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Mikecoxite

A valid IMA mineral species
This page kindly sponsored by Michael Cox
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About MikecoxiteHide

08879480017271953996400.jpg
Michael "Mike" Cox collecting mercury minerals

Castellón, Valencian Community, Spain
Formula:
[CHg4]OCl2
Colour:
Black
Lustre:
Metallic, Sub-Metallic
Specific Gravity:
8.58 (Calculated)
Crystal System:
Monoclinic
Name:
Named in honor of Michael F. Cox (b. 1958) of Soquel, California, USA. He is a founding member of the New Almaden Quicksilver County Park Association (NAQCPA) and was responsible for characterizing and remediating environmental mercury on the site. He collected the rock containing the type material. He has also contributed to the research of other mercury-bearing species and is a very active member of the Bay Area Mineralogists (California, USA).
New structure type. First natural mercuroorganic compound. First mineral with tetramercurated methane moiety within.

Found in cavities of the host rock.

Structure details:
* 3-coordinated oxygen
* strongly corrugated layers
* layer topology fits that predicted for Hofmann's base

First evidence of cleaving C-C bonds by Hg2+ in nature (at least at the time of its first description).


Unique IdentifiersHide

Mindat ID:
55683
Long-form identifier:
mindat:1:1:55683:3

IMA Classification of MikecoxiteHide

Approved
IMA Formula:
[C4-Hg2+4]OCl2
First published:
2023

Classification of MikecoxiteHide

3.DD.

3 : HALIDES
D : Oxyhalides, hydroxyhalides and related double halides
D : With Hg

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
McxIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MikecoxiteHide

Metallic, Sub-Metallic
Transparency:
Opaque
Colour:
Black
Hardness Data:
Could not be measured
Comment:
Not measured but soft when manipulated with a needle.
Cleavage:
None Observed
Parting:
None Observed
Density:
8.58 g/cm3 (Calculated)
Comment:
Calculated based on the ideal formula.

Chemistry of MikecoxiteHide

Mindat Formula:
[CHg4]OCl2
Element Weights:
Element% weight
Hg89.025 %
Cl7.867 %
O1.775 %
C1.333 %

Calculated from ideal end-member formula.

Crystallography of MikecoxiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 10.164(5) Å, b = 10.490(4) Å, c = 6.547(3) Å
β = 90.037(10)°
Ratio:
a:b:c = 0.969 : 1 : 0.624
Unit Cell V:
698 ų
Z:
4
Morphology:
Bladed crystals.
Twinning:
Interpenetration twins (2-fold rotation about the c-axis).
Comment:
space group is P21/n

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.49 Å(34)
4.65 Å(32)
2.989 Å(81)
2.884 Å(100)
2.673 Å(79)
2.300 Å(30)
2.0453 Å(30)
1.7443 Å(40)
Comments:
McDermitt Mine, Nevada, USA. Data from the type description.

Type Occurrence of MikecoxiteHide

General Appearance of Type Material:
Prismatic / bladed crystals, highly reflective, <0.1 x 0.05 mm.
Place of Conservation of Type Material:
Mineralogical collections of the Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA, catalogue number 76196 (holotype) and 76197 (cotype).
Associated Minerals at Type Locality:

Other Language Names for MikecoxiteHide

German:Mikecoxit

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Mikecoxite associated with QuartzSiO2
3 photos of Mikecoxite associated with Kleinite(Hg2N)(Cl,SO4) · nH2O
2 photos of Mikecoxite associated with Eglestonite[Hg2]2+3OCl3(OH)
2 photos of Mikecoxite associated with CinnabarHgS
2 photos of Mikecoxite associated with TerlinguacreekiteHg2+3Cl2O2
1 photo of Mikecoxite associated with Calomel[Hg2]2+Cl2

Related Minerals - Strunz-mindat GroupingHide

3.DD.05Eglestonite[Hg2]2+3OCl3(OH)Iso. m3m(4/m32/m) : Ia3d
3.DD.05Kadyrelite[Hg2]2+3OBr3(OH)Iso. m3m(4/m32/m) : Ia3d
3.DD.10Poyarkovite[Hg2]2+3Cl2O2Mon. 2/m : B2/b
3.DD.15Hanawaltite[Hg2]2+3Hg2+(Cl,OH)2O3Orth. mmm(2/m2/m2/m)
3.DD.20Terlinguaite[Hg3]4+Hg2+Cl2O2Mon. 2/m : B2/m
3.DD.25PinchiteHg2+5Cl2O4Orth. mmm(2/m2/m2/m) : Ibam
3.DD.30Gianellaite[(Hg2N)2](SO4)(H2O)xIso. 43m : F43m
3.DD.30Mosesite(Hg2N)(Cl,SO4,MoO4) · H2OIso. 43m : F43m
3.DD.35Kleinite(Hg2N)(Cl,SO4) · nH2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
3.DD.40Tedhadleyite[Hg2]2+5Hg2+I2(Cl,Br)2O4Tric. 1
3.DD.45Vasilyevite[Hg2]2+10I3Br2Cl[CO3]O6Tric. 1 : P1
3.DD.50Aurivilliusite[Hg2]2+Hg2+2(I,Br,Cl)2O2Mon. 2/m : B2/b
3.DD.55TerlinguacreekiteHg2+3Cl2O2Orth.
3.DD.60Kelyanite[Hg]2+6Sb3+BrCl2O6Trig. 3 : P3
3.DD.65ComancheiteHg2+55N3-24(NH2,OH)4(Cl,Br)34Orth.
3.DD.70GaildunningiteHg2+3[NHg2+2]18(Cl,I,OH,Br,S)24Orth. mmm(2/m2/m2/m)

Fluorescence of MikecoxiteHide

Not fluorescent

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MikecoxiteHide

References for MikecoxiteHide

Localities for MikecoxiteHide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Spain
 
  • Extremadura
    • Badajoz
      • Usagre
Carnegie Museum of Natural History ...
USA (TL)
 
  • Nevada
    • Humboldt County
      • Opalite Mining District
Miyawaki et al. (2021) +1 other reference
 
and/or  
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