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Mbobomkulite

A valid IMA mineral species
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About MbobomkuliteHide

Formula:
(Ni,Cu)Al4((NO3)2,SO4)(OH)12 · 3H2O
Colour:
Pale sky-blue; colorless under the microscope
Specific Gravity:
2.30
Crystal System:
Monoclinic
Name:
For the type locality, the Mbobo Mkulu cave.

Unique IdentifiersHide

Mindat ID:
2608
Long-form identifier:
mindat:1:1:2608:2

IMA Classification of MbobomkuliteHide

Approved
IMA Formula:
(Ni2+,Cu2+)Al4(N5+O3,S6+O4)2(OH)12·3H2O
Approval year:
1979
First published:
1980

Classification of MbobomkuliteHide

5.ND.10

5 : CARBONATES (NITRATES)
N : NITRATES
D : With OH (etc.) and H2O
Dana 7th ed.:
19.2.4.1
19.1.4.1

19 : NITRATES CONTAINING HYDROXYL OR HALOGEN
1 : Anhydrous Nitrates Containing Hydroxyl or Halogen
13.11

13 : Nitrates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MbbIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MbobomkuliteHide

Transparency:
Translucent
Comment:
Macroscopically powdery
Colour:
Pale sky-blue; colorless under the microscope
Cleavage:
Perfect
{001}
Density:
2.30 g/cm3 (Measured)    2.344 g/cm3 (Calculated)

Optical Data of MbobomkuliteHide

Type:
Biaxial
RI values:
nα = 1.515 nγ = 1.585
Max. Birefringence:
δ = 0.070
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Low (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Dispersion:
relatively weak

Chemistry of MbobomkuliteHide

Mindat Formula:
(Ni,Cu)Al4((NO3)2,SO4)(OH)12 · 3H2O
Element Weights:
Element% weight
O62.030 %
Al16.737 %
Ni9.102 %
S4.973 %
N4.344 %
H2.814 %

Calculated from ideal end-member formula.
O
Al
Ni
S
N
H

Crystallography of MbobomkuliteHide

Crystal System:
Monoclinic
Class (H-M):
2 - Sphenoidal
Space Group:
P21
Setting:
P21
Cell Parameters:
a = 10.17 Å, b = 8.86 Å, c = 17.14 Å
β = 95.37°
Ratio:
a:b:c = 1.148 : 1 : 1.935
Unit Cell V:
1,537.64 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Pseudohexagonal, very thin plates about 10 microns across, piled up along the c axis as well as forming rosettes.
Comment:
Space group is by analogy to chalcoalumite.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
8.550 Å(100)
4.271 Å(40)
7.87 Å(15)
4.549 Å(15)
3.179 Å(15)
3.054 Å(15)
2.512 Å(15

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47b : [Sulfates and sulfites]
47c : [Carbonates, phosphates, borates, nitrates]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
52 : Guano- and urine-derived minerals<0.4

Type Occurrence of MbobomkuliteHide

General Appearance of Type Material:
Pale blue nodules.
Place of Conservation of Type Material:
Museum of the Geological Survey, Pretoria, South Africa.
Geological Setting of Type Material:
A cave located immediately below palaeokarst residual breccia ("giant chert").
Associated Minerals at Type Locality:

Synonyms of MbobomkuliteHide

Other Language Names for MbobomkuliteHide

Simplified Chinese:硫硝镍铝石
Spanish:Mbobomkulita
Traditional Chinese:硫硝鎳鋁石

Relationship of Mbobomkulite to other SpeciesHide

Other Members of Chalcoalumite Group:
ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2OMon. 2 : P21
KyrgyzstaniteZnAl4(SO4)(OH)12 · 3H2OMon. 2/m : P21/b
NickelalumiteNiAl4(SO4)(OH)12(H2O)3Mon. 2/m

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Mbobomkulite associated with GypsumCaSO4 · 2H2O
1 photo of Mbobomkulite associated with AntleriteCu3(SO4)(OH)4

Related Minerals - Strunz-mindat GroupingHide

5.ND.05LikasiteCu3(NO3)(OH)5 · 2H2OOrth. mmm(2/m2/m2/m)
5.ND.15Hydrombobomkulite(Ni,Cu)Al4((NO3)2,SO4)(OH)12 · 13-14H2OMon.
5.ND.20Sveite(K3-xx)Al8(NO3)6O8Cl4 · nH2OMon.
5.ND.25LislkirchneritePb6Al(OH)8Cl2(NO3)5 · 2H2OMon. 2/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MbobomkuliteHide

References for MbobomkuliteHide

Localities for MbobomkuliteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Japan
 
  • Yamagata Prefecture
    • Mogami District
      • Mogami
LIN et al. (2020)
South Africa (TL)
 
  • Mpumalanga
    • Ehlanzeni District Municipality
      • Mbombela Local Municipality
        • Mbombela
Ann.Geol.Surv.S.Africa (1980) +1 other reference
USA
 
  • Utah
    • San Juan County
      • White Canyon Mining District
Vochten et al. (2001)
 
and/or  
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