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Barrerite

A valid IMA mineral species
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About BarreriteHide

Formula:
Na2(Si7Al2)O18 · 6H2O
Usually not pure, but containing also minor K and Ca. Formula also given as (Na,K,Ca0.5)2[Al2Si7O18] · 7H2O.
Colour:
White, Pink
Lustre:
Vitreous
Hardness:
3 - 4
Specific Gravity:
2.3
Crystal System:
Orthorhombic
Name:
Named for Richard Maling Barrer (1910-1996), New Zealand-born British teacher and student of the chemistry of zeolites.

Unique IdentifiersHide

Mindat ID:
536
Long-form identifier:
mindat:1:1:536:6

Similar NamesHide

BarariteA valid IMA mineral species - grandfathered(NH4)2[SiF6]

IMA Classification of BarreriteHide

Classification of BarreriteHide

9.GE.15

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
E : Chains of T10O20 Tetrahedra
Dana 7th ed.:
77.1.4.5
77.1.4.5

77 : TECTOSILICATES Zeolites
1 : Zeolite group - True zeolites
16.10.14

16 : Silicates Containing Aluminum and other Metals
10 : Aluminosilicates of Ca and alkalis

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
BreIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
BrrThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of BarreriteHide

Vitreous
Transparency:
Transparent, Translucent
Colour:
White, Pink
Streak:
White
Hardness:
3 - 4 on Mohs scale
Cleavage:
Perfect
on {010}
Density:
2.3 g/cm3 (Measured)    2.08 g/cm3 (Calculated)

Optical Data of BarreriteHide

Type:
Biaxial (-)
RI values:
nα = 1.4791 nβ = 1.4851 nγ = 1.4891
2V:
Measured: 78° , Calculated: 78°
Max. Birefringence:
δ = 0.010
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (negative)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
none

Chemistry of BarreriteHide

Mindat Formula:
Na2(Si7Al2)O18 · 6H2O

Usually not pure, but containing also minor K and Ca. Formula also given as (Na,K,Ca0.5)2[Al2Si7O18] · 7H2O.
Element Weights:
Element% weight
O55.439 %
Si28.385 %
Al7.791 %
Na6.639 %
H1.746 %

Calculated from ideal end-member formula.
O
Si
Al
Na
H
Common Impurities:
Ca,K,Fe,Mn,Mg,Sr,Ba

Crystallography of BarreriteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Cell Parameters:
a = 13.634 Å, b = 18.206 Å, c = 17.845 Å
Ratio:
a:b:c = 0.749 : 1 : 0.98
Unit Cell V:
4,429.50 ų (Calculated from Unit Cell)
Z:
8
Comment:
Non-standard space-group setting Amma

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014405BarreriteSacerdoti M, Sani A, Vezzalini G (1999) Structural refinement of two barrerites from Alaska Microporous and Mesoporous Materials 30 103-1091999Kuiu Island, Alaska, USA0293
0014404BarreriteSacerdoti M, Sani A, Vezzalini G (1999) Structural refinement of two barrerites from Alaska Microporous and Mesoporous Materials 30 103-1091999Kuiu Island, Alaska, USA0293
0004773BarreriteOri S, Mazzucato E, Vezzalini G (2009) Dehydration dynamics of barrerite: An in situ synchrotron XRPD study American Mineralogist 94 64-732009Kuiu Island, Alaska0339
0004774BarreriteOri S, Mazzucato E, Vezzalini G (2009) Dehydration dynamics of barrerite: An in situ synchrotron XRPD study American Mineralogist 94 64-732009Kuiu Island, Alaska0482
0004775BarreriteOri S, Mazzucato E, Vezzalini G (2009) Dehydration dynamics of barrerite: An in situ synchrotron XRPD study American Mineralogist 94 64-732009Kuiu Island, Alaska0637
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Loading XRD data...
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacingIntensity
9.10 Å(> 100)
4.054 Å(100)
3.028 Å(80)
3.004 Å(25)
4.659 Å(20)
2.773 Å(20)
1.8192 Å(17)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
10 : Basalt-hosted zeolite minerals

Type Occurrence of BarreriteHide

General Appearance of Type Material:
As well-formed, laminar crystals, to 5 mm
Place of Conservation of Type Material:
University of Modena, Modena, Italy; National Museum of Natural History, Washington, D.C., USA, 128521.
Geological Setting of Type Material:
On the walls of large fractures in deeply weathered andesitic and rhyolitic lavas
Associated Minerals at Type Locality:

Other Language Names for BarreriteHide

Dutch:Barreriet
German:Barrerit
Simplified Chinese:板沸石
Spanish:Barrerita

Relationship of Barrerite to other SpeciesHide

Other Members of Stilbite Subgroup:
StelleriteCa4(Si28Al8)O72 · 28H2OOrth. mmm(2/m2/m2/m) : Fmmm
Stilbite-CaNaCa4(Si27Al9)O72 · 28H2OMon. 2/m : B2/m
Stilbite-NaNa9(Si27Al9)O72 · 28H2OMon. 2/m : B2/m

Common AssociatesHide

Associations Based on Photo Data:
17 photos of Barrerite associated with QuartzSiO2
9 photos of Barrerite associated with CalciteCaCO3
7 photos of Barrerite associated with PyriteFeS2
2 photos of Barrerite associated with LaumontiteCaAl2Si4O12 · 4H2O
1 photo of Barrerite associated with Stilbite-NaNa9(Si27Al9)O72 · 28H2O
1 photo of Barrerite associated with Heulandite-Ca(Ca,Na)5(Si27Al9)O72 · 26H2O
1 photo of Barrerite associated with Stilbite-CaNaCa4(Si27Al9)O72 · 28H2O

Related Minerals - Strunz-mindat GroupingHide

9.GE.05Heulandite-Ca(Ca,Na)5(Si27Al9)O72 · 26H2OMon. 2/m : B2/m
9.GE.05Heulandite-K(K,Ca,Na)5(Si27Al9)O72 · 26H2OMon. 2/m : B2/m
9.GE.05Heulandite-Na(Na,Ca,K)6(Si,Al)36O72 · 22H2OMon. m : Bm
9.GE.05Heulandite-Sr(Sr,Na,Ca)5(Si27Al9)O72 · 24H2OMon. m : Bm
9.GE.05Heulandite-Ba(Ba,Ca,K)5(Si27Al9)O72 · 22H2OMon. 2/m : B2/m
9.GE.05Clinoptilolite-CaCa3(Si30Al6)O72 · 20H2OMon. 2/m
9.GE.05Clinoptilolite-KK6(Si30Al6)O72 · 20H2OMon. 2/m
9.GE.05Clinoptilolite-NaNa6(Si30Al6)O72 · 20H2OMon. 2/m : B2/m
9.GE.10Stilbite-CaNaCa4(Si27Al9)O72 · 28H2OMon. 2/m : B2/m
9.GE.10Stilbite-NaNa9(Si27Al9)O72 · 28H2OMon. 2/m : B2/m
9.GE.15StelleriteCa4(Si28Al8)O72 · 28H2OOrth. mmm(2/m2/m2/m) : Fmmm
9.GE.20Brewsterite-BaBa(Al2Si6)O16 · 5H2OMon. 2/m : P21/m
9.GE.20Brewsterite-SrSr(Al2Si6)O16 · 5H2OMon. 2/m : P21/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BarreriteHide

References for BarreriteHide

Reference List:

Localities for BarreriteHide

Showing 32 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Antarctica
 
  • East Antarctica
    • Buckley Island quadrangle
Liu et al. (2015)
Argentina
 
  • Chubut Province
    • Futaleufú Department
R. S. Bowman and S. E. Delap (Eds.)
R. S. Bowman and S. E. Delap (Eds.)
  • Neuquén Province
    • Los Lagos Department
Vattuone et al. (2001)
Canada
 
  • British Columbia
    • Vancouver Island
      • Victoria Mining Division
Timpa et al. (2005)
  • Northwest Territories
    • Mackenzie Mountains
      • Tungsten (Cantung)
www.trinityminerals.com +1 other reference
  • Nova Scotia
    • Colchester Co.
Pe-Piper et al. (2002)
    • Cumberland Co.
Pe-Piper et al. (2002)
Pe-Piper et al. (2002)
      • Parrsboro
Pe-Piper et al. (2002)
      • West Bay
Pe-Piper et al. (2002)
    • Kings Co.
Pe-Piper (2000)
      • Ross Creek
Pe-Piper (2000)
Ethiopia
 
  • Afar Region
Gebregziabher (1998)
Italy
 
  • Sardinia
    • Metropolitan City of Cagliari
      • Pula
Passaglia et al. (1974) +7 other references
Passaglia et al. (1974) +7 other references
    • South Sardinia Province
Fernando Caboni et al. (2024)
Fernando Caboni et al. (2024)
Japan
 
  • Nagasaki Prefecture
    • Hirado City
Nishido et al. (2005)
Norway
 
  • Nordland
    • Vefsn
King et al. (1993) +1 other reference
Romania
 
  • Cluj County
    • Săndulești
      • Copăceni
Kristály et al. (2003) +1 other reference
Russia
 
  • Kamchatka Krai
    • Bystrinsky District
      • Central Kamchatka mining district
Okrugin et al. (2015)
        • Baranyevskoe ore field
Okrugin et al. (2015)
    • Yelizovsky District
Okrugin et al. (2015)
Okrugin et al. (2015)
Okrugin et al. (2015)
USA
 
  • Alaska
    • Petersburg Borough
June 1997 +3 other references
Di Renzo et al. (1997) +1 other reference
June 1997 +3 other references
Valange et al. (1996) +2 other references
  • Nevada
    • Pershing County
      • Seven Troughs Mining District
Castor et al. (2004)
  • Virginia
    • Culpeper County
      • Mitchell
Dietrich (1990)
 
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