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Millosevichite

A valid IMA mineral species - grandfathered
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About MillosevichiteHide

08905970017271925311385.jpg
Federico Millosevich
Formula:
Al2(SO4)3
Colour:
Red, violet-blue; becoming grey with hydration
Lustre:
Vitreous
Hardness:
Crystal System:
Trigonal
Name:
Named in 1913 by Ugo Panichi in honor of Federico Millosevich (10 January 1875, Venice – 9 November 1942, Rome, Italy), mineralogist, University of Rome.
Compare also sulfalumite. The Al analogue of mikasaite. Structurally related to koryakite.

The hydrated counterparts of millosevichite include UM1976-22-SO:AlFeH, Unnamed (Al Sulphate-Hydrate), 'meta-alunogen', and alunogen.


Unique IdentifiersHide

Mindat ID:
2713
Long-form identifier:
mindat:1:1:2713:3

IMA Classification of MillosevichiteHide

Classification of MillosevichiteHide

7.AB.05

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
A : Sulfates (selenates, etc.) without additional anions, without H2O
B : With medium-sized cations
28.4.5.1

28 : ANHYDROUS ACID AND NORMAL SULFATES
4 : Miscellaneous
25.11.24

25 : Sulphates
11 : Sulphates of Fe and other metals

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MsvIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MillosevichiteHide

Vitreous
Colour:
Red, violet-blue; becoming grey with hydration
Comment:
The color fades if the mineral absorbs moisture from the air. Panichi (1913) gives purple, fading to light gray. Srebrodol'skii (1974) give cherry-red, fading to clear red to brick-red.
Streak:
Red
Hardness:
1½ on Mohs scale

Optical Data of MillosevichiteHide

Type:
Uniaxial (+)
RI values:
nω = 1.5 nε = 1.515
Max. Birefringence:
δ = 0.015
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (negative)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Comments:
Optically isotropic with n = 1.573

Chemistry of MillosevichiteHide

Mindat Formula:
Al2(SO4)3
Element Weights:
Element% weight
O56.114 %
S28.115 %
Al15.772 %

Calculated from ideal end-member formula.
O
S
Al

Crystallography of MillosevichiteHide

Crystal System:
Trigonal
Class (H-M):
3 - Rhombohedral
Space Group:
R3
Cell Parameters:
a = 8.055 Å, c = 21.191 Å
Ratio:
a:c = 1 : 2.631
Unit Cell V:
1,190.73 ų (Calculated from Unit Cell)
Z:
6
Morphology:
Granular masses exhibiting small, clear crystals on their surfaces.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0011035MillosevichiteDahmen T, Gruehn R (1993) Beitrage zum thermischen verhalten von sulfaten. IX. Einkristallstrukturverfeinerung der metall(III)-sulfate Cr2(SO4)3 und Al2(SO4)3 Zeitschrift fur Kristallographie 204 57-651993synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.50 Å(100)
5.81 Å(50)
2.656 Å(40)
4.23 Å(30)
2.91 Å(30)
2.357 Å(20)
2.220 Å(20)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
45a : [Sulfates, arsenates, selenates, antimonates]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
50 : Coal and/or oil shale minerals<0.36
Stage 10b: Anthropogenic minerals<10 Ka
54 : Coal and other mine fire minerals (see also #51 and #56)
Geological Setting:
High temperature fumaroles; burning coal.

Type Occurrence of MillosevichiteHide

Synonyms of MillosevichiteHide

Other Language Names for MillosevichiteHide

Common AssociatesHide

Associations Based on Photo Data:
4 photos of Millosevichite associated with VoltaiteK2Fe2+5Fe3+3Al(SO4)12 · 18H2O
4 photos of Millosevichite associated with Godovikovite(NH4)Al(SO4)2
1 photo of Millosevichite associated with PickeringiteMgAl2(SO4)4 · 22H2O

Related Minerals - Strunz-mindat GroupingHide

7.AB.DravertiteCuMg(SO4)2Mon. 2/m
7.AB.AndymcdonalditeFe2TeO6Tet. 4/mmm(4/m2/m2/m) : P42/mnm
7.AB.DagenaisiteZn3Te6+O6Mon. 2/m : B2/b
7.AB.05MikasaiteFe2(SO4)3Trig. 3 : R3
7.AB.05KoryakiteNaKMg2Al2(SO4)6Trig. 3 : R3
7.AB.10ZinkositeZnSO4Orth. mmm(2/m2/m2/m) : Pnma
7.AB.10ChalcocyaniteCuSO4Orth. mmm(2/m2/m2/m)
7.AB.15HermannjahniteCuZn(SO4)2Mon. 2/m
7.AB.25OttoitePb2TeO5Mon. 2/m : B2/b
7.AB.55McalpineiteCu3(Te6+O6)Iso. m3(2/m3) : Ia3

Other InformationHide

Thermal Behaviour:
Slight change at 95C (hygroscopic water), large endothermic change at 850C (decomposition of sulfate)
Notes:
Hygroscopic and easily altered.
Insoluble in water, dissolved by acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MillosevichiteHide

References for MillosevichiteHide

Reference List:

Localities for MillosevichiteHide

Showing 27 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Bulgaria
 
  • Blagoevgrad Province
    • Simitli Municipality
      • Brezhani
Elena Shcherbakova (2010)
Cape Verde
 
  • Sotavento Islands
    • Fogo Island
Silva et al. (2019)
China
 
  • Inner Mongolia
    • Wuhai (Wuhai Prefecture)
      • Wuda District
        • Wuda Coal mining area
Stracher et al. (2005)
Czech Republic
 
  • Central Bohemian Region
Žáček et al. (1995)
      • Libušin
Hyrsl J. +2 other references
  • Hradec Králové Region
    • Trutnov District
      • Radvanice
Sejkora et al. (2001) +1 other reference
  • Moravian-Silesian Region
    • Ostrava-City District
      • Ostrava
        • Heřmanice
Matýsek et al. (2022)
France
 
  • Provence-Alpes-Côte d'Azur
    • Hautes-Alpes
      • Gap
        • La Chapelle-en-Valgaudemar
Bourgoin et al. (2011)
Germany
 
  • North Rhine-Westphalia
    • Cologne
      • Aachen
        • Alsdorf
Witzke et al. (2015)
Košek (2018) +1 other reference
  • Thuringia
    • Greiz District
      • Kauern
Witzke et al. (1998)
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Plaka
          • Plaka Mines
Schnorrer (1995) +1 other reference
Rieck (n.d.)
  • Eastern Macedonia and Thrace
    • Rhodope
      • Maroneia-Sapes
Voudouris (2011)
Hungary
 
  • Baranya County
    • Pécs District
Koller G.Own found.
  • Borsod-Abaúj-Zemplén County
    • Miskolc District
      • Miskolc
Szakáll et al. (1997)
Iran
 
  • Kerman Province
    • Sirjan County
      • Pariz
Khorasanipour (2015)
Italy
 
  • Sicily
    • Metropolitan City of Messina
      • Eolie Islands (Aeolian Islands)
        • Lipari
          • Vulcano Island
            • Porto Levante
              • Faraglioni di Levante
PANICHI U. (1913)
Panichi (1913)
  • Tuscany
    • Siena Province
      • Chiusdino
www.mindat.org (n.d.) +1 other reference
Poland
 
  • Silesian Voivodeship
    • Rybnik County
      • Gmina Czerwionka-Leszczyny
Parafiniuk et al. (2009)
    • Wodzisław County
      • Radlin
Kruszewski (2012)
    • Zabrze
Parafiniuk et al. (2009)
Russia
 
  • Kamchatka Krai
    • Yelizovsky District
      • Mutnovskoe
www.kscnet.ru (2019)
Slovakia
 
  • Banská Bystrica Region
    • Detva District
      • Detva
Juraj ŽItňan (2011)
USA
 
  • California
    • Shasta County
      • Klamath Mountains
Livingston et al. (2005, December)
  • Pennsylvania
    • Northumberland County
rruff.geo.arizona.edu (n.d.)
 
and/or  
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