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Calciborite

A valid IMA mineral species - grandfathered
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About CalciboriteHide

Formula:
Ca(B2O4)
Colour:
Colorless to white
Hardness:
Specific Gravity:
2.878
Crystal System:
Orthorhombic
Name:
The name alludes to the composition, containing CALCIum and BORon.
Calcium metaborate.

Compare the hydrated calcium borate korzhinskite.


Unique IdentifiersHide

Mindat ID:
854
Long-form identifier:
mindat:1:1:854:9

IMA Classification of CalciboriteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
CaB2O4

Classification of CalciboriteHide

6.BC.10

6 : BORATES
B : Diborates
C : Ino-diborates with triangles and/or tetrahedra
24.5.2.1

24 : ANHYDROUS BORATES
5 : Miscellaneous
9.3.1

9 : Borates
3 : Borates of Ca and Sr

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
CboIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CalciboriteHide

Transparency:
Transparent, Translucent
Colour:
Colorless to white
Hardness:
3½ on Mohs scale
Fracture:
Irregular/Uneven, Conchoidal
Density:
2.878 g/cm3 (Measured)    2.88 g/cm3 (Calculated)

Optical Data of CalciboriteHide

Type:
Biaxial (-)
RI values:
nα = 1.595 nβ = 1.654 nγ = 1.670
2V:
Measured: 54° , Calculated: 52°
Max. Birefringence:
δ = 0.075
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v or r < v

Chemistry of CalciboriteHide

Mindat Formula:
Ca(B2O4)
Element Weights:
Element% weight
O50.914 %
Ca31.885 %
B17.202 %

Calculated from ideal end-member formula.
O
Ca
B

Crystallography of CalciboriteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pccn
Setting:
Pccn
Cell Parameters:
a = 8.38 Å, b = 13.82 Å, c = 5.00 Å
Ratio:
a:b:c = 0.606 : 1 : 0.362
Unit Cell V:
579.06 ų (Calculated from Unit Cell)
Z:
8

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012450CalciboriteShashkin D N, Simonov M A, Belov N V (1970) Crystal structure of calciborite CaB2O4=Ca2[BO3BO]2 Doklady Akademii Nauk SSSR 195 345-34819700293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.44 Å(10)
3.57 Å(8)
1.976 Å(7)
1.870 Å(7)
1.793 Å(7)
7.10 Å(6)
3.81 Å(6)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
31 : Thermally altered carbonate, phosphate, and iron formations

Type Occurrence of CalciboriteHide

General Appearance of Type Material:
Prismatic crystals, to 1.5 cm
Place of Conservation of Type Material:
St. Petersburg Mining Institute, St. Petersburg, 1297/1; A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 64943.
Geological Setting of Type Material:
a contact metasomatized limestone near a quartz diorite
intrusion associated with a copper deposit in skarn.
Associated Minerals at Type Locality:

Other Language Names for CalciboriteHide

Related Minerals - Strunz-mindat GroupingHide

6.BC.15VimsiteCaB2O2(OH)4Mon. 2/m : B2/b
6.BC.20ParasibirskiteCa2(B2O5) · H2OMon. 2/m : P21/m
6.BC.20SibirskiteCa2(HB2O5)(OH)Mon. 2/m : P21/b
6.BC.25ShimazakiiteCa2B2-xO5-3x(OH)3x (x = 0~0.06)Mon. 2/m : P21/b

Other InformationHide

Notes:
Bright green cathodoluminescence.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for CalciboriteHide

References for CalciboriteHide

Reference List:

Localities for CalciboriteHide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Japan
 
  • Okayama Prefecture
    • Takahashi City
      • Bitchū
        • Fuka
Kobayashi et al. (2014)
Russia (TL)
 
  • Sverdlovsk Oblast
    • Serovsky District
      • Turya river
        • Tur'insk
American Mineralogist: 85: 1322. +6 other references
 
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