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Becquerelite

A valid IMA mineral species - grandfathered
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About BecquereliteHide

05284150017271921569300.jpg
Antoine Henri Becquerel
Formula:
Ca(UO2)6O4(OH)6 · 8H2O
Colour:
Amber-yellow, golden to lemon-yellow, yellow-orange, brownish yellow; yellow in transmitted light
Lustre:
Adamantine, Greasy
Hardness:
Specific Gravity:
5.09 - 5.2
Crystal System:
Orthorhombic
Name:
Named in honor of Antoine Henri Becquerel (15 December 1852, Paris, France – 25 August 1908, Le Croisic, Brittany, France), a physicist who discovered radioactivity in 1896. Among many honors, he was awarded the 1903 Nobel Prize in Physics, along with Marie Skłodowska-Curie and Pierre Curie.
Highly stable in the presence of hydrogen peroxide. At intermediate H2O2 concentrations, it is the second most stable phase after schoepite. At high concentrations of H2O2, the stability path is as follows: studtite, schoepite, metaschoepite, becquerelite.


Unique IdentifiersHide

Mindat ID:
597
Long-form identifier:
mindat:1:1:597:7

IMA Classification of BecquereliteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca(U6+O2)6O4(OH)6·8H2O
First published:
1922

Classification of BecquereliteHide

4.GB.10

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
G : Uranyl Hydroxides
B : With additional cations (K, Ca, Ba, Pb, etc.); with mainly UO2(O,OH)5 pentagonal polyhedra
5.7.1.2

5 : OXIDES CONTAINING URANIUM OR THORIUM
7 : AX6O19·xH2O
7.16.11

7 : Oxides and Hydroxides
16 : Oxides of U

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
BqrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BecquereliteHide

Adamantine, Greasy
Transparency:
Transparent
Colour:
Amber-yellow, golden to lemon-yellow, yellow-orange, brownish yellow; yellow in transmitted light
Streak:
Yellow
Hardness:
2½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
on {001}; imperfect on {101}, {010} and {110}
Density:
5.09 - 5.2 g/cm3 (Measured)    5.1 g/cm3 (Calculated)

Optical Data of BecquereliteHide

Type:
Biaxial (-)
RI values:
nα = 1.725 - 1.735 nβ = 1.815 - 1.825 nγ = 1.825 - 1.83
2V:
Measured: 32°
Max. Birefringence:
δ = 0.095 - 0.100
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v, marked
Pleochroism:
Visible
Comments:
X = colourless to pale yellow, Y = Z = yellow to deep yellow; Orientation: X = c, Y = a, Z = b

Chemistry of BecquereliteHide

Mindat Formula:
Ca(UO2)6O4(OH)6 · 8H2O
Element Weights:
Element% weight
U72.481 %
O24.360 %
Ca2.034 %
H1.125 %

Calculated from ideal end-member formula.
Common Impurities:
Pb

Crystallography of BecquereliteHide

Crystal System:
Orthorhombic
Class (H-M):
mm2 - Pyramidal
Space Group:
Pna21
Cell Parameters:
a = 13.8378 Å, b = 12.3781 Å, c = 14.9238 Å
Ratio:
a:b:c = 1.118 : 1 : 1.206
Unit Cell V:
2,556.23 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Crystals usually tabular on {001}, with a pseudohexagonal outline, also prismatic, elongated along [010] into thick laths; striations parallel to [100] on {010}; also as coatings and fine-grained aggregates.
Twinning:
On {110}, polysynthetic, producing pseudohexagonal aggregates.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0001132BecquerelitePagoaga M K, Appleman D E, Stewart J M (1987) Crystal structures and crystal chemistry of the uranyl oxide hydrates becquerelite, billietite, and protasite American Mineralogist 72 1230-12381987Shaba, Zaire0293
0012079BecquerelitePiret-Meunier J, Piret P (1982) Nouvelle determination de la structure cristalline de la bequerelite Bulletin de Mineralogie 105 606-6101982Shinkolobwe, Shaba, Zaire0293
0002790BecquereliteBurns P C, Li Y (2002) The structures of becquerelite and Sr-exchanged becquerelite put occ in tables American Mineralogist 87 550-55720020293
0002789BecquereliteBurns P C, Li Y (2002) The structures of becquerelite and Sr-exchanged becquerelite American Mineralogist 87 550-55720020293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.50 Å(10)
3.22 Å(9)
3.75 Å(8)
3.56 Å(8)
2.58 Å(7)
4.71 Å(6)
1.943 Å(5)
Comments:
Recorded on material from Shaba Province, Congo

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
27 : Radioactive decay; auto-oxidation
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47f : [Uranyl (U⁶⁺) minerals]
Geological Setting:
In oxidized portions of uranium deposits; also in pegmatites

Type Occurrence of BecquereliteHide

General Appearance of Type Material:
Fairly well formed, brownish yellow crystals to 0.45 mm.
Place of Conservation of Type Material:
Natural History Museum, Paris, France (No. 122.135)
Geological Setting of Type Material:
Among weathering products of uraninite in the oxidized portions of a uranium deposit
Associated Minerals at Type Locality:

Synonyms of BecquereliteHide

Other Language Names for BecquereliteHide

Common AssociatesHide

Associations Based on Photo Data:
54 photos of Becquerelite associated with UraniniteUO2
32 photos of Becquerelite associated with UranophaneCa(UO2)2(SiO3OH)2 · 5H2O
18 photos of Becquerelite associated with FourmarieritePb(UO2)4O3(OH)4 · 4H2O
12 photos of Becquerelite associated with Schoepite(UO2)8O2(OH)12 · 12H2O
10 photos of Becquerelite associated with Rutherfordine(UO2)CO3
10 photos of Becquerelite associated with CuritePb3(H2O)2[(UO2)4O4(OH)3]2
9 photos of Becquerelite associated with BillietiteBa(UO2)6O4(OH)6 · 4-8H2O
9 photos of Becquerelite associated with Studtite[(UO2)(O2)(H2O)2] · H2O
9 photos of Becquerelite associated with WölsendorfitePb7(UO2)14O19(OH)4 · 12H2O
8 photos of Becquerelite associated with Lepersonnite-(Gd)Ca(Gd,Dy)2(UO2)24(SiO4)4(CO3)8(OH)24 · 48H2O

Related Minerals - Strunz-mindat GroupingHide

4.GB.05RameauiteK2Ca(UO2)6O6(OH)4 · 6H2OMon. m : Bb
4.GB.05AgrinieriteK2(Ca,Sr)[(UO2)3O3(OH)2]2 · 5H2OMon. m : Bm
4.GB.05CompreignaciteK2(UO2)6O4(OH)6 · 7H2OOrth. mmm(2/m2/m2/m) : Pnnm
4.GB.10BillietiteBa(UO2)6O4(OH)6 · 4-8H2OOrth. mm2
4.GB.10ProtasiteBa(UO2)3O3(OH)2 · 3H2OMon. m
4.GB.15Richetite(Fe3+,Mg)Pb 8.6(UO2)36O36(OH)24 · 41H2O Tric. 1 : P1
4.GB.20Calciouranoite(Ca,Ba,Pb)U2O7 · 5H2O
4.GB.20BauranoiteBa(UO2)2(OH)6 · 1-2H2O
4.GB.20Metacalciouranoite(Ca,Ba,Pb,K2)U2O7 · 2H2O
4.GB.25FourmarieritePb(UO2)4O3(OH)4 · 4H2OOrth. mm2
4.GB.30WölsendorfitePb7(UO2)14O19(OH)4 · 12H2OOrth. mmm(2/m2/m2/m) : Cmcm
4.GB.35MasuyitePb(UO2)3O3(OH)2 · 3H2OOrth. mmm(2/m2/m2/m)
4.GB.40VandendriesscheitePbU7O22 · 12H2OOrth. mmm(2/m2/m2/m) : Pbca
4.GB.40MetavandendriesscheitePbU7O22 · nH2O n < 12Orth.
4.GB.45VandenbrandeiteCu(UO2)(OH)4Tric. 1 : P1
4.GB.50SayritePb2(UO2)5O6(OH)2 · 4H2OMon. 2/m
4.GB.55CuritePb3(H2O)2[(UO2)4O4(OH)3]2Orth. mmm(2/m2/m2/m) : Pnma
4.GB.60Iriginite(UO2)Mo2O7 · 3H2OOrth. mmm(2/m2/m2/m) : Pbcm
4.GB.65UranosphaeriteBi(UO2)O2(OH)Mon. 2/m
4.GB.70HolfertiteCaxU6+2-xTi(O8-xOH4x) · 3H2OTrig. 3 : P3
4.GB.75Carlosbarbosaite(UO2)2Nb2O6(OH)2 · 2H2OOrth. mmm(2/m2/m2/m) : Cmcm
4.GB.80GauthieriteKPb[(UO2)7O5(OH)7] · 8H2OMon. 2/m : P21/b
4.GB.85KroupaiteKPb0.5[(UO2)8O4(OH)10] · 10H2OOrth. mmm(2/m2/m2/m) : Pbca
4.GB.90LeesiteK(H2O)2[(UO2)4O2(OH)5] · 3H2OOrth. mmm(2/m2/m2/m) : Pbca
4.GB.95ShinkolobweitePb1.333[U5+O(OH)(UO2)5O4.67(OH)5.33](H2O)5Orth. mmm(2/m2/m2/m) : Pnnm
4.GB.95NollmotziteMg[U5+(U6+O2)2O4F3] · 4H2OMon. m : Bm

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 72.4811% 18,120,275 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 0.0000% 0 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BecquereliteHide

References for BecquereliteHide

Reference List:

Localities for BecquereliteHide

Showing 121 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • La Rioja Province
    • Coronel Felipe Varela department
      • Guandacol
Lucero et al. (1963)
Lucero et al. (1963)
American Mineralogist: 46: 12-25. +1 other reference
    • Vinchina department
      • Jagüé
        • Sierra de Cumichango
          • Quebrada de Cumichango
Las Especies Minerales de La Republica ...
Australia
 
  • Northern Territory
    • West Arnhem Region
      • South Alligator River
Henry et al. (2005)
Henry et al. (2005)
Austria
 
  • Salzburg
    • St. Johann im Pongau District
Paar et al. (1978)
      • Mühlbach am Hochkönig
Strasser (1989)
Brazil
 
  • Bahia
Pires et al. (2014)
Canada
 
  • Northwest Territories
    • North Slave Region
      • Great Bear Lake
Tyson (1989)
  • Nova Scotia
    • Cumberland Co.
Nova Scotia Natural Resources Mineral ...
  • Saskatchewan
    • Athabasca Basin
Cloutier et al. (2009)
Rich et al. (1977)
Anthony (1997)
    • Nistowiack Lake
Anthony (1997)
China
 
  • Guangdong
    • Shaoguan
      • Wengyuan Co.
Long Lu et al. (2006)
  • Sichuan
    • Panzhihua
      • Miyi County
        • Haita town
          • Uranium deposits
Zhao et al. (2026)
Czech Republic
 
  • Karlovy Vary Region
    • Karlovy Vary District
Hloušek et al. (2002)
        • Svornost Mine
Pauliš P. et al. (Kutna Hora, issue 1)
  • Olomouc Region
    • Jeseník District
      • Javorník
        • Horní Hoštice
Pauliš et al. (2004)
        • Zálesí
Sejkora (1994)
  • Plzeň Region
    • Tachov District
      • Tachov
        • Oldřichov
Pauliš P. et al. (Kutna Hora, issue 1)
DR Congo (TL)
 
  • Haut-Katanga
    • Kambove Territory
      • Shinkolobwe
Schoep (1922) +1 other reference
  • Lualaba
    • Mutshatsha
      • Kamoto
Deliens (1996)
Anthony et al. (2003)
Anthony et al. (2003)
Deliens (1992)
      • Kolwezi
Wilson (2018)
Egypt
 
  • Red Sea Governorate
Hussein et al. (1988)
France
 
  • Auvergne-Rhône-Alpes
    • Loire
      • Roanne
        • Saint-Priest-la-Prugne
- (1998)
J.-J. Périchaud: "Où trouver les minéraux d'Auvergne" et al. (Clermont-Ferrand)
    • Puy-de-Dôme
      • Thiers
        • Lachaux
- (1998)
Patrice Queneau Collection. Visual ...
    • Savoie
De Ascençao Guedes (2000)
  • Nouvelle-Aquitaine
    • Haute-Vienne
      • Bellac
        • Compreignac
- (1998)
      • Limoges
        • Saint-Sylvestre
- (1998)
  • Occitanie
    • Hérault
      • Lodève
        • Le Bosc
"minéraux uranifères +1 other reference
          • Saint-Martin
Personal Collection
        • Le Puech
Bariand et al. (1993) +2 other references
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Ortenaukreis
        • Oberwolfach
Walenta (1992) +1 other reference
  • Bavaria
    • Upper Palatinate
Dill et al. (2010)
  • Rhineland-Palatinate
    • Birkenfeld
      • Birkenfeld
        • Ellweiler
Aufschluss 69/ (7+8) +1 other reference
  • Saxony
    • Erzgebirgskreis
Wittern (2001)
Anthony (1997)
    • Vogtlandkreis
Gröbner et al. (2007) +1 other reference
Hungary
 
  • Baranya County
    • Pécs District
      • Kővágótöttös
Zsombor Eva
Italy
 
  • Lombardy
    • Lecco Province
      • Colico
        • Piona Peninsula
Vignola P. et al. (2011)
    • Sondrio Province
      • Novate Mezzola
        • Codera Valley
De Michele V. (1979)
  • Trentino-Alto Adige/Südtirol
    • Trento Province
      • Bocenago
        • Monte Toff
Ravagnani (1974)
      • Borgo Chiese
        • Condino
Campostrini et al. (2006)
      • Valdaone
        • Daone
          • Daone Valley
            • Limes
Campostrini et al. (2005)
Madagascar
 
  • Matsiatra Ambony
    • Ikalamavony District
      • Fitampito
Behier (1960)
Behier (1963)
  • Sava
    • Vohémar District
      • Maromokotra Loky Commune
Behier (1960)
Mexico
 
  • Chihuahua
    • Aldama Municipality
      • Peña Blanca District
        • Sierra Peña Blanca
Econ Geol (1991) +1 other reference
Namibia
 
  • Hardap Region
    • Daweb
Bowell et al. (2017)
New Zealand
 
  • West Coast Region
    • Buller District
      • Westport
Railton et al. (1990)
Norway
 
  • Troms og Finnmark
    • Salangen
Neumann (1985)
    • Tromsø
Neumann (1985)
Peru
 
  • Puno
    • Carabaya Province
Li (2016)
Poland
 
  • Lower Silesian Voivodeship
    • Lubin County
Kucha (2021)
    • Lwówek Śląski County
      • Gmina Lubomierz
        • Radoniów
Syczewski et al. (2023) +1 other reference
    • Polkowice County
      • Gmina Polkowice
Kucha (2021)
Romania
 
  • Bihor County
    • Nucet
Szakáll:Minerals of Carpathians
Russia
 
  • Zabaykalsky Krai
    • Krasnokamensky District
      • Krasnokamensk
Aleshin et al. (2007)
Slovakia
 
  • Košice Region
    • Rožňava District
      • Gemerská Poloma
Ferenc et al. (2018)
South Africa
 
  • Northern Cape
    • Namakwa District Municipality
      • Kamiesberg Local Municipality
Cairncross et al. (1995)
Spain
 
  • Community of Madrid
    • Soto del Real
      • San Pedro Massif
        • Rancajales
Gonzalez del Tánago (1985)
Switzerland
 
  • Valais
    • Martigny
      • Isérables
Stalder et al. (1998)
    • Saint-Maurice
      • Finhaut
        • Giétroz
Stalder et al. (1998) +1 other reference
      • Salvan
        • Les Marécottes
          • La Creusaz
UK
 
  • England
    • Cornwall
      • St Just
        • Botallack
Golley et al. (1995)
        • Pendeen
Golley et al. (1995)
    • Devon
      • West Devon
        • Dartmoor Forest
          • Princetown
Alysson Rowan collection +2 other references
USA
 
  • Arizona
    • Apache County
      • Cane Valley Mining District
        • Yazzie Mesa
          • Monument No. 2 channel
Frondel (1956) +4 other references
Frondel (1956) +4 other references
    • Coconino County
      • Cameron Mining District
        • Cameron
          • Huskon Mines (Huskon group)
Scarborough (1981)
      • Grand Canyon National Park
        • House Rock Wash
Scarborough (1981)
      • Sand Springs Mesa
Scarborough (1981)
    • Mohave County
      • Cerbat Mountains
        • Wallapai Mining District
Robert B. Scarborough (1981)
    • Navajo County
      • Holbrook
Galbraith (1959)
      • Joseph City
Scarborough (1981)
  • California
    • Ventura County
Dickinson +1 other reference
  • Colorado
    • Gunnison County
Eckel et al. (1997)
    • Jefferson County
      • Critchell area
Eckel et al. (1997)
    • Moffat County
      • Maybell Mining District
        • Maybell Mines
Eckel et al. (1997)
Eckel et al. (1997)
    • Saguache County
Gross (1965) +1 other reference
Eckel et al. (1997)
  • Connecticut
    • Middlesex County
      • Haddam
        • Haddam Neck
Schooner (circa 1980s) +1 other reference
  • New Hampshire
    • Cheshire County
      • Marlow
Personal collection and XRD analysis by ...
    • Grafton County
      • Grafton
  • New Mexico
    • Cibola County
Northrop et al. (1996)
NMBMMR Memoir 15 Geology and Technology ...
Anthony (1997)
NMBMMR Memoir 15 Geology and Technology ... +1 other reference
  • North Carolina
    • Mitchell County
Finch et al. (1997)
Finch et al. (1997)
      • Spruce Pine
        • Greasy Creek Township
American Mineralogist +1 other reference
    • Yancey County
      • Celo
        • Micaville
Finch et al. (1997)
  • South Dakota
    • Fall River County
Page et al. (1956) +3 other references
    • Pennington County
      • Keystone Mining District
        • Keystone
Rocks & Min.:10:147 & 60:112
  • Utah
    • Emery County
      • San Rafael Swell Mining District
        • Green Vein Mesa
Bullock (1981)
Bullock (1981)
Bullock (1981)
Page et al. (1956) +3 other references
    • Grand County
      • Seven Mile Canyon Mining District
USGS Circular 336 +1 other reference
    • San Juan County
      • Deer Flat Mining District
Bullock (1981)
      • Lisbon Valley Mining District
        • Casa Colorado Rock
Bullock (1981)
      • Red Canyon Mining District
Page et al. (1956) +3 other references
Bullock (1981)
Joe Marty photo
Yedlin (1971)
Desor (11/2020)
    • Wayne County
      • Fremont Mining District
Bullock (1981)
  • Wyoming
    • Campbell County
Anthony (1997)
    • Fremont County
Hausel et al. (2001)
USGS MRDS Database
Hausel et al. (2001)
 
and/or  
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