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Panunzite

A valid IMA mineral species
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About PanunziteHide

00037940017271925734044.jpg
Achille Panunzi collecting at the Procida Island

Procida Island, Metropolitan City of Naples, Campania, Italy
Formula:
(K,Na)AlSiO4
Colour:
colourless
Lustre:
Vitreous
Hardness:
Specific Gravity:
2.59
Crystal System:
Hexagonal
Name:
Named by Enrico Franco and Maurizio De Gennaro in 1988 in honor of Achille Panunzi, professor of chemistry, University of Naples. Dr. Panunzi discovered the blocks ejected from Mt. Somma that contained the mineral.
Isostructural with:
See also the closely related kalsilite and kaliophilite.


Unique IdentifiersHide

Mindat ID:
3075
Long-form identifier:
mindat:1:1:3075:1

IMA Classification of PanunziteHide

Approved
IMA Formula:
K3Na(AlSiO4)4
Approval year:
1978

Classification of PanunziteHide

9.FA.05

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
A : Tektosilicates without additional non-tetrahedral anions
76.2.1.4

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
16.4.2

16 : Silicates Containing Aluminum and other Metals
4 : Aluminosilicates of Na and K

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
PnzIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PanunziteHide

Vitreous
Transparency:
Transparent
Colour:
Colourless
Streak:
White
Hardness:
5½ on Mohs scale
Density:
2.59 g/cm3 (Measured)    2.62 g/cm3 (Calculated)

Optical Data of PanunziteHide

Type:
Uniaxial (-)
RI values:
nω = 1.540(1) nε = 1.535(1)
Birefringence:
0.005
Max. Birefringence:
δ = 0.005
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
None to Very Low
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Pleochroism:
Not Visible

Chemistry of PanunziteHide

Mindat Formula:
(K,Na)AlSiO4
Element Weights:
Element% weight
O40.463 %
K24.720 %
Si17.757 %
Al17.059 %

Calculated from ideal end-member formula.
O
K
Si
Al
Common Impurities:
Fe,Mg,Ca,Sr,Ba,Rb,H2O

Crystallography of PanunziteHide

Crystal System:
Hexagonal
Class (H-M):
6 - Pyramidal
Space Group:
P63
Cell Parameters:
a = 20.513(8) Å, c = 8.553(3) Å
Ratio:
a:c = 1 : 0.417
Unit Cell V:
3,116.79 ų (Calculated from Unit Cell)
Z:
32

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014796PanunziteMerlino S, Franco E, Mattia C A, Pasero M, De Gennaro M (1985) The crystal structure of panunzite (natural tetrakalsilite) Neues Jahrbuch fur Mineralogie, Monatshefte 1985 322-3281985Somma-Vesuvius area, Italy0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.277 Å(25)
3.929 Å(70)
3.071 Å(100)
2.914 Å(30)
2.558 Å(40)
2.380 Å(20)
2.268 Å(20)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
9 : Lava/xenolith minerals (hornfels, sanidinite facies)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of PanunziteHide

General Appearance of Type Material:
Hexagonal prisms up to 4 mm in length.
Geological Setting of Type Material:
In cavities in pyroxene-rich ejecta blocks in recent volcanoclastic deposits.

Synonyms of PanunziteHide

Other Language Names for PanunziteHide

Dutch:Panunziet
German:Panunzit
Spanish:Panunzita

Common AssociatesHide

Associations Based on Photo Data:
2 photos of Panunzite associated with DiopsideCaMgSi2O6

Related Minerals - Strunz-mindat GroupingHide

9.FA.BonaccorsiiteKK2Na3(Al6Si36)O84Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.FA.HexacelsianBaAl2Si2O8Hex. 6/mmm(6/m2/m2/m) : P63/mcm
9.FA.Wodegongjieite KCa3(Al7Si9)O32Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.FA.05Yoshiokaite(Ca,Na)[Al(Al,Si)O4]Trig. 3 : P3
9.FA.05NephelineNa3K(Al4Si4O16)Hex. 6 : P63
9.FA.05TrinephelineNaAlSiO4Hex. 6 : P61
9.FA.05Davidsmithite(Ca,◻)2Na6Al8Si8O32Hex. 6 : P63
9.FA.05KaliophiliteKAlSiO4Trig. 3 : P3
9.FA.05KalsiliteKAlSiO4Hex. 622 : P6322
9.FA.05'Carnegieite'NaAlSiO4Tric.
9.FA.05MegakalsiliteKAlSiO4Hex. 6 : P63
9.FA.05TrikalsiliteK2NaAl3(SiO4)3Hex. 6 : P63
9.FA.10MalinkoiteNaBSiO4Hex. 6 : P63
9.FA.15VirgiliteLiAlSi2O6Hex. 622 : P6222
9.FA.25LisitsyniteKBSi2O6Orth. 222 : P222
9.FA.30FerrisanidineK[Fe3+Si3O8]Mon. 2/m : B2/m
9.FA.30Buddingtonite(NH4)(AlSi3O8)Mon. 2 : P21
9.FA.30RubiclineRb(AlSi3O8)Mon. 2/m : B2/m
9.FA.30'Monalbite'NaAlSi3O8Mon. 2/m : B2/m
9.FA.30MicroclineK(AlSi3O8)Tric. 1
9.FA.30 va'Germanate-celsian'BaAl2Ge2O8
9.FA.30CelsianBa(Al2Si2O8)Mon. 2/m
9.FA.30SanidineK(AlSi3O8)Mon. 2/m : B2/m
9.FA.30OrthoclaseK(AlSi3O8)Mon. 2/m : B2/m
9.FA.35ReedmergneriteNaBSi3O8Tric. 1 : P1
9.FA.35AlbiteNa(AlSi3O8)Tric. 1
9.FA.35AnorthiteCa(Al2Si2O8)Tric. 1 : P1
9.FA.40ParacelsianBa(Al2Si2O8)Mon. 2/m : P21/b
9.FA.45SvyatoslaviteCa(Al2Si2O8)Mon. 2 : P21
9.FA.45KumdykoliteNa(AlSi3O8)Orth. mmm(2/m2/m2/m) : Pnnm
9.FA.50SlawsoniteSr(Al2Si2O8)Mon. 2/m : P21/b
9.FA.55LisetiteCaNa2Al4Si4O16Orth. mm2
9.FA.60StronalsiteNa2SrAl4Si4O16Orth.
9.FA.60BanalsiteNa2BaAl4Si4O16Orth. mm2 : Iba2
9.FA.65MaleeviteBaB2Si2O8Orth. mmm(2/m2/m2/m) : Pnma
9.FA.65PekoviteSrB2Si2O8Orth. mmm(2/m2/m2/m) : Pnma
9.FA.65DanburiteCaB2Si2O8Orth. mmm(2/m2/m2/m)
9.FA.70LiebermanniteKAlSi3O8Tet. 4/m : I4/m
9.FA.70LinguniteNaAlSi3O8Tet. 4/m : I4/m
9.FA.70StöffleriteCaAl2Si2O8Tet. 4/m : I4/m
9.FA.75PfaffenbergiteKNa3(Al4Si12)O32Hex. 6/mmm(6/m2/m2/m) : P6/mcc
9.FA.75KokchetaviteK(AlSi3O8)Hex. 6/mmm(6/m2/m2/m) : P6/mcc

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 24.7203% 7,663 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for PanunziteHide

References for PanunziteHide

Localities for PanunziteHide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy (TL)
 
  • Campania
    • Metropolitan City of Naples
[Lapis 1994:5 p.13-23 +1 other reference
  • Umbria
    • Terni Province
      • San Venanzo
Ciriotti et al. (2004)
 
and/or  
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