Unnamed (Pd Arsenide)
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Formula:
Pd5As2
From empirical formula (Stillwater Complex): close to (Pd,Au,Hg,Cu,Pt)8(As,Sn)2
Colour:
brown-grey (phase II, Poland; reflected light?)
Crystal System:
Orthorhombic
The correct name is UM1975-05-As:Pd. Compositionally similar to arsenopalladinite, stillwaterite, isomertieite. Compare 'UM1984-01-As:AgAuCuNiPdS'.
The material from Polish Cu-bearing Zechstein shales, associated with electrum and sometimes found in the contact zone of gold and other Pd minerals, corresponds to:
- Pd2.73Cu0.67Ag0.55Au0.37(Ni,Co,Fe,Bi)0.67As2.00S0.19 phase [here: phase I]
- a similar Pd3.21Ag0.60Cu0.49Ni0.22(Au,Co,Bi,Fe)0.09As2.00S0.17 phase [here: phase II]
The material from Stillwater Complex is coded in the Valid Unnamed Minerals list as UM1975-05-As:Pd; it coexists with chalcopyrite, palladoarsenide, sperrylite; with stillwaterite; with and Unnamed (Pd-Cu-As phase).
Compare: UM1975-06-As:Pd, UM1975-01-As:AgCoNiPdS, UM1975-02-As:AgCuNiPdS, UM1975-03-As:AgCuPdS, UM1975-04-As:NiPdS, Unnamed (Pd Arsenide Sulfide).
The material from Polish Cu-bearing Zechstein shales, associated with electrum and sometimes found in the contact zone of gold and other Pd minerals, corresponds to:
- Pd2.73Cu0.67Ag0.55Au0.37(Ni,Co,Fe,Bi)0.67As2.00S0.19 phase [here: phase I]
- a similar Pd3.21Ag0.60Cu0.49Ni0.22(Au,Co,Bi,Fe)0.09As2.00S0.17 phase [here: phase II]
The material from Stillwater Complex is coded in the Valid Unnamed Minerals list as UM1975-05-As:Pd; it coexists with chalcopyrite, palladoarsenide, sperrylite; with stillwaterite; with and Unnamed (Pd-Cu-As phase).
Compare: UM1975-06-As:Pd, UM1975-01-As:AgCoNiPdS, UM1975-02-As:AgCuNiPdS, UM1975-03-As:AgCuPdS, UM1975-04-As:NiPdS, Unnamed (Pd Arsenide Sulfide).
Unique Identifiers
Mindat ID:
7675
Long-form identifier:
mindat:1:1:7675:9
Physical Properties of Unnamed (Pd Arsenide)
Colour:
Brown-grey (phase II, Poland; reflected light?)
Optical Data of Unnamed (Pd Arsenide)
Bireflectance:
none to weak (oil, Stillwater Complex); weak (air, Poland)
Reflectivity:
| Wavelength | R1 (%) |
|---|---|
| 0nm | 8 (Poland% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 8 (Poland%.
Colour in reflected light:
pale cream to cream (Stillwater Complex)
Chemistry of Unnamed (Pd Arsenide)
Mindat Formula:
Pd5As2
From empirical formula (Stillwater Complex): close to (Pd,Au,Hg,Cu,Pt)8(As,Sn)2
From empirical formula (Stillwater Complex): close to (Pd,Au,Hg,Cu,Pt)8(As,Sn)2
Elements listed:
Crystallography of Unnamed (Pd Arsenide)
Crystal System:
Orthorhombic
Cell Parameters:
a = 11.261(4) Å, b = 3.857(1) Å, c = 11.345(5) Å
Ratio:
a:b:c = 2.92 : 1 : 2.941
Unit Cell V:
492.76 ų (Calculated from Unit Cell)
Comment:
Stillwater Complex
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.066 Å | (100) |
| 2.778 Å | (60) |
| 2.433 Å | (50) |
| 2.119 Å | (80) |
| 1.947 Å | (90) |
| 0.7770 Å | (90) |
Comments:
Stillwater Complex; different from stillwaterite and arsenopalladinite
Synonyms of Unnamed (Pd Arsenide)
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Unnamed (Pd Arsenide)
mindat.org URL:
https://www.mindat.org/min-7675.html
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References for Unnamed (Pd Arsenide)
Localities for Unnamed (Pd Arsenide)
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Poland | |
| Kucha (1975) |
Russia | |
| [AmMin 85:265] |
| Sluzhenikin et al. (2015) | |
| [AmMin 65:198] |
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