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Turkestanite

A valid IMA mineral species
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About TurkestaniteHide

Formula:
(K,◻)(Ca,Na)2ThSi8O20 · nH2O
Colour:
Brown, apple-green
Lustre:
Vitreous, Dull
Hardness:
5½ - 6
Specific Gravity:
3.36
Crystal System:
Tetragonal
Member of:
Name:
Named after the discovery locality, along the Turkestan Ridge, Dara-i-Pioz massif, Tien-Shan Mountains, Tadjikistan.
Steacyite Group. The thorium analogue of arapovite.


Unique IdentifiersHide

Mindat ID:
7345
Long-form identifier:
mindat:1:1:7345:1

IMA Classification of TurkestaniteHide

Classification of TurkestaniteHide

9.CH.10

9 : SILICATES (Germanates)
C : Cyclosilicates
H : [Si4O12]8- 4-membered double rings

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
TktIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TurkestaniteHide

Vitreous, Dull
Transparency:
Translucent
Colour:
Brown, apple-green
Hardness:
5½ - 6 on Mohs scale
Tenacity:
Brittle
Density:
3.36(2) g/cm3 (Measured)    3.39 g/cm3 (Calculated)

Optical Data of TurkestaniteHide

Type:
Uniaxial (-)
RI values:
nω = 1.611 nε = 1.606
Max. Birefringence:
δ = 0.005
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of TurkestaniteHide

Mindat Formula:
(K,◻)(Ca,Na)2ThSi8O20 · nH2O
Element Weights:
Element% weight
O36.761 %
Th25.388 %
Si24.583 %
Ca8.770 %
K4.278 %
H0.221 %

Calculated from ideal end-member formula.
O
Th
Si
Ca
K
H

Crystallography of TurkestaniteHide

Crystal System:
Tetragonal
Class (H-M):
4/mmm(4/m2/m2/m) - Ditetragonal Dipyramidal
Space Group:
P4/mcc
Cell Parameters:
a = 7.592 Å, c = 14.824 Å
Ratio:
a:c = 1 : 1.953
Unit Cell V:
854.43 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Prisms. Forms observed include {100}, {001}, and rarely {101}.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012357TurkestaniteKabalov Yu K, Sokolova E V, Pautov L A, Schneider J (1998) Crystal structure of a new mineral turkestanite: a calcium analogue of steacyite Crystallography Reports 43 584-5881998Dzhelisu massif, Alayskiy range, Tien Shan, Kyrgyzstan0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.40 Å(100)
5.31 Å(70)
3.33 Å(65)
2.654 Å(59)
5.36 Å(40)
2.175 Å(25)
7.59 Å(23)
Comments:
Dara-iPioz massif, Tajikistan. Data from the type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of TurkestaniteHide

General Appearance of Type Material:
At Dara-i-Pioz, occurs as prisms, 0.5 to 5 mm across, showing {100}, {001}, and rarely {101}. At the Jelisu massif, the mineral forms deformed {100} prisms, 2 to 50 mm across, rarely with {101} pyramids.
Place of Conservation of Type Material:
Museum of the Ilmen Reserve, Miass, Russia.
A. E. Fersman Mineralogical Museum, Moscow, Russia.
Geological Setting of Type Material:
Albitized Upper Carboniferous sandy shales in the contact aureole of the Jelisu massif (a massif consisting largely of albitized nepheline syenites). Also found in a boulder of microcline, pectolite, quartz, aegirine, and calcite near the alkaline to subalkaline intrusions of the Dara-i-Pioz massif.
Associated Minerals at Type Locality:

Synonyms of TurkestaniteHide

Other Language Names for TurkestaniteHide

Simplified Chinese:突厥斯坦石
Spanish:Turkestanita
Traditional Chinese:突厥斯坦石

Relationship of Turkestanite to other SpeciesHide

Member of:
Other Members of Steacyite Group:
Arapovite(K1-xx)(Ca,Na)2U4+Si8O20 (x ~ 0.5)Tet. 4/mmm(4/m2/m2/m) : P4/mcc
Iraqite-(La)KCa2(La,Ce,Th)Si8O20Tet. 4/mmm(4/m2/m2/m) : P4/mcc
SteacyiteK0.3(Na,Ca)2ThSi8O20Tet. 4/mmm(4/m2/m2/m) : P4/mcc

Common AssociatesHide

Associations Based on Photo Data:
6 photos of Turkestanite associated with AegirineNaFe3+Si2O6
4 photos of Turkestanite associated with QuartzSiO2
3 photos of Turkestanite associated with EudialyteNa15Ca6Fe3Zr3Si(Si25O73)(O,OH,H2O)3(Cl,OH)2
2 photos of Turkestanite associated with SteacyiteK0.3(Na,Ca)2ThSi8O20
1 photo of Turkestanite associated with AlbiteNa(AlSi3O8)
1 photo of Turkestanite associated with CalciteCaCO3
1 photo of Turkestanite associated with FluoriteCaF2
1 photo of Turkestanite associated with Arapovite(K1-xx)(Ca,Na)2U4+Si8O20 (x ~ 0.5)

Related Minerals - Strunz-mindat GroupingHide

9.CH.05Khvorovite(Pb,Ba,K)4Ca2[Si8B2(Si,B)2O28]FTric.
9.CH.05Guastoniite-(Y)Pb4(YCa)(Si8B4O28)FTric. 1 : P1
9.CH.05Kapitsaite-(Y)(Ba,K,Pb)4(Y,Ca)2Si8(B,Si)4O28FTric. 1 : P1
9.CH.05Hyalotekite(Ba,Pb,K)4(Ca,Y)2(B,Be)2(Si,B)2Si8O28(F,Cl)Tric. 1 : P1
9.CH.05ItsiiteBa4Ca2[Si8B4O28]◻Tet. 42m : I42m
9.CH.10Arapovite(K1-xx)(Ca,Na)2U4+Si8O20 (x ~ 0.5)Tet. 4/mmm(4/m2/m2/m) : P4/mcc
9.CH.10SteacyiteK0.3(Na,Ca)2ThSi8O20Tet. 4/mmm(4/m2/m2/m) : P4/mcc
9.CH.10Iraqite-(La)KCa2(La,Ce,Th)Si8O20Tet. 4/mmm(4/m2/m2/m) : P4/mcc

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 25.3877% 1,015,508 α, β, γ
Potassium (K) 4.2778% 1,326 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

IR Spectrum:
The infrared spectrum has strong absorption bands at 449, 591, 1040, and 1097 cm-1, typical for ring silicates, and also a broad band at about 3460 cm-1 attributable to H2O.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for TurkestaniteHide

References for TurkestaniteHide

Reference List:

Localities for TurkestaniteHide

Showing 15 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Brazil
 
  • Paraná
    • Tijucas do Sul
      • Morro Redondo complex
Vilalva et al. (2010) +1 other reference
Canada
 
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
HORVÁTH et al. (2012)
Germany
 
  • Rhineland-Palatinate
    • Mayen-Koblenz
      • Mendig
        • Mendig
in the collection of Christof Schäfer
Greenland
 
  • Kujalleq
    • Igaliku
      • Narsaarsuk Plateau
Structural and chemical analysis by Henrik Friis (unpublished)
Sørensen (2001) +1 other reference
Petersen et al. (1999)
Petersen et al. (1999)
Japan
 
  • Ehime Prefecture
    • Ochi District
      • Iwagi Island
Imaoka et al. (2021) +1 other reference
Kyrgyzstan
 
  • Batken Region
    • Batken District
Pautov et al. (2013)
    • Sokh Valley
      • Upper Khodzhaachkan River
Pautov et al. (1997) +3 other references
Madagascar
 
  • Diana
    • Ambanja District
      • Antsirabe
Estrade (2014)
Estrade et al. (2014)
Namibia
 
  • Khomas Region
    • Windhoek Rural
      • Aris
Uwe Kolitsch (single-crystal X-ray diffraction) +1 other reference
Portugal
 
  • Azores
    • São Miguel
Analysed by Pedro Alves +1 other reference
Tajikistan (TL)
 
  • Districts of Republican Subordination
Pautov et al. (1997) +6 other references
 
and/or  
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