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Cumengeite

A valid IMA mineral species - grandfathered
This page kindly sponsored by John Kashuba
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About CumengeiteHide

Formula:
Pb21Cu20Cl42(OH)40 · 6H2O
Colour:
Indigo blue
Lustre:
Sub-Vitreous
Hardness:
Specific Gravity:
4.656
Crystal System:
Tetragonal
Name:
Named in honor of Bernard Louis Philippe Édouard Cumenge (16 April 1828, Castres, France - 20 July 1902, Paris, France), mining engineer at Boleo, Mexico. He collected the first specimens.
A secondary mineral.
May be confused with diaboleite.

Correct spelling defined by Burke (2008); other, incorrect spelling is cumengéite.


Unique IdentifiersHide

Mindat ID:
6894
Long-form identifier:
mindat:1:1:6894:5

Similar NamesHide

IMA Classification of CumengeiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Pb2+21Cu2+20Cl42(OH)40·6H2O

Classification of CumengeiteHide

3.DB.20

3 : HALIDES
D : Oxyhalides, hydroxyhalides and related double halides
B : With Pb, Cu, etc.
Dana 7th ed.:
10.6.7.1
10.6.7.1

10 : OXYHALIDES AND HYDROXYHALIDES
6 : AmBn(O,OH)pXq

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
CgeIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CumengeiteHide

Sub-Vitreous
Transparency:
Translucent
Colour:
Indigo blue
Streak:
Sky-blue
Hardness:
2½ on Mohs scale
Cleavage:
Distinct/Good
{101} good; {110} distinct; {001} Poor.
Density:
4.656 g/cm3 (Measured)    4.66 g/cm3 (Calculated)

Optical Data of CumengeiteHide

Type:
Uniaxial (-)
RI values:
nω = 2.026 - 2.041 nε = 1.926 - 1.965
Max. Birefringence:
δ = 0.076 - 0.100
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Pleochroism:
Visible
Comments:
Dichroic.
O = darker blue with green tint
E = Pure blue

Chemistry of CumengeiteHide

Mindat Formula:
Pb21Cu20Cl42(OH)40 · 6H2O
Element Weights:
Element% weight
Pb55.082 %
Cl18.850 %
Cu16.089 %
O9.317 %
H0.664 %

Calculated from ideal end-member formula.

Crystallography of CumengeiteHide

Crystal System:
Tetragonal
Class (H-M):
4/mmm(4/m2/m2/m) - Ditetragonal Dipyramidal
Space Group:
I4/mmm
Cell Parameters:
a = 15.065(2) Å, c = 24.436(5) Å
Ratio:
a:c = 1 : 1.622
Unit Cell V:
5,545.85 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Octahedral or cubo-octahedral crystals. Commonly on the faces of boleite or pseudoboleite.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014482CumengeiteHawthorne F C, Groat L A (1986) The crystal structure and chemical composition of cumengeite Mineralogical Magazine 50 157-1621986Boleo, Baja California, Mexico0293
CIF Raw Data - click here to close

Epitaxial Relationships of CumengeiteHide

Epitaxial Minerals:
'Boleite'KPb26Ag9Cu24(OH)48Cl62
'Pseudoboleite'Pb31Cu24Cl62(OH)48
Epitaxy Comments:
Parallel overgrowths of cumengite on crystals of boleite and pseudoboleite.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.02 Å(4)
4.86 Å(9)
3.98 Å(4)
3.73 Å(6)
3.08 Å(4)
2.66 Å(4)
2.38 Å(10)

Geological EnvironmentHide

Paragenetic Mode(s):
Geological Setting:
Secondary zone of lead deposits. Smelter slag immersed in sea water.

Type Occurrence of CumengeiteHide

Place of Conservation of Type Material:
Muséum Nationale d’Histoire Naturelle, Paris, France, numbers 93.252, 95.98.
Associated Minerals at Type Locality:

Synonyms of CumengeiteHide

Other Language Names for CumengeiteHide

Common AssociatesHide

Associations Based on Photo Data:
42 photos of Cumengeite associated with BoleiteKPb26Ag9Cu24(OH)48Cl62
21 photos of Cumengeite associated with PhosgenitePb2CO3Cl2
17 photos of Cumengeite associated with PseudoboleitePb31Cu24Cl62(OH)48
11 photos of Cumengeite associated with CerussitePbCO3
10 photos of Cumengeite associated with LaurionitePbCl(OH)
9 photos of Cumengeite associated with ParalaurionitePbCl(OH)
8 photos of Cumengeite associated with HemimorphiteZn4Si2O7(OH)2 · H2O
8 photos of Cumengeite associated with DiaboleitePb2CuCl2(OH)4
6 photos of Cumengeite associated with ParatacamiteCu3(Cu,Zn)(OH)6Cl2
6 photos of Cumengeite associated with AnglesitePbSO4

Related Minerals - Strunz-mindat GroupingHide

3.DB.RickturneritePb7O4[Mg(OH)4](OH)Cl3Orth. mmm(2/m2/m2/m) : Pnma
3.DB.05DiaboleitePb2CuCl2(OH)4Tet. 4mm : P4mm
3.DB.10PseudoboleitePb31Cu24Cl62(OH)48Tet. 4/mmm(4/m2/m2/m) : I4/mmm
3.DB.15BoleiteKPb26Ag9Cu24(OH)48Cl62Iso. m3m(4/m32/m) : Pm3m
3.DB.25BideauxitePb2AgCl3(F,OH)2Iso. m3m(4/m32/m) : Fd3m
3.DB.30ChloroxiphitePb3CuO2Cl2(OH)2Mon. 2/m : P21/m
3.DB.35HematophanitePb4Fe3O8(OH,Cl)Tet. 4mm : P4mm
3.DB.40ParkinsonitePb7MoO9Cl2Tet.
3.DB.40JanchevitePb9V5+(O10.250.75)Cl2.5Tric. 1 : P1
3.DB.40AsisitePb7SiO9Cl2 Tet. 4/mmm(4/m2/m2/m) : I4/mmm
3.DB.45EddaviditeCu12Pb2O15Br2Iso. m3m(4/m32/m) : Fm3m
3.DB.45MurdochiteCu12Pb2O15Cl2Iso. m3m(4/m32/m) : Fm3m
3.DB.50YedlinitePb6Cr3+Cl6(O,OH,H2O)8Trig. 3 : R3
3.DB.55SiidraitePb2Cu(OH)2I3Orth. mmm(2/m2/m2/m) : Fddd

Other InformationHide

Notes:
Soluble in HNO3.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for CumengeiteHide

References for CumengeiteHide

Reference List:

Localities for CumengeiteHide

Showing 66 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • New South Wales
    • Yancowinna Co.
      • Broken Hill district
Worner et al. (1982)
  • South Australia
    • City of Onkaparinga
      • Chandlers Hill
Kolitsch et al. (1999)
  • Tasmania
    • Central Coast municipality
      • Penguin
Bottrill et al. (2008)
  • Western Australia
    • Ashburton Shire
Nickel et al. (1993)
Grice et al. (1991)
    • Northampton Shire
Downes et al. (2017)
Downes et al. (2017)
Austria
 
  • Carinthia
    • Sankt Veit an der Glan District
      • Guttaring
        • Waitschach
Kolitsch et al. (2013)
Chile
 
  • Antofagasta
    • Antofagasta Province
      • Antofagasta
Arfè et al. (2016)
    • Tocopilla Province
      • Gatico District
Samples analysed by Dr. Jochen Schlüter (Hamburg University)
  • Atacama
    • Chañaral Province
      • Caballo Muerto mining district
SEM-EDS and Raman Spectroscopy by Joy ...
France
 
  • Provence-Alpes-Côte d'Azur
    • Var
      • Toulon
        • Le Pradet
Cap Garonne museum specimen - EDS ... +2 other references
Favreau et al. (2024)
Germany
 
  • Lower Saxony
    • Goslar District
      • Langelsheim
        • Astfeld
van den Berg et al. (1990)
        • Lautenthal
Karl Volkman collection
  • North Rhine-Westphalia
    • Düsseldorf
      • Essen
        • Dellwig
Weiß (1990)
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Charakas
Fritz Schreiber collection (Uwe Kolitsch SXRD-analysis)
Ko Jansen collection
        • Elaiochori
          • Dipseliza mines
Rieck (n.d.)
        • Lavreotiki Municipal Unit
The Minerals of Lavrion 2019
Ko Jansen collection
Grolig et al. (1978) +1 other reference
        • Sounion
          • Cato Sounio mines
Gröbner et al. (2002)
Gelaude et al. (1996)
        • Velatouri
Fritz Schreiber collection (U. Kolitsch SXRD analysis)
Gelaude et al. (1996)
Gelaude et al. (1996)
Italy
 
  • Campania
    • Metropolitan City of Naples
Russo et al. (2004)
      • Ottaviano
Cruciani et al. (2005)
Russo et al. (2004) +1 other reference
  • Lazio
    • Metropolitan City of Rome Capital
      • Anzio
Marco Bonifazi collection +1 other reference
  • Liguria
    • Genoa
      • Genoa
        • Varenna Valley
Rivista Mineralogica Italiana (3)
  • Sardinia
    • South Sardinia Province
      • Villaputzu
Orlandi et al. (2005)
  • Tuscany
    • Livorno Province
      • Campiglia Marittima
        • Madonna di Fucinaia (Madonna della Fucinaia) slag heaps
www.comune.pisa.it (2000)
      • Castagneto Carducci
Jansen et al. (1998)
      • Piombino
Franzini et al. (1992) +2 other references
      • Suvereto
Luigi Chiappino data
Mexico (TL)
 
  • Baja California Sur
    • Mulegé Municipality
      • Santa Rosalía
Mallard (1893) +3 other references
          • Arroyo de la Soledad
Rocks & Min.:63:390. +1 other reference
          • Arroyo del Boleo
Panczner (1987)
Norway
 
  • Nordland
    • Narvik
Husdal (2019)
Slovakia
 
  • Banská Bystrica Region
    • Revúca District
      • Nandraž
Koděra et al. (1986)
Spain
 
  • Andalusia
    • Almería
      • Cuevas del Almanzora
        • Sierra Almagrera
Christian Rewitzer collection - SEM-EDS ...
          • Jaroso Ravine
Valladares et al. (2021)
      • Pechina
        • Baños de Alhamilla
Rewitzer et al. (2020)
    • Jaén
      • Linares
        • La Cruz
Calvo Rebollar et al. (2022)
  • Asturias
Calvo Rebollar et al. (2018)
      • Meredo
        • Bedures hill (Vidures hill)
Calvo Rebollar et al. (2018)
  • Catalonia
    • Tarragona
      • Baix Camp
        • L'Argentera
Joan Abella i Creus specimens
Joan Abella i Creus (Joanabellacreus@gmail.com)
Turkmenistan
 
  • Balkan Region
    • Cheleken Peninsula
Lebedev et al. (1983)
UK
 
  • England
    • Cornwall
      • Crantock
BMS Newsletter 79 (http://britishmicromountsociety.homestead.com/Gannell-Smelter.html)
      • Falmouth
Dean et al. (1983) +1 other reference
      • Feock
        • Penpol
Sorrell (n.d.)
      • Newquay
        • Trevelgue
      • Padstow
        • Gunver Head
Golley et al. (1995)
Schlomann et al. (1998)
      • Perranzabuloe
        • Perranporth
          • Perran St George and Droskyn Mines
George Eric Stanley Curtis specimen
      • St Just
        • Botallack
Elton et al. (1995)
      • St Minver
        • Trebetherick
      • Tywardreath and Par
P
  • Wales
    • Gwynedd
      • Llanengan
        • Abersoch
Dossett et al. (1998)
USA
 
  • Arizona
    • Maricopa County
      • Osborn Mining District
        • Tonopah
          • Belmont Mountain
Collected by and in the collection of ...
      • Painted Rock Mountains
        • Painted Rock Mining District
          • Theba
Raman ID on 2007 material +2 other references
 
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