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Pascoite Family

A group of related mineral species
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About Pascoite FamilyHide

A collection of minerals featuring the V10O28 "decavanadate" cluster in a spacious network of hydrogen bonds with various cations. Some minerals exhibit variations in the oxidation state of, or substitutions for, vanadium (e.g., trebiskyite). This is not a traditional mineral "group" because the members are not truly isostrucural, which is why Kampf et al. (2021) defined them as a "pascoite family". However, their structures all exhibit the same general architecture.


Unique IdentifiersHide

Mindat ID:
55048
Long-form identifier:
mindat:1:1:55048:6

Classification of Pascoite FamilyHide

00669880017683444897551.jpg
The Decavanadate Cluster

The decavanadate cluster found in the pascoite family.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
M12005BurroiteKampf, Anthony R., Nash, Barbara P., Hughes, John M., Marty, Joe (2017) Burroite, Ca2(NH4)2(V10O28)·15H2O, a new decavanadate mineral from the Burro Mine, San Miguel County, Colorado. The Canadian Mineralogist, 55 (3) 473-481 doi:10.3749/canmin.17000042017Burro Mine, Colorado, USA0293
M11981HydropascoiteKampf, A.R., Nash, B.P., Marty, J., Hughes, J.M., Rose, T.P. (2017) Hydropascoite Kampf, Anthony R., Nash, Barbara P., Marty, Joe, Hughes, John M., Rose, Timothy P. Hydropascoite, Ca3(V10O28)·24H2O, a new decavanadate mineral from the Packrat Mine, Mesa County, Colorado. The Canadian Mineralogist, 55 (2) 207-217 doi:10.3749/canm2017Packrat Mine, Colorado, USA0293
M12002BluestreakiteKampf, Anthony R., Hughes, John M., Marty, Joe, Nash, Barbara P., Chen, Yu-Sheng, Steele, Ian M. (2014) Bluestreakite, K4Mg2(V4+2V5+8O28)·14H2O, a new mixed-valence decavanadate mineral from the Blue Streak Mine, Montrose County, Colorado: crystal structure and descriptive mineralogy. The Canadian Mineralogist, 52 (6) 1007-1018 doi:10.3749/canmin.14000722014Blue Streak Mine, Colorado, USA0293
0019898WernerbauriteKampf A R, Hughes J M, Marty J, Nash B (2013) Wernerbaurite, {[Ca(H2O)7]2(H2O)2(H3O)2}{V10O28}, and schindlerite, {[Na2(H2O)10](H3O)4}{V10O28}, the first hydronium-bearing decavanadate minerals The Canadian Mineralogist 51 297-3122013St. Jude mine, San Miguel County, Colorado, U.S.A.0293
0019899SchindleriteKampf A R, Hughes J M, Marty J, Nash B (2013) Wernerbaurite, {[Ca(H2O)7]2(H2O)2(H3O)2}{V10O28}, and schindlerite, {[Na2(H2O)10](H3O)4}{V10O28}, the first hydronium-bearing decavanadate minerals The Canadian Mineralogist 51 297-3122013St. Jude mine, San Miguel County, Colorado, U.S.A.0293
0019804NashiteKampf A R, Hughes J M, Marty J, Brown F H (2013) Nashite, Na3Ca2[(V4+V5+9)O28]*24H2O, a new mineral species from the Yellow Cat Mining District, Utah and the Slick Rock Mining District, Colorado: crystal structure and descriptive mineralogy The Canadian Mineralogist 51 27-372013Little Eva mine, Grand County, Utah, USA0293
0019040PostiteKampf A R, Hughes J M, Marty J, Nash B (2012) Postite, Mg(H2O)6Al2(OH)2(H2O)8(V10O28)*13H2O, a new mineral species from the La Sal Mining District, Utah: Crystal structure and descriptive mineralogy The Canadian Mineralogist 50 45-532012La Sal Mining District, Utah, USA0293
0018627GunteriteKampf A R, Hughes J M, Marty J, Nash B (2011) Gunterite, Na4(H2O)16(H2V10O28)*6H2O, a new mineral species with a doubly-protonated decavanadate polyanion: crystal structure and descriptive mineralogy The Canadian Mineralogist 49 1243-12512011West Sunday mine, San Miguel County, Colorado, USA0293
0018981HughesiteRakovan J, Schmidt G R, Gunter M E, Nash B, Marty J, Kampf A R, Wise W S (2011) Hughesite, Na3Al(V10O28)*22H2O, a new member of the pascoite family of minerals from the Sunday mine, San Miguel county, Colorado The Canadian Mineralogist 49 1253-12652011Sunday mine, San Miguel county, Colorado0293
0018383RakovaniteKampf A R, Hughes J M, Marty J, Gunter M E, Nash B (2011) Rakovanite, Na3{H3[V10O28]}*15H2O, a new member of the pascoite family with a protonated decavanadate polyanion The Canadian Mineralogist 49 595-6042011Synthetic0293
0018461HuemuliteColombo F, Baggio R, Kampf A R (2011) The crystal structure of the elusive huemulite The Canadian Mineralogist 49 849-8642011West Sunday mine, Utah, USA0293
0018460HuemuliteColombo F, Baggio R, Kampf A R (2011) The crystal structure of the elusive huemulite The Canadian Mineralogist 49 849-8642011synthetic0293
0006192MagnesiopascoiteKampf A R, Steele I M (2008) Magnesiopascoite, a new member of the pascoite group: description and crystal structure The Canadian Mineralogist 46 679-6862008Blue Cap mine, San Juan County, Utah, USA0293
0006198LasaliteHughes J M, Wise W S, Gunter M E, Morton J P, Rakovan J (2008) Lasalite, Na2Mg2[V10O28]*20H2O, a new decavanadate mineral species from the Vanadium Queen mine, La Sal District, Utah: Description, atomic arrangement, and relationship to the pascoite group of minerals The Canadian Mineralogist 46 1365-13722008Vanadium Queen mine, La Sal District, Utah0293
0006048PascoiteHughes J M, Schindler M, Francis C A (2005) The C2/m disordered structure of pascoite, Ca3[V10O28]*17H2O: Bonding between structural units and interstitial complexes in compounds containing the [V10O28]6- decavanadanate polyanion The Canadian Mineralogist 43 1379-13862005Minasragra, Peru0293
0010329LasaliteIida A, Ozeki T (2004) Mg2Na2V10O28*20H2O and Mg3V10O28*28H2O Acta Crystallographica C60 i43-i462004synthetic0293
0018393RakovaniteDuraisamy T, Ramanan A, Vittal J J (2000) Novel self-assembled decavanadate clusters forming 1D molecular chains and 2D molecular arrays: [HMTA-H...H2O][HMTA-CH2OH][H3V10O28{Na(H2O)4}]*4H2O and [Na2(H2O)10] [H3V10O28 {Na(H2O)2}]*3H2O Crystal Engineering 3 237-2502000Synthetic0293
M11971ProtocaseyiteKampf, A.R., Cooper, M.A., Hughes, J.M., Ma, C., Casey, W.H., Hawthorne, F.C., Marty, J. (2022) Protocaseyite Kampf, Anthony R., Cooper, Mark A., Hughes, John M., Ma, Chi, Casey, William H., Hawthorne, Frank C., Marty, Joe Protocaseyite, a new decavanadate mineral containing a [Al4(OH)6(H2O)12]6+ linear tetramer, a novel isopolycation. American Mineralogis2022Burro Mine, Colorado, USA00
M11968CaseyiteKampf, A.R., Cooper, M.A., Hughes, J.M., Nash, B.P., Hawthorne, F.C., Marty, J. (2020) Caseyite Kampf, Anthony R., Cooper, Mark A., Hughes, John M., Nash, Barbara P., Hawthorne, Frank C., Marty, Joe Caseyite, a new mineral containing a variant of the flat-Al13 polyoxometalate cation. American Mineralogist, 105 (1) 123-131 doi:10.2138/am-2020-20200293
0005792HummeriteHughes J M, Schindler M, Rakovan J F, Cureton F E (2002) The crystal structure of hummerite, K Mg(V5O14).8H2O: Bonding between the [V10O28] structural units and the {K2Mg2(H2O)16} interstitial complex The Canadian Mineralogist 40 1429-143520020293
CIF Raw Data - click here to close

Synonyms of Pascoite FamilyHide

Relationship of Pascoite Family to other SpeciesHide

Pascoite Family Members:
Ammoniolasalite [(NH4)2Mg2(H2O)20] [V10O28]Mon. 2/m : B2/b
Bluestreakite K4Mg2(V4+2V5+8O28) · 14H2OMon. 2/m
Burroite Ca2(NH4)2(V10O28) · 15H2OTric. 1 : P1
Caseyite [(V5+O2)Al10-x(OH)20-2x(H2O)18-2x]2[H2V4+V5+9O28][V5+10O28]2(Na,K,Ca)2-y(SO4)2-z · (60+8x+y+4z)H2O (x = 0-2.5; y = 0-2; z = 0-2)Mon.
Flatimerite [Al13(OH)24(H2O)24][V5+9V4+O28] · [(SO4)4(H2O)24]Tric. 1 : P1
Gunterite Na4Ca(V10O28) · 20H2OMon. 2/m : B2/m
Huemulite Na4Mg(V10O28) · 24H2OTric.
Hughesite Na3Al(V10O28) · 22H2OTric. 1 : P1
Hummerite K2Mg2(V10O28) · 16H2OTric. 1 : P1
Hydropascoite Ca3(V10O28) · 24H2OTric. 1 : P1
Kokinosite Na2Ca2(V10O28) · 24H2OTric. 1 : P1
Lasalite Na2Mg2(V10O28) · 20H2OMon. 2/m : B2/b
Magnesiopascoite Ca2Mg(V10O28) · 16H2OMon. 2/m : B2/m
Nashite Na3Ca2[(V5+9V4+)O28] · 24H2OMon. 2/m : P21/m
Okieite Mg3[V10O28] · 28H2OTric. 1 : P1
Pascoite Ca2Ca(V10O28) · 17H2OMon. 2 : B2
Postite Mg(H2O)6Al2(OH)2(H2O)8(V10O28) · 13H2OOrth. mmm(2/m2/m2/m) : Pccn
Protocaseyite [Al4(OH)6(H2O)12][V10O28] · 8H2OTric. 1 : P1
Rakovanite (NH4)3Na3(V10O28) · 12H2OMon. 2/m
Schindlerite {(NH4)4Na2(H2O)10}{V10O28}Tric. 1 : P1
Trebiskyite Na3Mg2[TiV9O28] · 22H2OMon. 2/m : P21/b
Wernerbaurite {(NH4)2[Ca2(H2O)14](H2O)2}{V10O28}Tric. 1 : P1
Click on any node to view relationships. Formula-derived relationship network for the group members above. Use Find related species to add formula-neighbour species outside the current group view. Solid links show inferred chemical differences; dashed violet links show same-formula crystallographic differences. Hydration states are not treated as relationship changes. These relationships do not imply any real-world substitution reactions between these species.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Pascoite FamilyHide

References for Pascoite FamilyHide

Localities for Pascoite FamilyHide

Showing 227 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • La Rioja Province
    • Coronel Felipe Varela department
      • Guandacol
[Pascoite] de Brodtkorb (1982)
  • Mendoza Province
    • Malargüe Department
      • Pampa Amarilla mining district
[Huemulite] Gordillo et al. (1966)
[Huemulite] Anthony et al. (1997)
[Huemulite] Anthony et al. (1997)
[Huemulite, Hummerite] Gordillo et al. (1966)
China
 
  • Zhejiang
    • Hangzhou
      • Yuhang District
[Pascoite] Huijin Lu and Jian Wang (2005)
Czech Republic
 
  • Central Bohemian Region
[Huemulite, Pascoite] Josef Vajdak (2008)
      • Dubno
[Huemulite, Pascoite] Sejkora et al. (2003)
  • Pardubice Region
    • Chrudim District
      • Prachovice
[Pascoite] Sejkora et al. (2013)
Germany
 
  • Thuringia
    • Greiz District
      • Kauern
[Hummerite] Witzke et al. (1998)
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Agios Konstantinos (Kamariza)
[Huemulite, Pascoite] Färber (n.d.) +2 other references
Italy
 
  • Liguria
    • Genoa
      • Ne
[Hummerite, Pascoite] Balestra et al. (2009) +1 other reference
        • Reppia
[Pascoite] Balestra et al. (2009) +1 other reference
Kyrgyzstan
 
  • Batken Region
    • Kadamjay District
[Hummerite] Karpenko et al. (2009)
Peru
 
  • Pasco
    • Pasco Province
      • Huayllay District
[Pascoite] Hillebrand et al. (1914) +2 other references
Romania
 
  • Maramureș County
    • Târgu Lăpuș
[Hummerite] HÎRTOPANU et al. (2025)
Spain
 
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • Tenerife
        • Candelaria
          • Barranco Hondo
[Pascoite] Dill et al. (2023)
[Pascoite] Dill et al. (2023)
  • Catalonia
    • Lleida
      • Pallars Jussà
        • La Vall Fosca
          • La Torre de Cabdella
            • Castell-estaó
[Huemulite] Joy Desor analysis by Raman spectroscopy and SEM-EDS: Desor (2018)
UK
 
  • England
    • Devon
      • East Devon
        • Budleigh Salterton
[Huemulite, Pascoite] Brian Craik-Smith collection (NHM London XRD ID)
USA
 
  • Arizona
    • Apache County
      • Cane Valley Mining District
        • Yazzie Mesa
          • Monument No. 2 channel
[Pascoite] Witkind (1963) +1 other reference
      • Carrizo Range
        • Black Rock Point Mining District
          • Black Rock Point
[Pascoite] Scarborough (1981) +1 other reference
        • Northeast Carrizo Mountains Mining District
          • Teec Nos Pos
[Pascoite] Galbraith (1959)
[Pascoite] Page et al. (1956) +2 other references
        • Lukachukai Mining District
          • White Ash Peak
[Hummerite, Pascoite] Page et al. (1956) +2 other references
[Pascoite] Scarborough (1981)
[Pascoite] Scarborough (1981)
[Pascoite] Scarborough (1981)
[Hummerite, Pascoite] Scarborough (1981)
[Pascoite] Galbraith (1959) +2 other references
[Pascoite] Galbraith (1959) +2 other references
[Hummerite, Pascoite] Galbraith (1959) +1 other reference
  • Colorado
    • Garfield County
      • East Rifle Creek area
[Pascoite] - (2005)
[Pascoite] Eckel et al. (1997)
    • Mesa County
      • Gateway Mining District
        • Beaver Mesa
[Ammoniolasalite, Hummerite, Schindlerite] In the collection of Alex Earl
[Pascoite] Eckel et al. (1997)
[Hummerite, Magnesiopascoite, Postite] Tony Kampf Identification
[Caseyite, Hummerite, Hydropascoite, Lasalite, Magnesiopascoite, Pascoite, Postite] Kampf et al. (2017)
    • Montrose County
[Pascoite] Luc Vandenberghe collection
[Bluestreakite, Huemulite, Hughesite, Hummerite, Magnesiopascoite, Pascoite] Kampf et al. (2012) +1 other reference
      • Bull Canyon
[Hummerite, Pascoite] Eckel et al. (1997)
[Pascoite] Collection of Alex Earl
      • Gypsum Valley
[Magnesiopascoite] Nikischer
[Pascoite] Eckel et al. (1997)
[Hummerite] Eckel et al. (1997)
      • Paradox Valley
[Pascoite] USGS Bull 1042F +1 other reference
[Hummerite, Okieite] Hurlbut (1951)
[Hummerite, Pascoite] Eckel et al. (1997)
[Pascoite] Dana 7:I:602.
[Bluestreakite, Huemulite, Kokinosite, Pascoite, Trebiskyite] Carnegie Museum of Natural History ...
[Pascoite] Wm. Walker Collection
[Hummerite] Eckel et al. (1997)
    • Pueblo County
      • Turkey Creek Mining District
[Hummerite] Eckel et al. (1997)
    • San Miguel County
[Pascoite] Jamison K. Brizendine
      • Bull Pen Canyon
[Pascoite] Rocks & Minerals 80:5 pp358-359
[Ammoniolasalite, Burroite, Caseyite, Flatimerite, Gunterite, Huemulite, Hughesite, Kokinosite, Lasalite, Magnesiopascoite, Okieite, Pascoite, Postite, Protocaseyite, Schindlerite, Wernerbaurite] Kampf et al. (2019)
      • Carnation Mine Group (Rye No. 8)
[Pascoite] Excalibur Mineral Co. sample and ...
[Pascoite] Eckel et al. (1997)
[Pascoite] Haynes (1992) +1 other reference
      • Gypsum Valley Mining District
[Pascoite] Amended Technical Report on Energy ...
      • Lower San Miguel Mining District
[Pascoite] Eckel et al. (1997)
[Pascoite] Thorne (n.d.)
    • Slick Rock Mining District
[Huemulite, Hughesite, Kokinosite, Nashite, Pascoite, Rakovanite, Schindlerite, Wernerbaurite] Collected by and in the collection of ...
[Huemulite, Hughesite] Collected by and in the collection of ...
[Gunterite, Hughesite, Lasalite, Pascoite, Rakovanite] Min News (1987)
[Pascoite] Collection of Alex Earl
[Caseyite, Gunterite, Huemulite, Hughesite, Pascoite, Rakovanite] Kampf et al. (2012)
  • Nevada
    • Eureka County
      • Carlin Trend
        • Maggie Creek Mining Subdistrict
[Hummerite] Newmont Mining Corporation
      • Fish Creek Mining District
[Huemulite] Castor et al. (2004)
      • Gibellini Mining District
        • Fish Creek Range
[Huemulite] Rocks & Minerals. Nov. 1999.
[Huemulite] Castor et al. (2004)
[Huemulite] Frost et al. (2005)
      • Lynn Mining District
[Hummerite] Jensen et al. (1995)
    • Humboldt County
      • Osgood Mountains
        • Potosi Mining District
          • Adam Peak
            • Getchell Mine
[Pascoite] Castor et al. (2004)
  • New Mexico
    • Cibola County
      • Laguna subdistrict
[Magnesiopascoite] Caldwell (2018)
[Pascoite] Northrop et al. (1996)
    • McKinley County
[Pascoite] Betts (n.d.)
      • Church Rock - Crownpoint subdistrict
[Pascoite] NMBMMR Memoir 15 Geology and Technology ...
[Pascoite] NMBMMR Memoir 15 Geology and Technology ...
[Pascoite] NMBMMR Memoir 15 Geology and Technology ...
[Pascoite] NMBMMR Memoir 15 Geology and Technology ...
      • Poison Canyon area
[Pascoite] NMBMMR Memoir 38 Geology and Technology ...
[Pascoite] NMBMMR Memoir 15 Geology and Technology ...
[Pascoite] NMBMMR Memoir 15 Geology and Technology ...
[Pascoite] NMBMMR Memoir 15 Geology and Technology ...
    • San Juan County
[Pascoite] Northrop et al. (1996)
        • Eastside mines
[Pascoite] Northrop et al. (1996)
  • South Dakota
    • Fall River County
[Hummerite, Pascoite] USGS Bull 1063D +4 other references
        • Craven Canyon
[Hummerite] Roberts et al. (1965)
[Hummerite] Roberts et al. (1965)
[Hummerite] Roberts et al. (1965)
[Hummerite] Roberts et al. (1965)
[Hummerite, Pascoite] Roberts et al. (1965)
  • Utah
    • Emery County
[Hummerite, Pascoite] Bullock (1981)
[Hummerite, Magnesiopascoite]
[Hummerite, Magnesiopascoite] Collected by and in the collection of ...
[Pascoite] - (2005)
[Pascoite] Collected by and in the collection of ...
    • Garfield County
      • East Henry Mountains Mining District
[Pascoite] Bullock (1981)
    • Grand County
      • Gateway Mining District
[Pascoite, Postite] Collected by and in the collection of ...
      • Thompsons Mining District
        • AEC Group
[Pascoite] - (2005)
[Pascoite] Bullock (1981) +1 other reference
[Pascoite] - (2005)
        • D-Day Mine group
[Pascoite] Collected by Michael Cline +1 other reference
[Huemulite] Pavel M. Kartashov analytical data 2015
[Pascoite] - (2005)
[Pascoite] Sorrell (n.d.)
        • Mollie Hogans
[Pascoite] - (2005)
[Pascoite] - (2005)
[Huemulite] Kampf et al. (2025)
        • The Poison Strip
[Pascoite] - (2005)
[Pascoite] - (2005)
[Pascoite] - (2005)
[Pascoite] - (2005)
[Pascoite] - (2005)
[Pascoite] - (2005)
[Pascoite] - (2005)
        • Yellow Cat Mesa
[Huemulite, Hughesite, Kokinosite, Lasalite, Nashite, Pascoite] Kasatkin et al. (2014) +1 other reference
[Pascoite] - (2005)
    • San Juan County
      • Cottonwood Canyon Mining District
[Pascoite] - (2005)
[Pascoite] - (2005)
[Pascoite] - (2005)
[Pascoite] - (2005)
[Pascoite] - (2005)
      • La Sal Creek Mining District
[Postite] Collected By Chuck Adan
[Lasalite, Magnesiopascoite, Pascoite, Postite] Kampf et al. (2012)
[Lasalite, Magnesiopascoite, Pascoite] Canadian Mineralogist (2001)
[Pascoite] Carter et al. (1965) +1 other reference
[Hummerite, Lasalite, Magnesiopascoite, Okieite, Pascoite, Postite, Rakovanite] Collected and analyzed by Joy Desor.
      • La Sal Mining District
[Ammoniolasalite, Lasalite, Magnesiopascoite, Okieite, Pascoite, Postite, Wernerbaurite] Färber (n.d.)
      • Lisbon Valley Mining District
[Pascoite] Page et al. (1956) +2 other references
      • Montezuma Canyon Mining District
        • Coal Bed Canyon Group
[Pascoite] Bullock (1981)
 
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