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Unnamed (Pd Arsenide)

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Formula:
Pd5As2
From empirical formula (Stillwater Complex): close to (Pd,Au,Hg,Cu,Pt)8(As,Sn)2
Colour:
brown-grey (phase II, Poland; reflected light?)
Crystal System:
Orthorhombic
The correct name is UM1975-05-As:Pd. Compositionally similar to arsenopalladinite, stillwaterite, isomertieite. Compare 'UM1984-01-As:AgAuCuNiPdS'.

The material from Polish Cu-bearing Zechstein shales, associated with electrum and sometimes found in the contact zone of gold and other Pd minerals, corresponds to:

- Pd2.73Cu0.67Ag0.55Au0.37(Ni,Co,Fe,Bi)0.67As2.00S0.19 phase [here: phase I]
- a similar Pd3.21Ag0.60Cu0.49Ni0.22(Au,Co,Bi,Fe)0.09As2.00S0.17 phase [here: phase II]

The material from Stillwater Complex is coded in the Valid Unnamed Minerals list as UM1975-05-As:Pd; it coexists with chalcopyrite, palladoarsenide, sperrylite; with stillwaterite; with and Unnamed (Pd-Cu-As phase).

Compare: UM1975-06-As:Pd, UM1975-01-As:AgCoNiPdS, UM1975-02-As:AgCuNiPdS, UM1975-03-As:AgCuPdS, UM1975-04-As:NiPdS, Unnamed (Pd Arsenide Sulfide).


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Unique IdentifiersHide

Mindat ID:
7675
Long-form identifier:
mindat:1:1:7675:9

Physical Properties of Unnamed (Pd Arsenide)Hide

Colour:
Brown-grey (phase II, Poland; reflected light?)

Optical Data of Unnamed (Pd Arsenide)Hide

Bireflectance:
none to weak (oil, Stillwater Complex); weak (air, Poland)
Reflectivity:
WavelengthR1 (%)
0nm8 (Poland%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 8 (Poland%.
Colour in reflected light:
pale cream to cream (Stillwater Complex)

Chemistry of Unnamed (Pd Arsenide)Hide

Mindat Formula:
Pd5As2

From empirical formula (Stillwater Complex): close to (Pd,Au,Hg,Cu,Pt)8(As,Sn)2
Element Weights:
Element% weight
Pd78.027 %
As21.973 %

Calculated from ideal end-member formula.

Crystallography of Unnamed (Pd Arsenide)Hide

Crystal System:
Orthorhombic
Cell Parameters:
a = 11.261(4) Å, b = 3.857(1) Å, c = 11.345(5) Å
Ratio:
a:b:c = 2.92 : 1 : 2.941
Unit Cell V:
492.76 ų (Calculated from Unit Cell)
Comment:
Stillwater Complex

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.066 Å(100)
2.778 Å(60)
2.433 Å(50)
2.119 Å(80)
1.947 Å(90)
0.7770 Å(90)
Comments:
Stillwater Complex; different from stillwaterite and arsenopalladinite

Synonyms of Unnamed (Pd Arsenide)Hide

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Unnamed (Pd Arsenide)Hide

References for Unnamed (Pd Arsenide)Hide

Localities for Unnamed (Pd Arsenide)Hide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Poland
 
  • Lower Silesian Voivodeship
    • Legnica City
Kucha (1975)
Russia
 
  • Krasnoyarsk Krai
    • Taymyrskiy Autonomous Okrug
      • Taimyr Peninsula
        • Norilsk-Talnakh Mining Region
[AmMin 85:265]
Sluzhenikin et al. (2015)
  • Murmansk Oblast
    • Monchegorsk
      • Sopcha Massif
[AmMin 65:198]
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