal | ||
| 4 | Langesundsfjorden, Norway | electron microprobe | ||
| 5 | Skutesundskjær, Barkevik area, Larvik Commune, Vestfold, Norway | wet-chemical analysis by P. T. Cleve. The sample studied is most probably from Skudesundskjaer. | ||
| 6 | Type Specimen | Løvøya, Porsgrunn, Telemark, Norway | Wet-chemical analysis, Nb erroneously reported as Ta by Scheerer. Locality probably Loevoya | |
| 7 | Pilanesbergite type locality, Ledig village area, Pilanesberg Alkaline Ring Complex, Moses Kotane Local Municipality, Bojanala Platinum District Municipality, North West, South Africa | empirical formula basis: 18 anions |
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0019477 | Normandite | Biagioni C, Merlino S, Parodi G C, Perchiazzi N (2012) Crystal chemistry of minerals of the wohlerite group from the Los Archipelago, Guinea The Canadian Mineralogist 50 593-609 | 2012 | the nepheline syenites of the Los Archipelago, Guinea | 0 | 293 | |
| 0019478 | Hiortdahlite | Biagioni C, Merlino S, Parodi G C, Perchiazzi N (2012) Crystal chemistry of minerals of the wohlerite group from the Los Archipelago, Guinea The Canadian Mineralogist 50 593-609 | 2012 | the nepheline syenites of the Los Archipelago, Guinea | 0 | 293 | |
| 0019218 | Hiortdahlite | Bellezza M, Merlino S, Perchiazzi N (2012) Distinct domains in "guarinite" from Monte Somma, Italy: Crystal structures and crystal chemistry The Canadian Mineralogist 50 531-548 | 2012 | Monte Somma syenite, Italy | 0 | 293 | |
| 0019216 | Hiortdahlite | Bellezza M, Merlino S, Perchiazzi N (2012) Distinct domains in "guarinite" from Monte Somma, Italy: Crystal structures and crystal chemistry The Canadian Mineralogist 50 531-548 | 2012 | Monte Somma syenite, Italy | 0 | 293 | |
| 0017878 | Hiortdahlite | Merlino S, Perchiazzi N (2010) The crystal structure of hiortdahlite II Mineralogy and Petrology 37 25-35 | 2010 | Kipawa river, Canada | 0 | 293 | |
| 0017879 | Baghdadite | Biagioni C, Bonaccorsi E, Perchiazzi N, Merlino S (2010) Single crystal refinement of the structure of baghdadite from Fuka (Okayama Prefecture, Japan) Periodico di Mineralogia 79 1-9 | 2010 | Fuka, Okayama Prefecture, Japan | 0 | 293 | |
| 0007083 | Cuspidine | Bellezza M, Merlino S, Perchiazzi N (2004) Chemical and structural study of the Zr,Ti-disilicates in the venanzite from Pian di Celle, Umbria, Italy European Journal of Mineralogy 16 957-969 | 2004 | Pian di Celle, Umbria, Italy | 0 | 293 | |
| 0005650 | Normandite | Perchiazzi N, McDonald A M, Gault R A, Johnsen O, Merlino S (2000) The crystal structure of normandite and its crystal-chemical relationships with lavenite The Canadian Mineralogist 38 641-648 | ![]() | 2000 | Mont Saint-Hilaire, Quebec, Canada | 0 | 293 |
| 0005649 | Normandite | Perchiazzi N, McDonald A M, Gault R A, Johnsen O, Merlino S (2000) The crystal structure of normandite and its crystal-chemical relationships with lavenite The Canadian Mineralogist 38 641-648 | ![]() | 2000 | Amdrup Fjord | 0 | 293 |
| 0013849 | Baghdadite | Plaisier J R, Jansen J, de Graaff R A G, Ijdo D J W (1995) Structure determination of Ca3HfSi2O9 and Ca3ZrSi2O9 from powder diffraction Journal of Solid State Chemistry 115 464-468 | 1995 | synthetic | 0 | 293 | |
| 0006380 | Burpalite | Merlino S, Perchiazzi N, Khomyakov A P, Pushcharovsky D Y, Kulikova I M, Kuzmin V I (1990) Burpalite, a new mineral from Burpalinskii massif, North Transbajkal, USSR: its crystal structure and OD character European Journal of Mineralogy 2 177-185 | 1990 | Burpalinskii massif, North Transbajkal, USSR | 0 | 293 | |
| 0014615 | Hiortdahlite | Merlino S, Perchiazzi N (1987) The crystal structure of hiortdahlite II Mineralogy and Petrology 37 25-35 | 1987 | Kipawa River, Canada | 0 | 293 | |
| 0015690 | Niocalite | Mellini M (1982) Niocalite revised: Twinning and crystal structure Tschermaks Mineralogische und Petrographische Mitteilungen 30 249-266 | 1982 | Oka, Quebec, Canada | 0 | 293 | |
| 0018273 | Cuspidine | Saburi S, Kawahara A, Henmi C, Kusachi I, Kihara K (1977) The refinement of the crystal structure of cuspidine Mineralogical Journal 8 286-298 | 1977 | Fuka, Okayama Prefecture, Japan | 0 | 293 | |
| 0002593 | Cuspidine | Piotrowski A, Kahlenberg V, Fischer R X (2000) Na2Ca2(P2O7)F2, the first diphosphate of the cuspidine family American Mineralogist 85 1534-1539 | ![]() | 2000 | 0 | 293 | |
| 0002594 | Cuspidine | Piotrowski A, Kahlenberg V, Fischer R X (1999) Na2Ca2(P2O7)F2, the first diphosphate of the cuspidine family American Mineralogist 85 1534-1539 | ![]() | 1999 | 0 | 293 | |
| 0005460 | Cuspidine | Fleet M E, Pan Y (1995) The structure of NaCa2LuSi2O7F2, a synthetic phase of the cuspidine group The Canadian Mineralogist 33 879-884 | ![]() | 1995 | 0 | 293 | |
| 0014794 | Janhaugite | Annehed H, Falth L, Raade G (1985) The crystal structure of janhaugite, a sorosilicate of the cuspidine family Neues Jahrbuch fur Mineralogie, Monatshefte 1985 7-18 | 1985 | 0 | 293 | ||
| 0015704 | Hiortdahlite | Merlino S, Perchiazzi N (1985) The crystal structure of hiortdahlite I Tschermaks Mineralogische und Petrographische Mitteilungen 34 297-310 | 1985 | 0 | 293 | ||
| 0018274 | Cuspidine | Smirnova R F, Rumanova I M, Belov N V (1955) Crystal structure of cuspidine Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva 84 159-169 | 1955 | 0 | 293 |
CIF Raw Data - click here to close
Synonyms of Wöhlerite Group
Relationship of Wöhlerite Group to other Species
Wöhlerite Group Members:
| Baghdadite | Ca6Zr2(Si2O7)2O4 | Mon. 2/m : P21/b |
| Burpalite | Na2CaZr(Si2O7)F2 | Mon. 2/m : P21/b |
| Cuspidine | Ca8(Si2O7)2F4 | Mon. 2/m : P21/b |
| Hiortdahlite | Na2Ca4(Ca0.5Zr0.5)Zr(Si2O7)2OF3 | Tric. 1 : P1 |
| Janhaugite | (Na,Ca)3(Mn2+,Fe2+)3(Ti,Zr,Nb)2(Si2O7)2O2(OH,F)2 | Mon. 2/m : P21/m |
| Låvenite | Na2Ca2Mn2Zr2(Si2O7)2O2F2 | Mon. 2/m : P21/b |
| Madeiraite | Na2Ca2Fe2Zr2(Si2O7)2O2F2 | Mon. 2/m : P21/b |
| Moxuanxueite | NaCa6Zr(Si2O7)2OF3 | Tric. 1 : P1 |
| Niocalite | (Ca,Nb)4(Si2O7)(O,OH,F)2 | Mon. m |
| Normandite | NaCa(Mn,Fe)(Ti,Nb,Zr)(Si2O7)OF | Mon. 2/m : P21/b |
| Pilanesbergite | Na2Ca2Fe2Ti2(Si2O7)2O2F2 | Mon. 2/m : P21/b |
| Wöhlerite | Na2Ca4ZrNb(Si2O7)2O3F | Mon. 2 : P21 |
Click on any node to view relationships. Formula-derived relationship network for the group members above. Use Find related species to add formula-neighbour species outside the current group view. Solid links show inferred chemical differences; dashed violet links show same-formula crystallographic differences. Hydration states are not treated as relationship changes. These relationships do not imply any real-world substitution reactions between these species.
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Wöhlerite Group
mindat.org URL:
https://www.mindat.org/min-35647.html
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References for Wöhlerite Group
Reference List:
Scheerer, Th. (1843) Ueber den Wöhlerit, eine neue Mineralspecies. Annalen der Physik und Chemie, 135. 327-336 doi:10.1002/andp.18431350611
Localities for Wöhlerite Group
Showing 493 localities.
Locality List
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- This locality has estimated coordinates.
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? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.







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The
San Vito Quarry, San Vito, Ercolano, Metropolitan City of Naples, Campania, Italy