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Khanneshite

A valid IMA mineral species
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About KhanneshiteHide

Formula:
(Na,Ca)3(Ba,Sr,Ce,Ca)3(CO3)5
Colour:
Light yellow, almost colourless
Hardness:
3 - 4
Specific Gravity:
3.8 - 3.9
Crystal System:
Hexagonal
Name:
After the type locality at Khanneshin, Afghanistan.
This page provides mineralogical data about Khanneshite.


Unique IdentifiersHide

Mindat ID:
2195
Long-form identifier:
mindat:1:1:2195:7

IMA Classification of KhanneshiteHide

Classification of KhanneshiteHide

5.AC.30

5 : CARBONATES (NITRATES)
A : Carbonates without additional anions, without H2O
C : Alkali and alkali-earth carbonates
14.4.4.2

14 : ANHYDROUS NORMAL CARBONATES
4 : Miscellaneous
11.8.15

11 : Carbonates
8 : Carbonates of the rare earths

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
KhaIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KhanneshiteHide

Transparency:
Transparent
Colour:
Light yellow, almost colourless
Hardness:
3 - 4 on Mohs scale
Tenacity:
Brittle
Cleavage:
Poor/Indistinct
One, parallel elongation, indistinct.
Parting:
Transverse parting.
Density:
3.8 - 3.9 g/cm3 (Measured)    3.94 g/cm3 (Calculated)

Optical Data of KhanneshiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.62 - 1.623 nε = 1.609 - 1.61
Max. Birefringence:
δ = 0.011 - 0.013
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of KhanneshiteHide

Mindat Formula:
(Na,Ca)3(Ba,Sr,Ce,Ca)3(CO3)5
Element Weights:
Element% weight
Ba52.751 %
O30.729 %
Na8.831 %
C7.689 %

Calculated from ideal end-member formula.
Ba
O
Na
C

Crystallography of KhanneshiteHide

Crystal System:
Hexagonal
Class (H-M):
6mm - Dihexagonal Pyramidal
Space Group:
P63mc
Cell Parameters:
a = 10.5790(1) Å, c = 6.5446(1) Å
Ratio:
a:c = 1 : 0.619
Unit Cell V:
634.31 ų
Z:
3
Morphology:
Elongated hexagonal crystals, to 1 cm, in radially fibrous or fine-grained aggregates
Comment:
Cell parameters from Belovitskaya et al. (2002).

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012375KhanneshiteBelovitskaya Y V, Pekov I V, Gobechiya E R, Kabalov Y K, Schneider J (2002) Determination of the crystal structure of khanneshite by the Rietveld method Crystallography Reports 47 39-422002Khibiny massif, Kola Peninsula, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.66 Å(100)
3.08 Å(62)
2.19 Å(55)
3.78 Å(50)
2.09 Å(42)
1.691 Å(40)
5.34 Å(30)
Comments:
Khanneshin complex, Afghanistan. Data from the type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
36 : Carbonatites, kimberlites, and related igneous rocks

Type Occurrence of KhanneshiteHide

General Appearance of Type Material:
Elongated prismatic crystals 5-10 mm long and 2-3 mm in diameter. Commonly altered and replaced by baryte.
Place of Conservation of Type Material:
Mining Institute, St. Petersburg; A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia.
Geological Setting of Type Material:
Disseminated in fine-grained carbonatite.
Associated Minerals at Type Locality:

Synonyms of KhanneshiteHide

Other Language Names for KhanneshiteHide

Relationship of Khanneshite to other SpeciesHide

Other Members of Burbankite Group:
Burbankite(Na,Ca)3(Sr,Ba,Ce)3(CO3)5Hex. 6mm : P63mc
CalcioburbankiteNa3(Ca,REE,Sr)3(CO3)5Hex. 6mm : P63mc
Lishiite(Ca2◻)Sr3(CO3)5Hex. 6mm : P63mc
Petersenite-(Ce)Na4(Ce,La,Nd)2(CO3)5Mon. 2 : P21
Rémondite-(Ce)Na3(Ce,Ca,Na)3(CO3)5Mon. 2 : P21
Rémondite-(La)Na3(La,Ca,Na)3(CO3)5Mon. 2 : P21
SanromániteNa2CaPb3[CO3]5Hex. 6mm : P63mc

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Khanneshite associated with PectoliteNaCa2Si3O8(OH)

Related Minerals - Strunz-mindat GroupingHide

5.AC.05EiteliteNa2Mg(CO3)2Trig. 3 : R3
5.AC.10ZemkoriteNa2Ca(CO3)2Hex.
5.AC.10NyerereiteNa2Ca(CO3)2Orth. mmm(2/m2/m2/m) : Pbca
5.AC.15BütschliiteK2Ca(CO3)2Trig. 3m(32/m) : R3m
5.AC.20FairchilditeK2Ca(CO3)2Hex. 6/mmm(6/m2/m2/m) : P63/mmc
5.AC.25ShortiteNa2Ca2(CO3)3Orth. mm2 : Amm2
5.AC.30Burbankite(Na,Ca)3(Sr,Ba,Ce)3(CO3)5Hex. 6mm : P63mc
5.AC.30CalcioburbankiteNa3(Ca,REE,Sr)3(CO3)5Hex. 6mm : P63mc
5.AC.30SanromániteNa2CaPb3[CO3]5Hex. 6mm : P63mc
5.AC.30Lishiite(Ca2◻)Sr3(CO3)5Hex. 6mm : P63mc

Other InformationHide

Thermal Behaviour:
DTA shows endothermic peaks at 590° and 645°, and a small one at 360° associated with loss of water.
Notes:
Readily dissolved by HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KhanneshiteHide

References for KhanneshiteHide

Localities for KhanneshiteHide

Showing 11 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Afghanistan
 
  • Helmand
    • Reg District
Asadzadeh et al. (2025)
Yeremenko et al. (1982) +2 other references
Russia
 
  • Krasnoyarsk Krai
    • Boguchansky District
      • Chadobets alkaline complex
Sharygin +11 other references
  • Murmansk Oblast
Belovitskaya et al. (2004)
Pekov et al. (1998) +1 other reference
Arzamastsev et al. (2006)
PEKOV et al. (2013)
    • Kovdorsky District
Belovitskaya et al. (2004)
maurice.strahlen.org (2003)
  • Republic of Karelia
    • Loukhsky District
Bea et al. (2001)
  • Tuva
Sharygin et al. (2017)
 
and/or  
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