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Beshtauite

A valid IMA mineral species
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About BeshtauiteHide

06915420017271951772536.jpg
Mount Beshtau, Russia
Formula:
(NH4)2(UO2)(SO4)2 · 2H2O
Colour:
Light green
Lustre:
Vitreous
Hardness:
2
Specific Gravity:
3.046 (Calculated)
Crystal System:
Monoclinic
Name:
Named after Mount Beshtau, Russia, the type locality.
New structure type. Beshtauite is important indicator mineral: its presence can be considered as an evidence of transportation of U6+ in nature in forms of mobile complexes of uranyl cation with ammonia or polyamines.


Unique IdentifiersHide

Mindat ID:
43574
Long-form identifier:
mindat:1:1:43574:3

Similar NamesHide

BeschtauiteA rock subtype

IMA Classification of BeshtauiteHide

Classification of BeshtauiteHide

7.EC.

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
E : Uranyl sulfates
C : With medium-sized and large cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
BesIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BeshtauiteHide

Vitreous
Transparency:
Transparent
Colour:
Light green
Hardness:
Comment:
ca. 2
Tenacity:
Brittle
Cleavage:
None Observed
Density:
3.046 g/cm3 (Calculated)

Optical Data of BeshtauiteHide

Type:
Biaxial (+)
RI values:
nα = 1.566(3) nβ = 1.566(3) nγ = 1.592(3)
2V:
Measured: < 10°
Max. Birefringence:
δ = 0.026
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.

No measured or calculated 2V is on file for this mineral, so the value used here (0°) is estimated from its recorded refractive indices and optic sign, not from a direct 2V measurement.

Chemistry of BeshtauiteHide

Mindat Formula:
(NH4)2(UO2)(SO4)2 · 2H2O
Element Weights:
Element% weight
U44.553 %
O35.936 %
S12.004 %
N5.243 %
H2.264 %

Calculated from ideal end-member formula.
U
O
S
N
H

Crystallography of BeshtauiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 7.7360(8) Å, b = 7.3712(5) Å, c = 20.856(2) Å
β = 102.123(8)°
Ratio:
a:b:c = 1.049 : 1 : 2.829
Unit Cell V:
1162.76 ų
Z:
4
Morphology:
Short-prismatic.
Comment:
From single-crystal X-ray diffraction data.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0020412BeshtauitePekov I V, Krivovichev S V, Yapaskurt V O, Chukanov N V, Belakovskiy D I (2014) Beshtauite, (NH4)2(UO2)(SO4)2*2H2O, a new mineral from Mount Beshtau, Northern Caucasus, Russia American Mineralogist 99 1783-17872014Mount Beshtau, Stavropol region, Northern Caucasus, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47b : [Sulfates and sulfites]
47f : [Uranyl (U⁶⁺) minerals]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
53 : Other minerals with taphonomic origins<0.4

Type Occurrence of BeshtauiteHide

General Appearance of Type Material:
Well-shaped short-prismatic crystals up to 0.1 × 0.15 × 0.2 mm, their clusters and crusts up to 0.5 mm across growing on marcasite.
Place of Conservation of Type Material:
Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia, registration number 4280/1
Geological Setting of Type Material:
Oxidation zone of the Beshtau uranium deposit, Northern Caucasus, Russia.
Associated Minerals at Type Locality:

Synonyms of BeshtauiteHide

Other Language Names for BeshtauiteHide

German:Beshtauit

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Beshtauite associated with QuartzSiO2

Related Minerals - Strunz-mindat GroupingHide

7.EC.Nitscheite(NH4)2[(UO2)2(SO4)3(H2O)2] · 3H2OMon. 2/m
7.EC.Oldsite-(K)K2Fe2+[(UO2)(SO4)2]2(H2O)8Orth. mm2 : Pmn21
7.EC.AdolfpateraiteK(UO2)(SO4)(OH)(H2O)Mon. 2/m : P21/b
7.EC.Libbyite(NH4)2(Na2◻)[(UO2)2(SO4)3(H2O)]2 · 7H2OTet. 422 : P41212
7.EC.SeaborgiteLiK2Na6(UO2)(SO4)5(SO3OH)(H2O)Tric. 1 : P1
7.EC.05ZinczippeiteZn(UO2)2(SO4)O2 · 3.5H2OMon. 2/m : B2/m
7.EC.05ZippeiteK3(UO2)4(SO4)2O3(OH) · 3H2OMon. 2 : B2
7.EC.05CobaltzippeiteCo(UO2)2(SO4)O2 · 3.5H2OMon. 2/m : B2/m
7.EC.05NickelzippeiteNi2(UO2)6(SO4)3(OH)10 · 16H2OMon.
7.EC.05Redcanyonite(NH4)2Mn[(UO2)4O4(SO4)2](H2O)4Mon. 2/m : B2/m
7.EC.05NatrozippeiteNa5(UO2)8(SO4)4O5(OH)3 · 12H2OMon. 2/m : P21/m
7.EC.05MagnesiozippeiteMg(UO2)2(SO4)O2 · 3.5H2OMon. 2/m : B2/m
7.EC.05Ammoniozippeite(NH4)2[(UO2)2(SO4)O2] · H2OOrth. mmm(2/m2/m2/m) : Cmca
7.EC.05PlavnoiteK0.8Mn0.6[(UO2)2O2(SO4)] · 3.5H2OMon. 2/m : B2/m
7.EC.10RabejaciteCa(UO2)4(SO4)2(OH)6 · 6H2OTric. 1 : P1
7.EC.10Svornostite-(NH4)(NH4)2Mg(UO2)2(SO4)4(H2O)8Orth. mm2 : Pmn21
7.EC.10Svornostite-(K)K2Mg[(UO2)(SO4)2]2(H2O)8Orth. mm2 : Pmn21
7.EC.15Sejkoraite-(Y)Y2(UO2)8(SO4)4O6(OH)2 · 26H2OTric. 1 : P1
7.EC.15MarécottiteMg3(UO2)8(SO4)4O6(OH)2 · 28H2OTric. 1 : P1
7.EC.15HubbarditeMg(H2O)6[(UO2)2O(OH)(SO4)]2 · 8H2OOrth. mmm(2/m2/m2/m) : Fddd
7.EC.20PseudojohanniteCu3(UO2)4(SO4)2O4(OH)2 · 12H2OTric. 1 : P1
7.EC.40BluelizarditeNa7(UO2)(SO4)4Cl(H2O)2Mon. 2/m : B2/b
7.EC.45MeisseriteNa5(UO2)(SO4)3(SO3OH)(H2O)Tric. 1 : P1
7.EC.45FermiiteNa4(UO2)(SO4)3 · 3H2OOrth. mm2 : Pmn21
7.EC.45OppenheimeriteNa2(UO2)(SO4)2 · 3H2OTric. 1 : P1
7.EC.50FeynmaniteNa(UO2)(SO4)(OH) · 3.5H2OMon.
7.EC.50PlášiliteNa(UO2)(SO4)(OH) · 2H2OMon. 2/m : P21/b
7.EC.55GeschieberiteK2(UO2)(SO4)2 · 2H2OOrth. mm2 : Pna21
7.EC.60OttohahniteNa6(UO2)2(SO4)5(H2O)7 · 1.5H2OTric. 1 : P1
7.EC.65PéligotiteNa6(UO2)(SO4)4 · 4H2OTric. 1 : P1
7.EC.70KlaprothiteNa6(UO2)(SO4)4 · 4H2OMon. 2/m : P21/b
7.EC.75Lussierite Na10[(UO2)(SO4)4](SO4)2 · 3(H2O)Mon. m : Bb
7.EC.80NavrotskyiteK2Na10(UO2)3(SO4)9 · 2H2OOrth. mmm(2/m2/m2/m) : Pbcm
7.EC.85Pseudomeisserite-(NH4)(NH4)2Na4[(UO2)2(SO4)5] · 4H2OMon. 2/m : P21/b
7.EC.90WetherilliteNa2Mg(UO2)2(SO4)4 · 18H2OMon. 2/m : P21/b

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 44.5530% 11,138,250 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 0.0000% 0 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Fluorescence of BeshtauiteHide

Fluoresces strongly yellow-green under both short- and long-wave UV irradiation.

Other InformationHide

Notes:
Slowly dissolves in H2O at room temperature.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BeshtauiteHide

References for BeshtauiteHide

Localities for BeshtauiteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Stavropol Krai
    • Lermontov
      • Beshtau Mountain
        • Mine no. 1
Pekov et al. (2013) +2 other references
USA
 
  • Utah
    • San Juan County
      • La Sal Mining District
Joe Marty Collection
      • Red Canyon Mining District
Hålenius et al. (2015) +1 other reference
 
and/or  
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