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Phillipsite-K-Phillipsite-Na Series

A solid-solution series between two end-member minerals

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Phillipsite-K

Limberg Quarries, Sasbach am Kaiserstuhl, Emmendingen, Freiburg Region, Baden-Württemberg, Germany

Phillipsite-K, etc.

Vallerano Quarries, Valleranello, Rome, Metropolitan City of Rome Capital, Lazio, Italy

Phillipsite-K

Vallerano Quarries, Valleranello, Rome, Metropolitan City of Rome Capital, Lazio, Italy

Phillipsite-K

Limberg Quarries, Sasbach am Kaiserstuhl, Emmendingen, Freiburg Region, Baden-Württemberg, Germany

Phillipsite-K, etc.

Vallerano Quarries, Valleranello, Rome, Metropolitan City of Rome Capital, Lazio, Italy

Phillipsite-K

Vallerano Quarries, Valleranello, Rome, Metropolitan City of Rome Capital, Lazio, Italy

Phillipsite-K

Limberg Quarries, Sasbach am Kaiserstuhl, Emmendingen, Freiburg Region, Baden-Württemberg, Germany

Phillipsite-K, etc.

Vallerano Quarries, Valleranello, Rome, Metropolitan City of Rome Capital, Lazio, Italy

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About Phillipsite-K-Phillipsite-Na SeriesHide

Crystal System:

Monoclinic

Series Formula:

K₆(Si₁₀Al₆)O₃₂ · 12H₂O to (Na,K,Ca_0.5,Ba_0.5)_4-7[Al_4-7Si_12-9O₃₂] · 12H₂O

A series between Phillipsite-K and Phillipsite-Na

Unique IdentifiersHide

Mindat ID:

8719

Long-form identifier:

mindat:1:1:8719:9

Similar NamesHide

Phillipsite-Ca-Phillipsite-Na Series

A solid-solution series between two end-member minerals

Crystallography of Phillipsite-K-Phillipsite-Na SeriesHide

Crystal System:

Monoclinic

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0012860	Phillipsite-K	Gualtieri A F (2000) Accuracy of XRPD QPA using the combined Rietveld-RIR method Journal of Applied Crystallography 33 267-278		2000	Vallerano, Rome, Italy	0	293
0009270	Phillipsite-Na	Steinfink H (1962) The crystal structure of the zeolite, phillipsite Acta Crystallographica 15 644-651		1962	pelagic sediments of the Pacific Ocean	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Phillipsite-K'
loop_
_publ_author_name
'Gualtieri A F'
_journal_name_full 'Journal of Applied Crystallography'
_journal_volume 33 
_journal_year 2000
_journal_page_first 267
_journal_page_last 278
_publ_section_title
;
 Accuracy of XRPD QPA using the combined Rietveld-RIR method
;
_database_code_amcsd 0012860
_chemical_compound_source 'Vallerano, Rome, Italy'
_chemical_formula_sum 'K1.22 Ca.78 Na.41 (Si4.8 Al3.2) O21.13 H10.26'
_cell_length_a 9.8881
_cell_length_b 14.4040
_cell_length_c 8.6848
_cell_angle_alpha 90
_cell_angle_beta 124.2711
_cell_angle_gamma 90
_cell_volume 1022.202
_exptl_crystal_density_diffrn      2.138
_symmetry_space_group_name_H-M 'P 1 21/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2-y,z'
  '-x,1/2+y,-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
K1   0.84280   0.25000   0.18760   0.85000   0.03700
Ca2   0.58730   0.62610   0.41480   0.18500   0.06700
K2   0.58730   0.62610   0.41480   0.18500   0.06700
Na3   0.55920   0.13780   0.40140   0.20500   0.05100
Ca3   0.55920   0.13780   0.40140   0.20500   0.05100
Si1   0.73890   0.02560   0.28240   0.60000   0.01900
Al1   0.73890   0.02560   0.28240   0.40000   0.01900
Si2   0.41070   0.14190   0.00600   0.60000   0.03100
Al2   0.41070   0.14190   0.00600   0.40000   0.03100
Si3   0.05250   0.00380   0.27490   0.60000   0.02900
Al3   0.05250   0.00380   0.27490   0.40000   0.02900
Si4   0.11490   0.13940   0.05110   0.60000   0.04100
Al4   0.11490   0.13940   0.05110   0.40000   0.04100
O1   0.13860   0.09260   0.24250   1.00000   0.02000
O2   0.66150   0.57080   0.18470   1.00000   0.03000
O3   0.60780   0.10630   0.16550   1.00000   0.06900
O4   0.03070   0.91640   0.15310   1.00000   0.01400
O5   0.89180   0.04950   0.26420   1.00000   0.06700
O6   0.30130   0.36660   0.09290   1.00000   0.07000
O7   0.81720   0.48770   0.50200   1.00000   0.03800
O8   0.56590   0.75000   0.02160   1.00000   0.03800
O9   0.05780   0.25000   0.01990   1.00000   0.03000
Wat1   0.77760   0.75000   0.52880   0.78000   0.02000
Wat2   0.18910   0.75000   0.49470   0.88000   0.06000
Wat3   0.34130   0.85890   0.17360   0.90000   0.12000
Wat4   0.44200   0.25000   0.44970   1.00000   0.04000
Wat5   0.50000   0.50000   0.50000   0.67000   0.09000

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Phillipsite-K-Phillipsite-Na SeriesHide

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https://www.mindat.org/min-8719.html
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References for Phillipsite-K-Phillipsite-Na SeriesHide

Reference List:

Localities for Phillipsite-K-Phillipsite-Na SeriesHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Australia
New South Wales Buckland Co. Ardglen ⓘ Ardglen Quarry (State Rail Quarry)	[Phillipsite-Na] England (2000)
Gloucester Co. Barrington Tops Barrington ⓘ Cowlesite locality	[Phillipsite-K] Graham et al. (2002)
Northumberland County Kulnura ⓘ Hanson Quarry (Hymix Quarry; Kulnura Quarry)	[Phillipsite-K] Graham et al. (2020)
Westmoreland County ⓘ Hargraves quarry	[Phillipsite-K] Graham et al. (2002)
South Australia Pastoral Unincorporated Area Iron Knob ⓘ Iron Monarch Main Pit	[Phillipsite-K] Francis (2010)
Victoria City of Casey Narre Warren North ⓘ Pioneer quarry	[Phillipsite-Na] Birch (1989)
City of Whittlesea Bundoora ⓘ Boral Limited quarry	[Phillipsite-Na] Birch (1989) +1 other reference
City of Yarra Abbotsford ⓘ F-19 Freeway Cutting	[Phillipsite-Na] B. Birch chemical analysis +1 other reference
Collingwood Clifton Hill ⓘ Corporation quarries	[Phillipsite-Na] Birch (1989)
Fairfield ⓘ F-19 Freeway cutting	[Phillipsite-Na] Birch (1989)
ⓘ Richmond	[Phillipsite-Na] Gatta et al. (2009)
Hepburn Shire Trentham ⓘ Trentham Falls	[Phillipsite-K] Hollis (1979) +1 other reference

Austria
Burgenland Oberpullendorf District Markt Sankt Martin Pauliberg ⓘ Basalt quarry	[Phillipsite-K] U. Kolitsch et al. (2009)
Styria Südoststeiermark District Bad Gleichenberg Wilhelmsdorf ⓘ Stradner Kogel	[Phillipsite-K] Christine Elisabeth Hollerer (2001) +1 other reference

Canada
Québec Montérégie La Vallée-du-Richelieu RCM Mont Saint-Hilaire ⓘ Poudrette quarry (De-Mix quarry; Demix quarry; Uni-Mix quarry; Carrière Mont Saint-Hilaire; MSH)	[Phillipsite-K] Horváth et al. (1990) +1 other reference
Lajemmerais RCM Varennes & St-Amable Saint-Amable sill ⓘ Demix-Varennes quarry	[Phillipsite-K] HORVÁTH (2010)

China
Zhejiang Shaoxing ⓘ Shengzhou Co.	[Phillipsite-K] Jeffrey de Fourestier

Costa Rica
Alajuela Province Sarchí Canton ⓘ Poás Volcano	[Phillipsite-K] Rodríguez et al. (2017)

Cyprus
Larnaca District Athienou ⓘ Avhellero (Avdellero)	[Phillipsite-K] Prüfer (2011)

Czech Republic
Karlovy Vary Region Karlovy Vary District Krásný Les ⓘ Horní Hrad	[Phillipsite-K] Pauliš P. et al. (2015)
Liberec Region Česká Lípa District Cvikov ⓘ Křížový vrch quarry	[Phillipsite-K] Pauliš et al. (2023)
Nový Bor Arnultovice ⓘ Zaječí hill	[Phillipsite-K] Pauliš et al. (2019)
Nový Oldřichov ⓘ Mistrovice	[Phillipsite-K] P.Pauliš et al. (Czech republic)
Okrouhlá ⓘ Klučky-Hillside (Stráň)	[Phillipsite-K] Libor Hrůzek-Personal reference
ⓘ Klučky-Parking	[Phillipsite-K] Libor Hrůzek-Personal reference
Polevsko ⓘ Wachstein	[Phillipsite-K] Libor Hrůzek-Personal reference +1 other reference
Svor ⓘ Unnamed hill (altitude 455 m)	[Phillipsite-K] P.Pauliš et al. (Czech rep.)
Tachov ⓘ Tachovský Hill quarry	[Phillipsite-K] P.Pauliš et al. (2017)
South Moravian Region Znojmo District Jamolice ⓘ Templštejn	[Phillipsite-K] Hrazdil (2001)
Ústí nad Labem Region Děčín District Česká Kamenice Líska ⓘ Bukovina hill	[Phillipsite-K] Pauliš et al. (2024)
Malá Veleň ⓘ Jedlka	[Phillipsite-K] Pauliš et al. (2021)
ⓘ Havraní kameny	[Phillipsite-K] Petr Fuchs collection
Soutěsky (Zautig) ⓘ Böhmite locality	[Phillipsite-K] P.Pauliš et al. (Czech Rep.)
Litoměřice District Lovečkovice ⓘ Mukařov	[Phillipsite-K] ZEMAN P. (2018)
Úštěk ⓘ Pohorsko-Pohorský Hill	[Phillipsite-K] P.Zeman et al. (2017)
Ústí nad Labem District Chuderov Radešín ⓘ Radešín hill	[Phillipsite-K] Petr Fuchs (2024, December)

France
Auvergne-Rhône-Alpes Puy-de-Dôme Ambert Brousse ⓘ Montboissier quarry	[Phillipsite-K] Leconte J. (2015)
Issoire Perrier ⓘ Roca-Neyra	[Phillipsite-K] Galli et al. (1972)
Occitanie Ariège Foix Auzat ⓘ La Freychinède	[Phillipsite-K] Christophe Schwarze

Germany
Baden-Württemberg Freiburg Region Emmendingen Sasbach am Kaiserstuhl ⓘ Limberg Quarries	[Phillipsite-K] WEISENBERGER et al. (2009)
ⓘ Quarry II	[Phillipsite-K] Volker Betz and Peter Lof collections ...
ⓘ Quarry VI	[Phillipsite-K] Volker Betz collection and photos
Bavaria Upper Franconia Wunsiedel im Fichtelgebirge Selb Längenau ⓘ Wartberg quarries	[Phillipsite-K] Keck (2008)
Upper Palatinate Tirschenreuth District Kemnath Waldeck ⓘ Kalvarienberg	[Phillipsite-K] Pöllmann et al. (2007)
Pechbrunn ⓘ Großer Teichelberg (Teichelberg; Teichlberg)	[Phillipsite-K] Keck (2004)
Hesse Darmstadt Wetteraukreis Nidda ⓘ Rübenkeller	[Phillipsite-K] Doelter (1921)
Ortenberg ⓘ Gaulsberg quarry	[Phillipsite-K] SEM-EDS by Joy Desor
Giessen Region Lahn-Dill-Kreis Greifenstein Allendorf ⓘ Alter Stein Quarry	[Phillipsite-K] Hanneberg et al. (2009) +1 other reference
Rhineland-Palatinate Ahrweiler Brohltal Brenk ⓘ Schellkopf	[Phillipsite-K] Blass et al. (2006)
Glees ⓘ Hüttenberg	[Phillipsite-K] Blass (2010)
Altenkirchen Daaden-Herdorf Herdorf Malscheid (Mahlscheid; Mahlscheiderkopf; Mahlscheider Kopf) ⓘ Basalt quarry	[Phillipsite-K] Klein (2011)
Mayen-Koblenz Mendig Mendig ⓘ In den Dellen quarries	[Phillipsite-K] Blass (2010)
Pellenz Nickenich ⓘ Nickenicher Sattel	[Phillipsite-K] Blass et al. (2006)
Vordereifel Ettringen ⓘ Caspar quarry	[Phillipsite-K] Blass et al. (2006)
Vulkaneifel Daun Üdersdorf ⓘ Löhley	[Phillipsite-K] Hentschel (1983) +1 other reference
Gerolstein Gerolstein Roth ⓘ Rother Kopf	[Phillipsite-K] Blaß et al. (2012)
Hillesheim ⓘ Graulay quarry	[Phillipsite-K] Blass et al. (2006)
Kelberg Drees ⓘ Niveligsberg	[Phillipsite-K] Blass et al. (2006)
Höchstberg ⓘ Höchstberg (Schwarzley; Schwarzlay)	[Phillipsite-K] Blaß et al. (2003)
Saxony Erzgebirgskreis Bärenstein ⓘ Bärenstein quarry	[Phillipsite-K] Witzke (1994)

Hungary
Nógrád County ⓘ Bátonyterenye	[Phillipsite-Na] Szakáll et al. (2014)
Hasznos ⓘ Kövicses Brook Valley	[Phillipsite-K] Geoda
Veszprém County Sümeg District ⓘ Sümegprága	[Phillipsite-Na] Kónya-MÁFI
Tapolca District Zalahaláp ⓘ Halápi Hill (Haláp Hill)	[Phillipsite-K] Kónya et al. (2011)

Italy
Campania Metropolitan City of Naples Bacoli ⓘ Torregaveta	[Phillipsite-Na] Russo M. (2008)
Ercolano San Vito ⓘ San Vito Quarry	[Phillipsite-K] Russo et al. (2004) +1 other reference
Pollena Trocchia ⓘ Pollena quarries	[Phillipsite-K] Russo et al. (2004)
ⓘ Procida Island	[Phillipsite-Na] Russo (2008) +1 other reference
Sant'Anastasia ⓘ Lagno Amendolare	[Phillipsite-K] Russo et al. (2004) +1 other reference
Somma Vesuviana ⓘ Trapolino Quarry (Cava Nuova)	[Phillipsite-K] Russo (1996) +2 other references
Terzigno ⓘ Vitiello Quarry (Cava Vitiello)	[Phillipsite-K] Luigi Chiappino data +1 other reference
Torre del Greco ⓘ Villa Inglese quarries	[Phillipsite-K] Russo (1981) +4 other references
Lazio Metropolitan City of Rome Capital Monte Compatri Laghetto (Laghetto di Montecompatri) ⓘ Laghetto quarries	[Phillipsite-K] Stoppani et al. (1982) +2 other references
Rome ⓘ Capo di Bove	[Phillipsite-K] Marignac (1845) +2 other references
Osteria dell'Osa ⓘ Osa Quarry	[Phillipsite-K] Del Caldo (1971) +5 other references
Valleranello ⓘ Vallerano Quarries	[Phillipsite-K] Zambonini (1902) +5 other references
Viterbo Province Onano ⓘ Montenero Quarry	[Phillipsite-K] Cresta et al. (2002)
ⓘ Vetralla	[Phillipsite-K] AMI UK Service
ⓘ Tre Croci	[Phillipsite-K] Ciriotti et al. (2011)
Liguria Genoa Tiglieto ⓘ Badia di Tiglieto	[Phillipsite-K] Balestra C. (2014)
Piedmont Verbano-Cusio-Ossola Province Baveno Oltrefiume Mount Camoscio ⓘ Locatelli quarry	[Phillipsite-K] Grill (1935)
ⓘ Seula mine	[Phillipsite-K] Sergio Varvello collection
Sicily Metropolitan City of Catania Aci Castello ⓘ Rupe di Aci Castello	[Phillipsite-Na] Di Franco (1904) +4 other references
ⓘ Palagonia	[Phillipsite-K] Sicurella et al. (2010)
ⓘ Mount Caliella	[Phillipsite-K] Sicurella et al. (2010)
Syracuse Province Pachino ⓘ Contrada Maucini	[Phillipsite-K] Bianchi et al. (2020)
Tuscany Grosseto Province Pitigliano ⓘ Case Collina	[Phillipsite-K] AMI UK Service
Veneto Verona Province Marano di Valpolicella ⓘ Santa Cristina	[Phillipsite-K] Boscardin (2014)
Soave ⓘ Fittà	[Phillipsite-K] Boscardin (2014)
Vicenza Province Fara Vicentino San Giorgio di Perlena ⓘ "Fortelongo" locality	[Phillipsite-K] Boscardin et al. (2011)
Lugo di Vicenza ⓘ San Pietro di Lugo (San Pietro Mare)	[Phillipsite-K] Boscardin et al. (1975) +3 other references
Marostica Marsan ⓘ Monte Gloso (Monte di Gloso)	[Phillipsite-K] Boscardin et al. (2010) +1 other reference
Montecchio Maggiore San Pietro ⓘ Monte Nero	[Phillipsite-Na] Boscardin et al. (2011)
San Pietro Mussolino ⓘ Bertocchi quarry (ex Alvese quarry)	[Phillipsite-K] Zorzi et al. (eds.)
ⓘ Schio-Valdagno Tunnel (Zovo Tunnel)	[Phillipsite-Na] Passaglia et al. (2009) +1 other reference

Japan
Niigata Prefecture ⓘ Sado City	[Phillipsite-Na] Chiba et al (1995)
Shimane Prefecture Hamada City ⓘ Hamada alkaline volcanics	[Phillipsite-K] Matsubara (1998)

New Zealand
Canterbury Region Hurunui District Culverden ⓘ Pahau River	[Phillipsite-K] S. J. Mills
Otago Region Dunedin City ⓘ Blackhead Quarry	[Phillipsite-K] Blackhead Quarry +1 other reference
ⓘ Moeraki Point	[Phillipsite-K] J. Thornton in Micro-Scope

Portugal
Madeira Madeira Island Machico Porto da Cruz ⓘ Terra do Baptista gabbro outcrop	[Phillipsite-Na] Alves (n.d.)

Russia
Murmansk Oblast Khibiny Massif ⓘ Koashva Mt	[Phillipsite-K] PEKOV et al. (2013)
ⓘ Kukisvumchorr Mt	[Phillipsite-K] Pekov et al. (2004)
ⓘ Lovozero Massif	[Phillipsite-K] ...
Lovozersky District ⓘ Alluaiv Mountain	[Phillipsite-K] Yakovenchuk et al. (2010)
Suoluaiv Mountain ⓘ Seidozeritovyi pegmatite no. 1	[Phillipsite-K] Igor Pekov data
Sverdlovsk Oblast Asbest ⓘ Bazhenovskoye deposit	[Phillipsite-K] Антонов (2003)

Slovakia
Banská Bystrica Region Lučenec District Veľké Dravce ⓘ Basalt quarry	[Phillipsite-K] Martin Števko-unpublished
Prešov Region Vranov nad Topľou District Vechec ⓘ Vechec quarry	[Phillipsite-K] Števko M. et al. (2019)

South Africa
KwaZulu-Natal eThekwini Metropolitan Municipality Durban Umhlatuzana valley ⓘ Clairwood quarries	[Phillipsite-Na] Heron +2 other references

Spain
Andalusia Almería Níjar Cabo de Gata volcanic complex ⓘ Agua Amarga	[Phillipsite-K] Paragénesis.Revista de Mineralogia. ...
Canary Islands Las Palmas Province Fuerteventura Pájara ⓘ Valuello de la Cal	[Phillipsite-Na] Erich Keck
Lanzarote Haría ⓘ Famara cliff	[Phillipsite-K] Calvo (2018)
Yaiza Playa Blanca ⓘ Punta del Aguila	[Phillipsite-Na] Erich keck (personal communication)
Santa Cruz de Tenerife Province Tenerife Adeje Torviscas Alto ⓘ "Avenida de Francia" outcrop	[Phillipsite-Na] Analyzed by XRD by Dr. Joan Vinals (Barcelona)
Arona ⓘ ~~Centinela~~	[Phillipsite-Na] Dill et al. (2023)
Granadilla de Abona ⓘ El Médano	[Phillipsite-K] Calvo (2018)
Santa Cruz de Tenerife ⓘ Los Pasitos quarry	[Phillipsite-Na] Collection Agustin Agudo Espinosa ...
ⓘ Punta de los Organos quarry	[Phillipsite-K] Analyzed by XRD by Dr. Joan Vinals (Barcelona)
Santiago del Teide ⓘ ~~Puerto de Santiago~~	[Phillipsite-Na] Dill et al. (2023)
Castile-La Mancha Ciudad Real Ciudad Real ⓘ El Arzollar volcano	[Phillipsite-K] Calvo et al. (2013)
Catalonia Girona Bescanó ⓘ Crosa de Sant Dalmai volcano	[Phillipsite-K] Joan Rosell. RosellMinerals (2021)

Switzerland
Grisons Surselva Region Tujetsch Val Strem ⓘ Oberalpstock south slope	[Phillipsite-K] Stalder et al. (1998)

USA
Arizona Maricopa County ⓘ Horseshoe Dam area (Horseshoe Dam Clinoptilolite occurrence)	[Phillipsite-K] AM61_853
California Kern County Boron Kramer Borate deposit Rio Tinto Borax Mine ⓘ Rio Tinto Borax open pit	[Phillipsite-Na] Tschernich (1992) +1 other reference
Los Angeles County Agoura Hills ⓘ Canwood Street site	[Phillipsite-Na] Fred DeVito collection
Hawaii Honolulu County Oahu Island Honolulu ⓘ Moiliili Quarry	[Phillipsite-K] Dunham (1933)
Nevada Clark County Spring Mountains Goodsprings Mining District ⓘ Rosella claim	[Phillipsite-Na] Robert Housley pers.comm.
Oregon Clackamas County Clackamas River localities ⓘ Fish Creek Road - highway 224 junction	[Phillipsite-K] Gladwell ( ) +3 other references
Lincoln County Agate Beach ⓘ Yaquina Head Quarry	[Phillipsite-Na] Micro Probe Vol. 9 No 3 +1 other reference
Tillamook County Netarts ⓘ Cape Lookout Quarry	[Phillipsite-K] Micro Probe Volume VI Number 4
Washington Douglas County ⓘ Rock Island Dam	[Phillipsite-K] Tschernich et al. (1982) +1 other reference
Skamania County Cook ⓘ Carpathite occurrence	[Phillipsite-K] Gladwell (2022)

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