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Metaschoepite

A valid IMA mineral species - grandfathered

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Photos of Metaschoepite (18)Discuss Metaschoepite

Metaschoepite Gallery Search Photos of Metaschoepite

Edit Metaschoepite Add Synonym Edit CIF structures Clear Cache

Metaschoepite

Mesa County, Colorado, USA

Metaschoepite

Novazza mine, Valgoglio, Bergamo Province, Lombardy, Italy

Metaschoepite

Novazza mine, Valgoglio, Bergamo Province, Lombardy, Italy

Metaschoepite

Mesa County, Colorado, USA

Metaschoepite

Novazza mine, Valgoglio, Bergamo Province, Lombardy, Italy

Metaschoepite

Novazza mine, Valgoglio, Bergamo Province, Lombardy, Italy

Metaschoepite

Mesa County, Colorado, USA

Metaschoepite

Novazza mine, Valgoglio, Bergamo Province, Lombardy, Italy

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About MetaschoepiteHide

Alfred Schoep

Formula:

(UO₂)₈O₂(OH)₁₂ · 10H₂O

Studies on synthetic metaschoepite (Weller et al. 2000, Kubatko et al. 2006) confirmed presence of 10H2O.

Crystal System:

Orthorhombic

Member of:

Schoepite Group

Name:

Named by Charles L. Christ and Joan R. Clark in 1960 for the dehydrated relationship of the mineral to schoepite.

Type Locality:

ⓘ Shinkolobwe Mine, Shinkolobwe, Kambove Territory, Haut-Katanga, DR Congo

May occur as a dehydration product of schoepite, and may itself dehydrate to paulscherrerite.

Unique IdentifiersHide

Mindat ID:

2684

Long-form identifier:

mindat:1:1:2684:6

IMA Classification of MetaschoepiteHide

IMA status:

Approved, 'Grandfathered' (first described prior to 1959)

IMA Formula:

(U⁶⁺O₂)₈O₂(OH)₁₂·10H₂O

Classification of MetaschoepiteHide

Strunz-mindat (2026):

4.GA.05

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
G : Uranyl Hydroxides
A : Without additional cations

Dana 8th ed.:

5.2.1.1

5 : OXIDES CONTAINING URANIUM OR THORIUM
2 : AXO₃·xH₂O

Hey's CIM Ref.:

7.16.4

7 : Oxides and Hydroxides
16 : Oxides of U

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference for Standard
Mshp	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Chemistry of MetaschoepiteHide

Mindat Formula:

(UO₂)₈O₂(OH)₁₂ · 10H₂O

Studies on synthetic metaschoepite (Weller et al. 2000, Kubatko et al. 2006) confirmed presence of 10H2O.

Element Weights:

Element	% weight
U	73.909 %
O	24.839 %
H	1.252 %

Calculated from ideal end-member formula.

Elements listed:

H, O, U - search for minerals with similar chemistry

Crystallography of MetaschoepiteHide

Crystal System:

Orthorhombic

Class (H-M):

mmm(2/m2/m2/m) - Dipyramidal

Space Group:

Pbcn

Cell Parameters:

a = 13.98 Å, b = 16.7 Å, c = 14.67 Å

Ratio:

a:b:c = 0.837 : 1 : 0.878

Unit Cell V:

3,424.95 Å³ (Calculated from Unit Cell)

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Year	Locality	Temp (K)
0004319	Metaschoepite	Klingensmith A L, Deely K M, Kinman W S, Kelly V, Burns P C (2007) Neptunium incorporation in sodium-substituted metaschoepite American Mineralogist 92 662-669	2007	synthetic	293
0004318	Metaschoepite	Klingensmith A L, Deely K M, Kinman W S, Kelly V, Burns P C (2007) Neptunium incorporation in sodium-substituted metaschoepite American Mineralogist 92 662-669	2007	synthetic	293
0004317	Metaschoepite	Klingensmith A L, Deely K M, Kinman W S, Kelly V, Burns P C (2007) Neptunium incorporation in sodium-substituted metaschoepite American Mineralogist 92 662-669	2007	synthetic	293
0004316	Metaschoepite	Klingensmith A L, Deely K M, Kinman W S, Kelly V, Burns P C (2007) Neptunium incorporation in sodium-substituted metaschoepite American Mineralogist 92 662-669	2007	synthetic	293
0004315	Metaschoepite	Klingensmith A L, Deely K M, Kinman W S, Kelly V, Burns P C (2007) Neptunium incorporation in sodium-substituted metaschoepite American Mineralogist 92 662-669	2007	Katanga, Congo	293
0009921	Metaschoepite	Weller M T, Light M E, Gelbrich T (2000) Structure of uranium (VI) oxide dihydrate UO32H2O; synthetic meta-schoepite (UO2)4O(OH)65H2O Acta Crystallographica B56 577-583	2000	synthetic	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Metaschoepite'
loop_
_publ_author_name
'Klingensmith A L'
'Deely K M'
'Kinman W S'
'Kelly V'
'Burns P C'
_journal_name_full 'American Mineralogist'
_journal_volume 92 
_journal_year 2007
_journal_page_first 662
_journal_page_last 669
_publ_section_title
;
 Neptunium incorporation in sodium-substituted metaschoepite
 Sample: Na-Ms-AB2
;
_database_code_amcsd 0004319
_chemical_compound_source 'Synthetic'
_chemical_formula_sum 'Na.47 U8 O37.082 H26.164'
_cell_length_a 14.6592
_cell_length_b 14.0358
_cell_length_c 16.7148
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 3439.130
_exptl_crystal_density_diffrn      4.895
_symmetry_space_group_name_H-M 'P b c n'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,z'
  '1/2+x,1/2-y,-z'
  '1/2+x,1/2+y,1/2-z'
  '1/2-x,1/2-y,1/2+z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Na21   0.51000   0.68400   0.27600   0.23500   0.04000
U1   0.23414   0.74380   0.37476   1.00000   0.01425
U2   0.28636   0.76851   0.60317   1.00000   0.01568
U3   0.25637   0.51220   0.23922   1.00000   0.01576
U4   0.25652   0.51717   0.51109   1.00000   0.01603
O1   0.16830   0.74580   0.61260   1.00000   0.03200
O2   0.14520   0.46160   0.23190   1.00000   0.02900
O3   0.12250   0.74500   0.41630   1.00000   0.02020
O4   0.40570   0.78450   0.59640   1.00000   0.01940
O5   0.36990   0.56010   0.25110   1.00000   0.02280
O6   0.14070   0.54890   0.52930   1.00000   0.02660
O7   0.34490   0.74630   0.33100   1.00000   0.02610
O8   0.37210   0.48400   0.48950   1.00000   0.02930
O9   0.25240   0.92250   0.61750   1.00000   0.02900
O-H10   0.20530   0.36170   0.46850   1.00000   0.01870
O-H11   0.29660   0.67360   0.48810   1.00000   0.04000
O-H12   0.21230   0.56340   0.37260   1.00000   0.01790
O-H13   0.31230   0.60050   0.63870   1.00000   0.01680
O-H14   0.18690   0.68300   0.24350   1.00000   0.01690
O-H15   0.18800   0.88480   0.31350   1.00000   0.01800
Wat16A   0.00000   0.75100   0.25000   0.38000   0.04000
Wat16B   0.00000   0.65430   0.25000   0.48000   0.04000
Wat17   0.50040   0.41640   0.14270   0.68100   0.04000
Wat18  -0.02340   0.64490   0.57050   0.80100   0.04000
Wat19   0.02940   0.54960   0.37010   0.77700   0.04000
Wat20   0.49590   0.64040   0.41990   0.59700   0.04000
Wat22   0.50000   0.80890   0.25000   0.51000   0.04000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
U1 0.01970 0.01137 0.01163 -0.00003 -0.00099 -0.00143
U2 0.02500 0.01074 0.01126 0.00214 -0.00102 -0.00153
U3 0.02760 0.01094 0.00872 0.00096 -0.00104 0.00007
U4 0.02490 0.01192 0.01126 -0.00124 0.00134 0.00111
O1 0.03100 0.01500 0.04900 -0.00100 -0.01100 -0.00200
O2 0.03500 0.03100 0.02100 0.00300 -0.00400 -0.00400
O3 0.01700 0.02100 0.02200 0.00000 0.00500 0.00500
O4 0.02000 0.01500 0.02300 -0.00400 0.00000 0.00300
O5 0.03100 0.01300 0.02500 -0.00300 -0.00400 0.00000
O6 0.02700 0.02700 0.02600 0.00000 0.00300 -0.00600
O7 0.02000 0.03100 0.02700 0.00100 0.00200 -0.01200
O8 0.02200 0.04100 0.02600 0.00500 -0.00200 0.00300
O9 0.06300 0.01000 0.01300 0.00500 0.00300 -0.00100
O-H10 0.03700 0.00700 0.01200 0.00300 0.00700 0.00200
O-H11 0.09100 0.01600 0.01200 -0.00800 -0.02600 0.00300
O-H12 0.03500 0.01200 0.00700 0.00800 0.00200 0.00200
O-H13 0.03000 0.00900 0.01100 -0.00400 -0.00100 0.00100
O-H14 0.02200 0.01600 0.01200 -0.00700 -0.00100 -0.00100

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
5.09 Å	(100)
3.45 Å	(25)
3.39 Å	(17)
2.890 Å	(7)
2.48 Å	(7 broad)
2.542 Å	(6)
2.023 Å	(5)

Comments:

Shinkolobwe Mine, Haut-Katanga, DR Congo. The data are from Christ and Clark (1960).

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 7: Great Oxidation Event	<2.4
47a : [Near-surface hydration of prior minerals]
47f : [Uranyl (U⁶⁺) minerals]

Type Occurrence of MetaschoepiteHide

Type Locality:

ⓘ Shinkolobwe Mine, Shinkolobwe, Kambove Territory, Haut-Katanga, DR Congo

Other Language Names for MetaschoepiteHide

Dutch:Metaschoepiet

German:Metaschoepit

Spanish:Metaschoepita

Relationship of Metaschoepite to other SpeciesHide

Member of:

Schoepite Group

Other Members of Schoepite Group:

Paulscherrerite	UO₂(OH)₂	Mon.
Schoepite	(UO₂)₈O₂(OH)₁₂ · 12H₂O	Orth. mmm(2/m2/m2/m) : Pbca

Common AssociatesHide

Associations Based on Photo Data:

9 photos of Metaschoepite associated with Umohoite	(UO₂)MoO₄ · 2H₂O
8 photos of Metaschoepite associated with Parauranophane	Ca(UO₂)₂(SiO₃OH)₂ · 5H₂O
4 photos of Metaschoepite associated with Uranophane	Ca(UO₂)₂(SiO₃OH)₂ · 5H₂O
4 photos of Metaschoepite associated with Hydronováčekite	Mg(UO₂)₂(AsO₄)₂ · 12H₂O
3 photos of Metaschoepite associated with Becquerelite	Ca(UO₂)₆O₄(OH)₆ · 8H₂O
2 photos of Metaschoepite associated with Fourmarierite	Pb(UO₂)₄O₃(OH)₄ · 4H₂O
2 photos of Metaschoepite associated with Baryte	BaSO₄
1 photo of Metaschoepite associated with Gypsum	CaSO₄ · 2H₂O
1 photo of Metaschoepite associated with Vandendriesscheite	PbU₇O₂₂ · 12H₂O
1 photo of Metaschoepite associated with Uraninite	UO₂

Related Minerals - Strunz-mindat Grouping Hide

4.GA.05	Paraschoepite	UO₃ · 2H₂O	Orth. mmm(2/m2/m2/m) : Pbca
4.GA.05	Schoepite	(UO₂)₈O₂(OH)₁₂ · 12H₂O	Orth. mmm(2/m2/m2/m) : Pbca
4.GA.10	Ianthinite	U⁴⁺(UO₂)₅O₇ · 10H₂O	Orth. mm2 : Amm2
4.GA.15	Metastudtite	UO₄ · 2H₂O	Orth. mmm(2/m2/m2/m) : Pnma
4.GA.15	Studtite	[(UO₂)(O₂)(H₂O)₂] · H₂O	Mon. 2/m : B2/b
4.GA.20	Paulscherrerite	UO₂(OH)₂	Mon.

RadioactivityHide

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MetaschoepiteHide

mindat.org URL:

https://www.mindat.org/min-2684.html
Please feel free to link to this page.

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External Links:

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Look for Metaschoepite on Mineralien Atlas

Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

Mineral Dealers:

Buy from D. Joyce minerals

References for MetaschoepiteHide

Reference List:

Christ, C. L., Clark, J. R. (1960) Crystal chemical studies of some uranyl oxide hydrates. American Mineralogist, 45 (9-10) 1026-1061

Christ, C. L. (1965) Phase transformations and crystal chemistry of schoepite. American Mineralogist, 50 (1-2) 235-239

Finch, Robert J., Hawthorne, Frank C., Miller, M. L., Ewing, R. C. (1997) Distinguishing among schoepite, [(UO₂)₈O₂(OH)₁₂](H₂O)₁₂, and related minerals by X-ray powder diffraction. Powder Diffraction, 12 (4) 230-238 doi:10.1017/s0885715600009799

Finch, R.J., Hawthorne, F.C. and Ewing, R.C. (1998): Structural relations among schoepite, metaschoepite and "dehydrated schoepite". Canadian Mineralogist 36, 831-845.

Sowder, A. G., Clark, S. B., Fjeld, R. A. (1999) The Transformation of Uranyl Oxide Hydrates: The Effect of Dehydration on Synthetic Metaschoepite and Its Alteration to Becquerelite. Environmental Science & Technology, 33 (20). 3552-3557 doi:10.1021/es9901516

Weller, Mark. T., Light, Mark E., Gelbrich, Thomas (2000) Structure of uranium(VI) oxide dihydrate, UO₃·2H₂O; synthetic meta-schoepite (UO₂)₄O(OH)₆·5H₂O. Acta Crystallographica Section B Structural Science, 56 (4). 577-583 doi:10.1107/s0108768199016559

Burns, Peter C. (2005) U⁶⁺ minerals and inorganic compounds: insights into an expanded structural hierarchy of crystal structures. The Canadian Mineralogist, 43 (6) 1839-1894 doi:10.2113/gscanmin.43.6.1839

(2005) Metaschoepite. Handbook of Mineralogy. Mineralogical Society of America

Kubatko, K.-A., Helean, K., Navrotsky, A., Burns, P. C. (2006) Thermodynamics of uranyl minerals: Enthalpies of formation of uranyl oxide hydrates. American Mineralogist, 91 (4) 658-666 doi:10.2138/am.2006.1856

Klingensmith, A. L., Deely, K. M., Kinman, W. S., Kelly, V., Burns, P. C. (2007) Neptunium incorporation in sodium-substituted metaschoepite. American Mineralogist, 92 (4) 662-669 doi:10.2138/am.2007.2350

Colmenero, Francisco, Fernández, Ana María, Cobos, Joaquín, Timón, Vicente (2019) Periodic DFT Study of the Thermodynamic Properties and Stability of Schoepite and Metaschoepite Mineral Phases. ACS Earth and Space Chemistry, 3 (1). 17-28 doi:10.1021/acsearthspacechem.8b00109

Localities for MetaschoepiteHide

Showing 28 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Australia
South Australia Pastoral Unincorporated Area Arkaroola (Arkaroola Wilderness Sanctuary; Arkaroola Station) Mount Painter area ⓘ Mount Painter No. 2 workings	Brugger et al. (2003) +1 other reference
Tasmania Northern Midlands municipality Rossarden mining district ⓘ Tasmanian United Uranium Mine	Bottrill (2021)

Canada
Ontario Haliburton County Highlands East Township Cardiff Township ⓘ Richardson Mine (Fission Mine)	Reiner Mielke and Travis Olds

Czech Republic
Central Bohemian Region ⓘ Příbram District	Pauliš P. et al. (Kutna Hora, issue 1)
Karlovy Vary Region Karlovy Vary District Jáchymov ⓘ Eliáš Mine	Hloušek et al. (2002)
ⓘ Giftkies adit	Möhn et al. (12/2021)
ⓘ Svornost Mine	Analyzed by and in the collection of ...

DR Congo (TL)
Haut-Katanga Kambove Territory Shinkolobwe ⓘ Shinkolobwe Mine (TL)	Am Min 50 (1965)

France
Occitanie Hérault Lodève Lodève ⓘ Mas d'Alary opencast mine	collection BONNET Frederic

Germany
Baden-Württemberg Freiburg Region Ortenaukreis Oberwolfach ⓘ Clara Mine ?	Kolitsch (1997)
Waldshut St Blasien Menzenschwand ⓘ Krunkelbach Valley Uranium deposit	SEM-EDS and XRD by Joy Desor and ...
Saxony Erzgebirgskreis Schwarzenberg Pöhla ⓘ Pöhla-Tellerhäuser Mine	Witzke (1996)

Italy
Sardinia Metropolitan City of Cagliari Capoterra ⓘ Arcu su Linnarbu	In the collection of Brent Thorne. ...

Japan
Okayama Prefecture ⓘ Kenzan mine	Akira Kato (1973)
Shimane Prefecture Unnan City Daito ⓘ Higashiyama mine	Akira Kato (1973)

Mexico
Chihuahua Aldama Municipality Peña Blanca District Sierra Peña Blanca ⓘ Nopal No. 1 Mine	www.swri.org (2001)

Namibia
Hardap Region Daweb ⓘ Meob Bay uranium mineralisation	Bowell et al. (2017)

Pakistan
Khyber Pakhtunkhwa Province Lakki Marwat District ⓘ Qubul Khel deposit	Alia et al. (2018)

Poland
Lower Silesian Voivodeship Karkonosze County Kowary Podgórze ⓘ Podgórze Mine	Syczewski et al. (2023)

Switzerland
Valais Saint-Maurice Salvan ⓘ Van d'en Bas	Meisser (2012)

USA
Colorado Mesa County Gateway Mining District Beaver Mesa ⓘ Hubbard Homestead Mine	ID confirmed at Carnegie Museum of ... +1 other reference
San Miguel County ⓘ Burro Mine	Kampf et al. (2019)
Maine Androscoggin County Poland ⓘ Berry-Havey Quarry	King et al. (1994)
New Hampshire Sullivan County Acworth South Acworth ⓘ Beryl Mountain Quarry	Dana 8:258
New Mexico Cibola County Laguna subdistrict ⓘ St. Anthony deposit	Caldwell (2018)
North Carolina ⓘ Mitchell County	Foord et al. (1997)
Utah San Juan County La Sal Creek Mining District ⓘ Gray Daun Mine	Carnegie Museum of Natural History ...
White Canyon Mining District ⓘ Jomac Mine	Min News 16:1 p1

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Metaschoepite

About MetaschoepiteHide

Unique IdentifiersHide

IMA Classification of MetaschoepiteHide

Classification of MetaschoepiteHide

Mineral SymbolsHide

Chemistry of MetaschoepiteHide

Crystallography of MetaschoepiteHide

Crystal StructureHide

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Type Occurrence of MetaschoepiteHide

Other Language Names for MetaschoepiteHide

Relationship of Metaschoepite to other SpeciesHide

Common AssociatesHide

Related Minerals - Strunz-mindat GroupingHide

RadioactivityHide

Other InformationHide

Internet Links for MetaschoepiteHide

References for MetaschoepiteHide

Localities for MetaschoepiteHide

Locality ListHide

Related Minerals - Strunz-mindat Grouping Hide