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Karenwebberite

A valid IMA mineral species
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About KarenwebberiteHide

Formula:
NaFe2+PO4
Colour:
Pale green
Lustre:
Vitreous, Greasy
Specific Gravity:
3.65 (Calculated)
Crystal System:
Orthorhombic
Name:
In honor of Karen Louise Webber, Assistant Professor Research at the Mineralogy, Petrology and Pegmatology Research Group, Department of Earth and Environmental Sciences, University of New Orleans, Louisiana, U.S.A. Her research "has focused on the cooling and crystallization dynamics of granitic pegmatites."
Dimorph of:
The Fe2+-equivalent of natrophilite; Na-equivalent of triphylite.


Unique IdentifiersHide

Mindat ID:
42362
Long-form identifier:
mindat:1:1:42362:3

IMA Classification of KarenwebberiteHide

Approved
IMA Formula:
NaFe2+(PO4)
Approval year:
2011
First published:
2013

Classification of KarenwebberiteHide

8.AB.10

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
B : With medium-sized cations
38.1.1.4

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
1 : ABXO4

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
KwbIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KarenwebberiteHide

Vitreous, Greasy
Colour:
Pale green
Comment:
Lamellae are translucent (pale green) to opaque (dark green).
Streak:
Very pale grayish-green
Tenacity:
Brittle
Cleavage:
Perfect
In thin section it displays a perfect cleavage along {001}.
Fracture:
Irregular/Uneven
Density:
3.65 g/cm3 (Calculated)

Optical Data of KarenwebberiteHide

Type:
Biaxial (+)
RI values:
nα = 1.701(2) nβ = 1.708(2) nγ = 1.717(2)
2V:
Measured: 87° , Calculated: 41°
Max. Birefringence:
δ = 0.016
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Pleochroism:
Visible
Comments:
Moderate with X = dark gray, Y = brown, and Z = yellow

Chemistry of KarenwebberiteHide

Mindat Formula:
NaFe2+PO4
Element Weights:
Element% weight
O36.821 %
Fe32.131 %
P17.821 %
Na13.227 %

Calculated from ideal end-member formula.

Crystallography of KarenwebberiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pnma
Cell Parameters:
a = 4.882(1) Å, b = 10.387(2) Å, c = 6.091(1) Å
Ratio:
a:b:c = 0.47 : 1 : 0.586
Unit Cell V:
308.9 ų
Z:
4
Morphology:
Forms thin exsolution lamellae (< 0.1 x 7 mm) in graftonite.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0019819KarenwebberiteVignola P, Hatert F, Fransolet A M, Mendenbach O, Diella V, Ando S (2013) Karenwebberite, Na(Fe2+,Mn2+)PO4, a new member of the triphylite group from the Malpensata pegmatite, Lecco Province, Italy American Mineralogist 98 767-7722013the Malpensata pegmatite, Lecco Province, Italy0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.867 Å(97)
4.519 Å(77)
3.702 Å(46)
3.609 Å(82)
2.880 Å(75)
2.552 Å(100)
2.469 Å(96)
1.817 Å(42)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites

Type Occurrence of KarenwebberiteHide

General Appearance of Type Material:
Late-magmatic-stage exsolution lamellae up to 100 μm thick in graftonite.
Place of Conservation of Type Material:
Laboratory of Mineralogy, University of Liege, Belgium, cat. no. 20385
Geological Setting of Type Material:
Pegmatite dyke
Associated Minerals at Type Locality:

Synonyms of KarenwebberiteHide

Other Language Names for KarenwebberiteHide

Relationship of Karenwebberite to other SpeciesHide

Other Members of Triphylite Group:
HeterositeFe3+(PO4)Orth. mmm(2/m2/m2/m) : Pmna
LithiophiliteLiMn2+PO4Orth. mmm(2/m2/m2/m) : Pmna
NatrophiliteNaMn2+PO4Orth. mmm(2/m2/m2/m) : Pmna
PurpuriteMn3+(PO4)Orth. mmm(2/m2/m2/m) : Pmna
SimferiteLiMg(PO4)Orth.
TriphyliteLiFe2+PO4Orth. mmm(2/m2/m2/m) : Pmna

Common AssociatesHide

Associations Based on Photo Data:
2 photos of Karenwebberite associated with GraftoniteFe2+Fe2+2(PO4)2
1 photo of Karenwebberite associated with VivianiteFe2+Fe2+2(PO4)2 · 8H2O

Related Minerals - Strunz-mindat GroupingHide

8.AB.KryzaiteNa4(MgCr)(PO4)3Trig. 3m(32/m) : R3c
8.AB.NiasiteNi2+4.5(AsO4)3Tet. 42m : I42d
8.AB.JohanngeorgenstadtiteNi2+4.5(AsO4)3Mon. 2/m : B2/b
8.AB.RodolicoiteFe3+PO4Trig. 32 : P3121
8.AB.KarwowskiiteCa9Mg(Fe2+0.50.5)(PO4)7Trig. 3m : R3c
8.AB.OlseniteKFe4(PO4)3Orth. mmm(2/m2/m2/m) : Pnnm
8.AB.BorisenkoiteCu3[(V,As)O4]2Mon. 2/m : P21/b
8.AB.05FarringtoniteMg3(PO4)2Mon. 2/m
8.AB.10NatrophiliteNaMn2+PO4Orth. mmm(2/m2/m2/m) : Pmna
8.AB.10'Sicklerite'Li1-x(Mn3+xMn2+1-x)PO4Orth. mmm(2/m2/m2/m)
8.AB.10SimferiteLiMg(PO4)Orth.
8.AB.10HeterositeFe3+(PO4)Orth. mmm(2/m2/m2/m) : Pmna
8.AB.10LithiophiliteLiMn2+PO4Orth. mmm(2/m2/m2/m) : Pmna
8.AB.10TriphyliteLiFe2+PO4Orth. mmm(2/m2/m2/m) : Pmna
8.AB.10'Ferrisicklerite'Li1-x(Fe3+xFe2+1-x)PO4Orth. mmm(2/m2/m2/m) : Pmna
8.AB.10PurpuriteMn3+(PO4)Orth. mmm(2/m2/m2/m) : Pmna
8.AB.15ZavalíaiteMn2+3(PO4)2Mon. 2/m : P21/b
8.AB.15ChopiniteMg3(PO4)2Mon. 2/m : P21/b
8.AB.15SarcopsideFe2+3(PO4)2Mon. 2/m : P21/b
8.AB.20BeusiteMn2+Mn2+2 (PO4)2Mon. 2/m : P21/b
8.AB.20Graftonite-(Ca)CaFe2+2(PO4)2Mon. 2/m : P21/b
8.AB.20Graftonite-(Mn)MnFe2+2(PO4)2Mon. 2/m : P21/b
8.AB.20GraftoniteFe2+Fe2+2(PO4)2Mon. 2/m : P21/b
8.AB.20Beusite-(Ca)CaMn2+2(PO4)2Mon. 2/m : P21/b
8.AB.25XanthiositeNi3(AsO4)2Mon. 2/m : P21/b
8.AB.30LammeriteCu3(AsO4)2Mon. 2/m : P21/b
8.AB.30ParalammeriteCu3(AsO4)2Mon. 2/m : P21/b
8.AB.35McbirneyiteCu3(VO4)2Tric. 1 : P1
8.AB.35PseudolyonsiteCu3(VO4)2Mon. 2/m : P21/b
8.AB.35StranskiiteZn2Cu(AsO4)2Tric. 1 : P1
8.AB.40MichalskiiteFe3+1.33Cu2+2(MgFe3+)2(VO4)6Orth. mmm(2/m2/m2/m)
8.AB.40LyonsiteCu3Fe4(VO4)6Orth. mmm(2/m2/m2/m)

Fluorescence of KarenwebberiteHide

Non-fluorescent either under short-wave or long-wave ultraviolet light

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KarenwebberiteHide

References for KarenwebberiteHide

Localities for KarenwebberiteHide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Africa
 
  • Sahara Desert
V. V. Sharygin (2016)
Italy (TL)
 
  • Lombardy
    • Lecco Province
      • Colico
        • Piona Peninsula
Williams et al. (2011) +1 other reference
 
and/or  
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