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Arnhemite

Valid as an unnamed mineral
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Formula:
(K,Na)4Mg2(P2O7)2 · 5H2O
Colour:
White
Lustre:
Pearly
Crystal System:
Hexagonal
Name:
Named after its locality.
A hydrated pyrophospate originated from hydration of slag formed by bat guano combustion in Arnhem Cave, Namibia, about 2000 years ago. Cause of combustion unknown.

See also pyrocoproite and pyrophosphite; UM1991-10-PO:BaCaHMgSr; and approved pyrophosphate minerals: canaphite, anastasenkoite, and wooldridgeite.

Originally reported from Arnhem Cave, Windhoek District, Khomas Region, Namibia.


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Unique IdentifiersHide

Mindat ID:
6806
Long-form identifier:
mindat:1:1:6806:8

IMA Classification of ArnhemiteHide

IMA status notes:
Unnamed (probably valid)
Approval history:
Unnamed, but probably valid.

Classification of ArnhemiteHide

8.FC.20

8 : PHOSPHATES, ARSENATES, VANADATES
F : Polyphosphates, Polyarsenates, [4]-Polyvanadates
C : Polyphosphates, etc., with H2O only

Physical Properties of ArnhemiteHide

Pearly
Colour:
White

Optical Data of ArnhemiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.516 nε = 1.503
Max. Birefringence:
δ = 0.013
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Low (negative)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of ArnhemiteHide

Mindat Formula:
(K,Na)4Mg2(P2O7)2 · 5H2O
Element Weights:
Element% weight
O47.279 %
K24.324 %
P19.269 %
Mg7.560 %
H1.568 %

Calculated from ideal end-member formula.
O
K
P
Mg
H

Crystallography of ArnhemiteHide

Crystal System:
Hexagonal

Other Language Names for ArnhemiteHide

German:Arnhemit
Norwegian:Arnhemitt
Spanish:Arnhemita

Related Minerals - Strunz-mindat GroupingHide

8.FC.DonowensiteCa(H2O)3Fe3+2(V2O7)2Tric. 1 : P1
8.FC.XHylbrowniteNa3Mg(P3O10) · 12H2O Mon. 2/m
8.FC.05FianeliteMn2+2((V,As)2O7) · 2H2OMon. 2/m
8.FC.05RüdlingeriteMn2+2V5+As5+O7 · 2H2OMon.
8.FC.10CanaphiteNa2Ca(P2O7) · 4H2OMon. m : Pb
8.FC.15PintadoiteCa2(V2O7) · 9H2O
8.FC.25WooldridgeiteNa2CaCu2+2(P2O7)2 · 10H2OOrth. mm2 : Fdd2
8.FC.30KanoneroviteNa3Mn2+(P3O10) · 12H2OMon. 2/m
8.FC.35MesaiteCaMn2+5(V2O7)3 · 12H2OMon. 2/m : P2/b

RadioactivityHide

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ArnhemiteHide

References for ArnhemiteHide

Localities for ArnhemiteHide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Namibia
 
  • Khomas Region
    • Windhoek Rural
Martini (1994) +1 other reference
Saudi Arabia
 
  • Mecca Region
Saudi Geological Survey Open-File ... +1 other reference
 
and/or  
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