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Tarapacáite

A valid IMA mineral species - grandfathered
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About TarapacáiteHide

01820840017271927006238.jpg
Coat of arms, Tarapacá, Chile
Formula:
K2(CrO4)
Colour:
Bright yellow, yellow-orange
Specific Gravity:
2.74
Crystal System:
Orthorhombic
Name:
Named after Tarapacá, Chile, a region that includes the discovery locality, Tocopilla Pampa.
Isostructural with:
Easily synthesised (compare lopezite).


Name EncodingHide

ASCII-7:
Tarapacaite

Unique IdentifiersHide

Mindat ID:
3891
Long-form identifier:
mindat:1:1:3891:7

IMA Classification of TarapacáiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
K2Cr6+O4
First published:
1878

Classification of TarapacáiteHide

7.FA.05

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
F : Chromates
A : Without additional anions
Dana 7th ed.:
35.1.1.1
35.1.1.1

35 : ANHYDROUS CHROMATES
1 : A2XO4
27.2.1

27 : Sulphites, Chromates, Molybdates and Tungstates
2 : Chromates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
TpcIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TarapacáiteHide

Transparency:
Transparent
Colour:
Bright yellow, yellow-orange
Cleavage:
Distinct/Good
On {001} and {010}, distinct.
Density:
2.74 g/cm3 (Measured)    2.735 g/cm3 (Calculated)
Comment:
Measured value on artificial material.

Optical Data of TarapacáiteHide

Type:
Biaxial (-)
RI values:
nα = 1.687 nβ = 1.722 nγ = 1.731
2V:
Measured: 52° , Calculated: 52°
Max. Birefringence:
δ = 0.044
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v weak
Optical Extinction:
X = c; Y = a; Z = b.

Chemistry of TarapacáiteHide

Mindat Formula:
K2(CrO4)
Element Weights:
Element% weight
K40.268 %
O32.956 %
Cr26.776 %

Calculated from ideal end-member formula.
K
O
Cr

Crystallography of TarapacáiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Cell Parameters:
a = 7.662(1) Å, b = 10.391(1) Å, c = 5.919(1) Å
Ratio:
a:b:c = 0.737 : 1 : 0.57
Unit Cell V:
471.25 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Crystals thick tabular {001}.
Twinning:
Twinning on {110} producing pseudo-hexagonal twins analogous to aragonite.
Comment:
Space group Pnam (synthetic).

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.078 Å(100)
2.988 Å(75)
2.960 Å(40)
2.479 Å(25)
2.286 Å(25)
2.599 Å(22)
2.570 Å(21)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
25 : Evaporites (prebiotic)
High-? alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])

Type Occurrence of TarapacáiteHide

Synonyms of TarapacáiteHide

Other Language Names for TarapacáiteHide

Related Minerals - Strunz-mindat GroupingHide

7.FA.10ChromatiteCaCr6+O4Tet. 4/mmm(4/m2/m2/m) : I41/amd
7.FA.15HashemiteBaCr6+O4Orth. mmm(2/m2/m2/m) : Pnma
7.FA.20CrocoitePbCr6+O4Mon. 2/m

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 40.2680% 12,483 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

Notes:
Readily soluble in water.
Health Risks:
Chromate minerals contain the carcinogenic and mutagenic chromate ion. Always wash hands after handling. Avoid inhaling dust when handling or breaking. Never lick or ingest. Do not pour chromate-containing solutions down the drain.

Internet Links for TarapacáiteHide

References for TarapacáiteHide

Reference List:

Localities for TarapacáiteHide

Showing 6 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Chile
 
  • Antofagasta
    • Antofagasta Province
    • Tocopilla Province
      • María Elena
Palache et al. (1951) +2 other references
Palache et al. (1951) +1 other reference
Anthony et al. (2003)
  • Tarapacá
    • Iquique Province
      • Iquique
Konnert et al. (1994) +1 other reference
Israel
 
  • Southern District
    • Beersheba Subdistrict
      • Tamar Regional Council
        • Hatrurim Basin
Sharygin et al. (2019)
 
and/or  
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