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Manganarsite

A valid IMA mineral species
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About ManganarsiteHide

Formula:
Mn3(As2O4)(OH)4
Hardness:
3
Crystal System:
Trigonal
Name:
The name reflects its chemical composition: Manganese and Arsenic
This page provides mineralogical data about Manganarsite.


Unique IdentifiersHide

Mindat ID:
2468
Long-form identifier:
mindat:1:1:2468:2

IMA Classification of ManganarsiteHide

Approved
IMA Formula:
Mn2+3As3+2O4(OH)4
Approval year:
1985

Classification of ManganarsiteHide

4.JB.10

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
J : Arsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodates
B : Arsenites, antimonites, bismuthites; with additional anions, without H2O
46.2.6.1

46 : ANTIMONITES AND ARSENITES CONTAINING HYDROXYL OR HALOGEN
2 : Miscellaneous
23.15

23 : Arsenites

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
MnaIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
MnaWarr (2020)Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of ManganarsiteHide

Hardness:

Optical Data of ManganarsiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.81 nε = 1.78
Max. Birefringence:
δ = 0.030
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of ManganarsiteHide

Mindat Formula:
Mn3(As2O4)(OH)4
Element Weights:
Element% weight
Mn36.897 %
As33.546 %
O28.655 %
H0.903 %

Calculated from ideal end-member formula.
Mn
As
O
H

Crystallography of ManganarsiteHide

Crystal System:
Trigonal
Cell Parameters:
a = 11.451(6) Å, c = 7.252(6) Å
Ratio:
a:c = 1 : 0.633
Unit Cell V:
823.52 ų (Calculated from Unit Cell)
Z:
4
Comment:
Space groups P-31m, P31m, P3m1 , or P312 .

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.49 Å(30)
3.62 Å(50)
2.662 Å(100)
1.845 Å(70)
1.652 Å(60)
1.531 Å(40)
5.74 Å(30)

Geological EnvironmentHide

Type Occurrence of ManganarsiteHide

Synonyms of ManganarsiteHide

Other Language Names for ManganarsiteHide

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Manganarsite associated with CalciteCaCO3

Related Minerals - Strunz-mindat GroupingHide

4.JB.CuyaiteCa2Mn3+As3+14O24ClMon. m
4.JB.BrattforsiteMn19(AsO 3)12Cl2Mon. 2/m : B2/b
4.JB.05Fetiasite(Fe3+,Fe2+,Ti)3(As2O5)O2Mon. 2/m : P21/m
4.JB.15'UM1984-09-AsO:ClHMn'Mn10As6O18(OH)ClTet. 4/mmm(4/m2/m2/m) : I41/acd
4.JB.15MagnussoniteMn2+10(As3+O3)6(OH,Cl)2Iso. m3m(4/m32/m) : Ia3d
4.JB.20ArmangiteMn2+26(AsO3)14(HAsO3)4(CO3)Trig. 3 : P3
4.JB.25NanlingiteNa(Ca5Li)Mg12(AsO3)2[Fe(AsO3)6]F14Trig. 3m(32/m) : R3m
4.JB.30AsbecasiteCa3(Ti,Sn4+)Be2(AsO3)6(SiO4)2Trig. 3m : P3c1
4.JB.35StenhuggariteCaFeSb(AsO3)2OTet. 4/mmm(4/m2/m2/m) : I41/amd
4.JB.40TrigonitePb3Mn2+(AsO3)2(HAsO3)Mon. m
4.JB.45FinnemanitePb5(AsO3)3ClHex. 6/m : P63/m
4.JB.50GebharditePb8(As2O5)2OCl6Mon. 2/m : P21/b
4.JB.55GraeseriteFe3+4Ti3As3+O13(OH)Mon. 2/m : B2/m
4.JB.55Tomichite(V,Fe)4Ti3AsO13(OH)Mon. 2/m : P21/m
4.JB.55DerbyliteFe3+4Ti3Sb3+O13(OH)Mon. 2/m : P21/m
4.JB.60Hemloite(Ti,V3+,Fe3+,Al)12(As3+,Sb3+)2O23(OH)Tric. 1 : P1
4.JB.65FreediteCu+Pb8(AsO3)2O3Cl5Mon. 2/m : B2/m
4.JB.70GeorgiadesitePb4(As3+O3)Cl4(OH)Mon. 2/m : P21/b
4.JB.75Szklaryite◻Al6BAs3+3O15Orth. mmm(2/m2/m2/m) : Pbcm
4.JB.75Ekatite(Fe3+,Fe2+,Zn)12(AsO3)6(AsO3,HSiO4)2(OH)6Hex. 6mm : P63mc
4.JB.85LepageiteMn2+3(Fe3+7Fe2+4)O3[Sb3+5As3+8O34]Tric. 1 : P1
4.JB.90BianchiniiteBa2(TiV)(As2O5)2OFTet. 4/mmm(4/m2/m2/m) : I4/mcm

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ManganarsiteHide

References for ManganarsiteHide

Localities for ManganarsiteHide

Showing 4 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
Skarpelis et al. (2009)
Italy
 
  • Liguria
    • Genoa
      • Ne
        • Reppia
Ciriotti et al. (2004)
Romania
 
  • Maramureș County
    • Târgu Lăpuș
HÎRTOPANU et al. (2025)
Sweden (TL)
 
  • Värmland County
    • Filipstad
      • Långban Ore District
Peacor et al. (1986) +1 other reference
 
and/or  
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