Fluornatrocoulsellite
A valid IMA mineral species
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About Fluornatrocoulsellite
Formula:
CaNa3AlMg3F14
Colour:
Colorless
Lustre:
Vitreous
Hardness:
4½
Specific Gravity:
2.99
Crystal System:
Trigonal
Member of:
Name:
Originally named simply coulsellite in honor of Ruth Elise Coulsell (1912 – 2000), a foundation member and honorary life member of the Mineralogical Society of Victoria. Renamed to fluornatrocoulsellite by Atencio et al. (2017) according to the pyrochlore supergroup naming convention.
Originally named coulsellite, renamed fluornatrocoulsellite (IMA July 2016; Atencio et al., 2017).
A mineral in the Coulsellite Group of the Pyrochlore Supergroup.
Appears to be unique among published pyrochlore phases in having a 1:3 ordering of metal atoms Ca:Na in the A sites and Al:Mg in the B sites.
Related to hydrokenoralstonite.
Originally recognized as a Ca-bearing ralstonite-like mineral (UM199O-21-F:AlCaHMgNa) by Birch and Spring (1990). Subsequently fully characterized as a new species by Birch et al. (2009). The crystal structure was solved by Mumme et al. (2010).
A mineral in the Coulsellite Group of the Pyrochlore Supergroup.
Appears to be unique among published pyrochlore phases in having a 1:3 ordering of metal atoms Ca:Na in the A sites and Al:Mg in the B sites.
Related to hydrokenoralstonite.
Originally recognized as a Ca-bearing ralstonite-like mineral (UM199O-21-F:AlCaHMgNa) by Birch and Spring (1990). Subsequently fully characterized as a new species by Birch et al. (2009). The crystal structure was solved by Mumme et al. (2010).
Unique Identifiers
Mindat ID:
39766
Long-form identifier:
mindat:1:1:39766:5
IMA Classification of Fluornatrocoulsellite
Approved
IMA status notes:
Renamed by the IMA
IMA Formula:
(Na1.5Ca0.5)(Mg1.5Al0.5)F6F
Approval year:
2009
Approval history:
Renamed from coulsellite after being moved into the Pyrochlore Supergroup (IMA July 2016.)
Classification of Fluornatrocoulsellite
3.00.
3 : HALIDES
0 :
0 :
3 : HALIDES
0 :
0 :
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Fnc | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Fluornatrocoulsellite
Vitreous
Transparency:
Transparent, Translucent
Colour:
Colorless
Streak:
White
Hardness:
4½ on Mohs scale
Hardness Data:
Estimated
Tenacity:
Brittle
Cleavage:
None Observed
Parting:
None observed
Fracture:
Conchoidal
Density:
2.99 g/cm3 (Measured) 3.011 g/cm3 (Calculated)
Optical Data of Fluornatrocoulsellite
Type:
Uniaxial
Comments:
n(average) = 1.40. Pseudo-isotropic.
Chemistry of Fluornatrocoulsellite
Mindat Formula:
CaNa3AlMg3F14
Element Weights:
Chemical Analysis
wt%
| 1 | |
|---|---|
| Al | 5.93 % |
| Ca | 8.41 % |
| Mg | 14.9 % |
| Na | 14.2 % |
| F | 54.8 % |
| O | 1.81 % |
| P | 0.49 % |
| Total: | 100.54 % |
Empirical formulas:
| Sample ID | Empirical Formula |
|---|---|
| 1 | Ca0.98Na2.88Al1.03Mg2.86P0.07F13.47(OH)0.53 |
Sample references:
| ID | Locality | Reference | Notes |
|---|---|---|---|
| 1 | Mt Cleveland Mine, Luina, Heazlewood district, Waratah-Wynyard municipality, Tasmania, Australia | Electron microprobe |
Crystallography of Fluornatrocoulsellite
Crystal System:
Trigonal
Class (H-M):
3m(32/m) - Hexagonal Scalenohedral
Space Group:
R3m
Setting:
R3m
Cell Parameters:
a = 7.1756(1) Å
α = 59.867(1)°
α = 59.867(1)°
Unit Cell V:
260.46 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Pseudo-octahedral crystals, forming crusts.
Forms probably {00.1} and {12.1} for rhombohedral symmetry.
Forms probably {00.1} and {12.1} for rhombohedral symmetry.
Twinning:
Multiply twinned about threefold axes of the pseudocubic cell.
Comment:
Corresponding hexagonal unit-cell parameters are a = 7.1620(1) Å, c = 17.5972(3) Å.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0020643 | Fluornatrocoulsellite | Mumme W G, Grey I E, Birch W D, Pring A, Bougerol C, Wilson N C (2010) Coulsellite, CaNa3AlMg3F14, a rhombohedral pyrochlore with 1:3 ordering in both A and B sites, from the Cleveland mine, Tasmania, Australia American Mineralogist 95 736-740 | 2010 | Cleveland tin mine, Luina, western Tasmania | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 2.926 Å | (100) |
| 1.791 Å | (66) |
| 2.325 Å | (33) |
| 1.528 Å | (20) |
| 1.949 Å | (19) |
| 5.86 Å | (12) |
| 3.054 Å | (8) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Near-surface Processes | |
| 23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47) | |
| Stage 7: Great Oxidation Event | <2.4 |
| 45b : [Other oxidized fumarolic minerals] |
Type Occurrence of Fluornatrocoulsellite
General Appearance of Type Material:
Pseudo-octahedral crystals up to 2 mm across.
Place of Conservation of Type Material:
Museum Victoria, Melbourne, Victoria, Australia, number M41450.
Geological Setting of Type Material:
A tin-copper deposit within a complex of Early Cambrian sequence of altered mafic volcanic rocks and sediments.
Associated Minerals at Type Locality:
Synonyms of Fluornatrocoulsellite
Other Language Names for Fluornatrocoulsellite
Dutch:Fluornatrocoulselliet
German:Fluornatrocoulsellit
Relationship of Fluornatrocoulsellite to other Species
Member of:
Common Associates
Associations Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
| 3.00. | Paratacamite-(Mg) | Cu3(Mg,Cu)(OH)6Cl2 |
| 3.00. | Panichiite | (NH4)2SnCl6 |
Fluorescence of Fluornatrocoulsellite
Does not fluoresce under UV light.
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Fluornatrocoulsellite
mindat.org URL:
https://www.mindat.org/min-39766.html
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References for Fluornatrocoulsellite
Reference List:
Birch, W. D., Pring, A. (1990) A calcian ralstonite-like mineral from the Cleveland Mine, Tasmania, Australia. Mineralogical Magazine, 54 (377) 599-602 doi:10.1180/minmag.1990.054.377.11
Mumme, W. G., Grey, I. E., Birch, W. D., Pring, A., Bougerol, C., Wilson, N. C. (2010) Coulsellite, CaNa3AlMg3F14, a rhombohedral pyrochlore with 1:3 ordering in both A and B sites, from the Cleveland Mine, Tasmania, Australia. American Mineralogist, 95 (5) 736-740 doi:10.2138/am.2010.3360
Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2016) New minerals and nomenclature modifications approved in 2016, CNMNC Newsletter 32. Mineralogical Magazine, 80 (5) 915-922 doi:10.1180/minmag.2016.080.084
Localities for Fluornatrocoulsellite
Showing 6 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Australia (TL) | |
| Birch et al. (1990) +1 other reference |
Italy | |
| Demartin et al. (2014) |
| Demartin et al. (2014) +1 other reference |
| Demartin et al. (2014) +1 other reference | |
Russia | |
| Savel’eva et al. (2017) |
Spain | |
| Campeny et al. (2023) |
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The
Mt Cleveland Mine, Luina, Heazlewood district, Waratah-Wynyard municipality, Tasmania, Australia